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Methyl hydroperoxide

From Wikipedia, the free encyclopedia
Methyl hydroperoxide
Names
IUPAC name
Methaneperoxol
Other names
Hydroperoxide, methyl
Methane hydroperoxide
Methyl hydrogen peroxide
Hydroperoxymethane
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/CH4O2/c1-3-2/h2H,1H3
    Key: MEUKEBNAABNAEX-UHFFFAOYSA-N
Properties
CH4O2
Molar mass48.041 g·mol−1
Appearancecolorless liquid
Density0.9967 g/cm3 at 15°C
Melting point<25 °C
Boiling point46 °C (115 °F; 319 K)
Miscible in water and diethyl ether
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
explosive
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Methyl hydroperoxide is theorganic compound with the formula CH3OOH. It is a volaltile colorless liquid. In addition to being of theoretical interest as the simplest organichydroperoxide, methyl hydroperoxide is an intermediate in the oxidation ofmethane.[1] When condensed or in concentrated form methyl hydroperoxide is rather explosive, unlike tertiary hydroperoxides such astert-butylhydroperoxide.[2] Its laboratory preparation was first reported in 1929.[3]

References

[edit]
  1. ^Dummer, Nicholas F.; Willock, David J.; He, Qian; Howard, Mark J.; Lewis, Richard J.; Qi, Guodong; Taylor, Stuart H.; Xu, Jun; Bethell, Don; Kiely, Christopher J.; Hutchings, Graham J. (2023)."Methane Oxidation to Methanol".Chemical Reviews.123 (9):6359–6411.doi:10.1021/acs.chemrev.2c00439.PMC 10176486.PMID 36459432.
  2. ^Roger A. Sheldon (1983). "Synthesis and uses of alkyl hydroperoxides and dialkyl peroxides". In Patai, Saul (ed.).Syntheses and Uses of Hydroperoxides and Dialkylperoxides. PATAI'S Chemistry of Functional Groups. John Wiley & Sons. pp. 161–200.doi:10.1002/9780470771730.ch6.ISBN 978-0-471-10218-2.
  3. ^Rieche, Alfred; Hitz, Fritz (1929). "Über Monomethyl-hydroperoxyd)".Berichte der Deutschen Chemischen Gesellschaft.62 (8):2458–2474.doi:10.1002/cber.19290620888.
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