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Lithium tritelluride

From Wikipedia, the free encyclopedia
Lithium tritelluride
Identifiers
3D model (JSmol)
  • InChI=1S/Li.3H2Te/h;3*1H2
    Key: AVUONMXBLBDKIN-UHFFFAOYSA-N
  • [Li].[Te].[Te].[Te]
Properties
LiTe3
Molar mass389.74 g·mol−1
Related compounds
Related compounds
lithium telluride
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Lithium tritelluride is anintercalary compound oflithium andtellurium withempirical formulaLiTe
3
. It is one of four known members of the Li-Te system, the others being the raw metals andlithium telluride (Li
2
Te
).

LiTe3 was first discovered in 1969 by researchers at theUS Atomic Energy Commission.[1] Research into the compound has been primarily driven by the possibility of usingmolten tellurium salts to cool anuclear reactor.[2][3][4]

Lithium tritelluride can be synthesized by heating a mixture of the appropriate stoichiometry. It is unstable below304 °C; if left below that temperature, it will decompose, releasingtellurium vapor.[2][3][4]

Structurally, lithium tritelluride is composed ofparallelgraphene-like planes of tellurium. Atoms in these planes are aligned to form "vertical" columns of tellurium; the lithium ions then form columns running through the center of each tellurium hexagon.[5]

References

[edit]
  1. ^Foster, M. S.; Johnson, C. E.; Davis, K. A.; Peck, J.; Schablaske, R. (1969). (Technical report). USAEC. p. 141. ANL-7575.{{cite tech report}}:Missing or empty|title= (help), as cited inValentine, Cavin & Yakel 1977.
  2. ^abHitch, B.F.; Toth, L.M.; Brynestad, J. (January 1978). "The decomposition equilibrium of LiTe3".Journal of Inorganic and Nuclear Chemistry.40 (1):31–34.doi:10.1016/0022-1902(78)80301-7.
  3. ^abCunningham, P. T.; Johnson, S. A.; Cairns, E. J. (1973). "Phase Equilibria in Lithium-Chalcogen Systems".Journal of the Electrochemical Society.120 (3): 328.doi:10.1149/1.2403448.
  4. ^abSongster, J.; Pelton, A. D. (June 1992). "The li-te (lithium-tellurium) system".Journal of Phase Equilibria.13 (3):300–303.doi:10.1007/BF02667559.S2CID 97799347.
  5. ^Valentine, D. Y.; Cavin, O. B.; Yakel, H. L. (15 May 1977)."On the crystal structure of LiTe3".Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry.33 (5):1389–1396.Bibcode:1977AcCrB..33.1389V.doi:10.1107/S0567740877006141.S2CID 98036149.
Compounds withnoble gases
Compounds withhalogens
Oxides andhydroxides
Compounds withchalcogens
Compounds withpnictogens
Compounds withgroup 14 elements
Compounds withgroup 13 elements
Compounds withtransition metals
Organic (soaps)
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Minerals
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