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Jojoba oil

From Wikipedia, the free encyclopedia
Oil extracted from jojoba seeds

Glass vial containing jojoba oil

Jojoba oil (/həˈhbə/ ) is the liquid produced in the seed of theSimmondsia chinensis (jojoba)[1] plant, ashrub, which is native to southernArizona, southernCalifornia, and northwesternMexico. Theoil makes up approximately 50% of the jojoba seed by weight.[2] The terms "jojoba oil" and "jojoba wax" are often used interchangeably because the wax visually appears to be a mobile oil, but as a wax it is composed almost entirely (~97%) of mono-esters of long-chain fatty acids(wax ester) and alcohols (isopropyl jojobate), accompanied by only a tiny fraction oftriglyceride esters. This composition accounts for its extreme shelf-life stability and extraordinary resistance to high temperatures, compared with true vegetable oils.

History

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TheO'odham Native American tribe extracted the oil fromjojoba seeds to treat sores and wounds. The collection and processing of the seed from naturally occurring stands marked the beginning of jojoba domestication in the early 1970s.[2]

In 1943, natural resources of the U.S, including the jojoba oil, were used during war as additives to motor oil, transmission oil, and differential gear oil. Machine guns were lubricated and maintained with jojoba.[3]

Appearance

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Unrefined jojoba oil appears as a clear golden liquid atroom temperature with a slightly nutty odor. Refined jojoba oil is colorless and odorless. Themelting point of jojoba oil is approximately 10 °C (50 °F)[4] and theiodine value is approximately 80.[5] Jojoba oil is relatively shelf-stable when compared with other vegetable oils mainly because it contains fewtriglycerides, unlike most other vegetable oils such asgrape seed oil andcoconut oil.[6] It has an oxidative stability index of approximately 60,[7] which means that it is more shelf-stable thansafflower oil,canola oil,almond oil, orsqualene but less thancastor oil andcoconut oil.

Chemistry

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Physical properties
Freezing point7-10.6 °C[8][9]
Refractive index1.4650 at 25 °C[8]
Specific gravity0.863 at 25 °C[8]
Smoke point195 °C[9]
Flash point295 °C[8]
Iodine number82[8]
Viscosity48 SUS at 99 °C[9]

127 SUS at 37.8 °C[9]

Viscosity index190-230[10]
Fatty-acid content[11]
Fatty acidCarbon atoms:double bondsPosition(s) of double bondPercentage (mole fraction)
Palmitic acidC16:0-0.3
Palmitoleic acidC16:190.3
Stearic acidC18:0-0.2
Oleic acidC18:199.3
Arachidic acidC20:0--
11-Eicosenoic acidC20:11176.7
Behenic acidC22:0-trace
Erucic acidC22:11312.1
Lignoceric acidC24:0-0.1
Nervonic acidC24:1151.0

The fatty acid content of Jojoba oil can vary significantly depending on the soil and climate in which the plant is grown, as well as when it is harvested and how the oil is processed. In general, it contains a high proportion of mono-unsaturated fatty acids, primarily11-Eicosenoic acid (gondoic acid).

Uses

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Being derived from a plant that is slow-growing and difficult to cultivate, jojoba oil is mainly used for small-scale applications such as pharmaceuticals and cosmetics.[12] Overall, it is used as a replacement forwhale oil and its derivatives, such ascetyl alcohol. The ban on importing whale oil to the U.S. in 1971 led to the discovery that jojoba oil is "in many regards superior tosperm whale oil for applications in the cosmetics and other industries".[2]

Jojoba oil is found as an additive in manycosmetic products, especially those marketed as being made from natural ingredients.[citation needed] In particular, such products commonly containing jojoba arelotions andmoisturizers, hairshampoos andconditioners.[citation needed]

Likeolestra, jojoba oil is edible but non-caloric and non-digestible, meaning the oil will pass out of the intestines unchanged and can mimicsteatorrhea—a health condition characterized by the inability to digest or absorb normal dietary fats. Thus, this indigestible oil is present in the stool, but does not indicate an intestinal disease. If consumption of jojoba oil is discontinued in a healthy person, the indigestible oil in the stool will disappear. Jojoba oil also contains approximately 12.1% of the fatty aciderucic acid that would appear to have toxic effects on the heart at high enough doses, if it were digestible.[13]

See also

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Photo gallery

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  • Plant
    Plant
  • Female flower
    Female flower
  • Male flower
    Male flower
  • Fruits
    Fruits
  • Seed
    Seed

References

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  1. ^Sturtevant, Drew; Lu, Shaoping; Zhou, Zhi-Wei; Shen, Yin; Wang, Shuo; Song, Jia-Ming; Zhong, Jinshun; Burks, David J.; Yang, Zhi-Quan; Yang, Qing-Yong; Cannon, Ashley E.; Herrfurth, Cornelia; Feussner, Ivo; Borisjuk, Ljudmilla; Munz, Eberhard; Verbeck, Guido F.; Wang, Xuexia; Azad, Rajeev K.; Singleton, Brenda; Dyer, John M.; Chen, Ling-Ling; Chapman, Kent D.; Guo, Liang (13 March 2020)."The genome of jojoba (Simmondsia chinensis): A taxonomically isolated species that directs wax ester accumulation in its seeds".Science Advances.6 (11): eaay3240.Bibcode:2020SciA....6.3240S.doi:10.1126/sciadv.aay3240.PMC 7065883.PMID 32195345.
  2. ^abcUndersander DJ, Oelke EA, Kaminski AR, Doll JD, Putnam DH, Combs SM, Hanson CV (1990).Jojoba.Alternative field crops manual (Report). University of Wisconsin-Extension, Cooperative Extension.
  3. ^Gentry HS (1 January 1958). "The Natural History of Jojoba (Simmondsia chinensis) and Its Cultural Aspects".Economic Botany.12 (3):261–295.doi:10.1007/bf02859772.JSTOR 4287990.S2CID 20974482.
  4. ^"AOCS Method Cc 18-80". The American Oil Chemists' Society (AOCS). Archived fromthe original on 13 March 2007. Retrieved13 October 2006.
  5. ^"AOCS Method Cd 1-25". The American Oil Chemists' Society (AOCS). Archived fromthe original on 13 March 2007. Retrieved13 October 2006.
  6. ^Matsumoto, Y.; Ma, S.; Tominaga, T.; Yokoyama, K.; Kitatani, K.; Horikawa, K.; Suzuki, K. (2019)."Acute Effects of Transdermal Administration of Jojoba Oil on Lipid Metabolism in Mice".Medicina.55 (9): 594.doi:10.3390/medicina55090594.PMC 6780807.PMID 31540183.
  7. ^"AOCS Method Cd 12b-92". The American Oil Chemists' Society (AOCS). Archived fromthe original on 13 March 2007. Retrieved13 October 2006.
  8. ^abcdeWisniak J (1987).The chemistry and technology of jojoba oil. The American Oil Chemists Society. p. 24.ISBN 978-0-935315-17-2.
  9. ^abcdEl Bassam N (1998).Energy Plant Species: Their Use and Impact on Environment and Development. Earthscan. p. 168.ISBN 978-1-873936-75-7.
  10. ^Heilweil IJ (1988).Review of Lubricant Properties of Jojoba Oil and its Derivatives. The American Oil Chemists Society.ISBN 978-0-935315-22-6.
  11. ^Busson-Breysse, J.; Farines, M.; Soulier, J. (September 1994). "Jojoba wax: Its esters and some of its minor components".Journal of the American Oil Chemists' Society.71 (9):999–1002.doi:10.1007/BF02542268.
  12. ^Wolfmeier U, Schmidt H, Heinrichs FL, Michalczyk G, Payer W, Dietsche W, Boehlke K, Hohner G, Wildgruber J (2002). "Waxes".Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH.doi:10.1002/14356007.a28_103.ISBN 3527306730..
  13. ^Place, A. R. (September 1992). "Comparative aspects of lipid digestion and absorption: physiological correlates of wax ester digestion".American Journal of Physiology. Regulatory, Integrative and Comparative Physiology.263 (3):R464 –R471.doi:10.1152/ajpregu.1992.263.3.R464.PMID 1415629.

External links

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