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Lithium hypochlorite

From Wikipedia, the free encyclopedia
Lithium hypochlorite
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.034.130Edit this at Wikidata
RTECS number
  • NH3486000
UNII
  • InChI=1S/ClO.Li/c1-2;/q-1;+1 checkY
    Key: LWXVCCOAQYNXNX-UHFFFAOYSA-N checkY
  • InChI=1/ClO.Li/c1-2;/q-1;+1
    Key: LWXVCCOAQYNXNX-UHFFFAOYAC
  • [Li+].[O-]Cl
Properties
LiOCl
Molar mass58.39 g·mol−1
AppearanceColorless or white crystalline solid
Odorchlorine-like odor
Density0.531 g/cm3 (20 °C)
Melting point135 °C (275 °F; 408 K)
Boiling point1,336 °C (2,437 °F; 1,609 K)
soluble
Related compounds
Otheranions
Othercations
Related compounds
Hazards
> 180 °C (356 °F; 453 K)
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Chemical compound

Lithium hypochlorite is achemical compound with thechemical formula ofLiOCl. It is thelithiumsalt ofhypochlorous acid. It consists of lithiumcations (Li+) andhypochloriteanions (OCl). It is a colorless, crystalline compound. It has been used as a disinfectant for pools, and is also used as a reagent for some chemical reactions.

Safety

[edit]

Doses of 500 mg/kg cause detrimental clinical signs and significant mortality inrats.[1] The use ofchlorine-baseddisinfectants indomestic water, although widespread, has led to some controversy because of the formation of small quantities of harmfulbyproducts such aschloroform. Studies showed no uptake of lithium ifpools with lithium hypochlorite have been used.[2]

Use in swimming pools

[edit]

Lithium hypochlorite has been used as a fast-acting disfinectant for vinylswimming pools. However, due to the increasing demand for lithium inlithium-ion batteries, manufacturers have stopped producing lithium hypochlorite, making it much harder to find these days.[3]

See also

[edit]

References

[edit]
  1. ^Hoberman A. M.; Deprospo J. R.; Lochry E. A.; Christian M. S. (1990)."Developmental toxicity study of orally administered lithium hypochlorite in rats".Journal of the American College of Toxicology.9 (3):367–379.doi:10.3109/10915819009078746.S2CID 97957731.
  2. ^McCarty J. D.; Carter S. P.; Fletcher M. J.; Reape M. J. (1994). "Study of lithium absorption by users of spas treated with lithium ion".Hum Exp Toxicol.13 (5):315–9.Bibcode:1994HETox..13..315M.doi:10.1177/096032719401300506.PMID 8043312.S2CID 27971592.
  3. ^"Pool Shock - What YOU Need to Know | Leisure Pool & Spa Supply".Leisure Pool & Spa Supply, Inc. 2019-06-19. Retrieved2024-07-07.
Compounds withnoble gases
Compounds withhalogens
Oxides andhydroxides
Compounds withchalcogens
Compounds withpnictogens
Compounds withgroup 14 elements
Compounds withgroup 13 elements
Compounds withtransition metals
Organic (soaps)
Other compounds
Minerals
Other Li-related
Salts and covalent derivatives of thehypochlorite ion
HOClHe
LiOClBeBCClONO2OFNe
NaOClMgAlSiPSClAr
KOClCa(OCl)2ScTiVCrMnFeCoNiCuZnGaGeAsSeBrKr
RbSrYZrNbMoTcRuRhPdAgOClCdInSnSbTeIXe
CsBa(ClO)2*LuHfTaWReOsIrPtAuHgTlPbBiPoAtRn
FrRa**LrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
 
*LaCePrNdPmSmEuGdTbDyHoErTmYb
**AcThPaUNpPuAmCmBkCfEsFmMdNo


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