Maltitol is asugar alcohol (apolyol) used as asugar substitute andlaxative. It has 75–90% of the sweetness ofsucrose (table sugar) and nearly identical properties, except forbrowning. It is used to replace table sugar because it is half ascalorific, does not promote tooth decay, and has a somewhat lesser effect onblood glucose. In chemical terms, maltitol is known as4-O-α-glucopyranosyl-D-sorbitol. It is used in commercial products under trade names such as Lesys, Maltisweet and SweetPearl.[1]
Maltitol's highsweetness allows it to be used without being mixed with other sweeteners. It exhibits a negligible cooling effect (positiveheat of solution) in comparison with othersugar alcohols, similar to the subtle cooling effect ofsucrose.[3]It is used in candy manufacture, particularly sugar-freehard candy,chewing gum,chocolates,baked goods, andice cream. The pharmaceutical industry uses maltitol as anexcipient, where it is used as a low-calorie sweetening agent. Its similarity tosucrose allows it to be used in syrups with the advantage thatcrystallization (which may cause bottle caps to stick) is less likely. Maltitol may also be used as aplasticizer ingelatin capsules, as anemollient, and as ahumectant.[4]
Maltitol provides between 2 and 3kilocalories per gram [kcal/g] (8–10 kJ/g).[5] Maltitol is largely unaffected by human digestive enzymes and is fermented bygut flora, with about 15% of the ingested maltitol excreted unchanged in the feces.[6]
Maltitol in its crystallized form measures the same (bulk) astable sugar, but does notcaramelize nor participate inMaillard reactions upon heating due to its relative chemical inertness.[7][8] The crystallized form is readily dissolved in warm liquids (≈ 50 °C (120 °F) and above); the powdered form is preferred if room-temperature or cold liquids are used. Due to its sucrose-like structure, maltitol is easy to produce and made commercially available in crystallized, powdered, and syrup forms.