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Lithium tellurite

From Wikipedia, the free encyclopedia
Lithium tellurite
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/2Li.H2O3Te/c;;1-4(2)3/h;;(H2,1,2,3)/q2*+1;/p-2
    Key: NBPOTQRWKBWQSQ-UHFFFAOYSA-L
  • [Li+].[Li+].[O-][Te](=O)[O-]
Properties
Li2O3Te
Molar mass189.48 g·mol−1
Appearancesolid
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Lithium tellurite is aninorganic compound, with the chemical formula Li2TeO3. It crystallises in themonoclinic crystal system, with space groupC2/c.[1] It can be prepared by reactinglithium oxide,[2]lithium hydroxide[3] orlithium carbonate[4] withtellurium dioxide. It reacts withlithium fluoride at high temperatures in a 3:1stoichiometric ratio to obtain Li7(TeO3)3F.[4]

References

[edit]
  1. ^Folger, F. Crystal structure of lithium tellurate(IV).Zeitschrift fuer Anorganische und Allgemeine Chemie, 1975. 411 (2): 103-110. ISSN: 0044-2313.
  2. ^Moret, Jacques; Cachau-Herreillat, Danielle; Norbert, Alain; Maurin, Maurice. Lithium oxide-tellurium dioxide system.Comptes Rendus des Seances de l'Académie des Sciences, Série C: Sciences Chimiques, 1971. 272 (23): 1870-1873. ISSN: 0567-6541.
  3. ^Breusov, O.N.; Revzina, T. V.; Druz, N. A. Synthesis and some properties of lithium tellurite.Zhurnal Neorganicheskoi Khimii, 1965. 10 (9): 1990-1992. ISSN: 0044-457X.
  4. ^abJiang-He Feng, Chun-Li Hu, Hou-Ping Xia, Fang Kong, Jiang-Gao Mao (2017-12-04)."Li 7 (TeO 3 ) 3 F: A Lithium Fluoride Tellurite with Large Second Harmonic Generation Responses and a Short Ultraviolet Cutoff Edge".Inorganic Chemistry.56 (23):14697–14705.doi:10.1021/acs.inorgchem.7b02670.ISSN 0020-1669.PMID 29131609.Archived from the original on 2020-07-09. Retrieved2021-03-19.{{cite journal}}: CS1 maint: multiple names: authors list (link)
Compounds withnoble gases
Compounds withhalogens
Oxides andhydroxides
Compounds withchalcogens
Compounds withpnictogens
Compounds withgroup 14 elements
Compounds withgroup 13 elements
Compounds withtransition metals
Organic (soaps)
Other compounds
Minerals
Other Li-related
Salts and covalent derivatives of thetellurite ion
H2TeO3He
Li2TeO3BeBxTexOxCNO+FNe
Na2TeO3MgAlSiPSClAr
K2TeO3CaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKr
RbSrYZrNbMoTcRuRhPdAgCdTeO3InSnSb+TeO4IXe
CsBa*LuHfTaWReOsIrPtAuHgTlPbBiPoAtRn
FrRa**LrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
 
*LaCePrNdPmSmEuGdTbDyHoErTmYb
**AcThPaUNpPuAmCmBkCfEsFmMdNo
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