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Isotopes of ununennium

From Wikipedia, the free encyclopedia

Ununennium (119Uue) has not yet been synthesised, so there is no experimental data and astandard atomic weight cannot be given. Like allsynthetic elements, it would have nostable isotopes.

List of isotopes

[edit]

No isotopes of ununennium are known.

Nucleosynthesis

[edit]

Target-projectile combinations leading toZ = 119 compound nuclei

[edit]

The below table contains various combinations of targets and projectiles that could be used to form compound nuclei withZ = 119.[1]

TargetProjectileCNAttempt result
208Pb87Rb295UueReaction yet to be attempted
209Bi86Kr295UueReaction yet to be attempted
238U59Co297UueReaction yet to be attempted
237Np58Fe295UueReaction yet to be attempted
244Pu55Mn299UueReaction yet to be attempted
243Am54Cr297Uue[2]Reaction yet to be attempted
248Cm51V299UueReaction being attempted
250Cm51V301UueReaction yet to be attempted
249Bk50Ti299UueFailure to date
249Cf45Sc294UueReaction yet to be attempted
254Es48Ca302UueFailure to date

Cold fusion

[edit]

Following the claimed synthesis of293Og in 1999 at theLawrence Berkeley National Laboratory from208Pb and86Kr, the analogous reactions209Bi +86Kr and208Pb +87Rb were proposed for the synthesis of element 119 and its then-unknown alpha decaydaughters, elements117,115, and113.[3] The retraction of these results in 2001[4] and more recent calculations on the cross sections for "cold" fusion reactions cast doubt on this possibility; for example, a maximum yield of 2fb is predicted for the production of294Uue in the former reaction.[5] Radioactive ion beams may provide an alternative method utilizing alead orbismuth target, and may enable the production of more neutron-rich isotopes should they become available at required intensities.[5]

Hot fusion

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243Am(54Cr,xn)297−xUue

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There are indications that the team at theJoint Institute for Nuclear Research (JINR) in Russia plans to try this reaction in the future. The product of the 3n channel would be294Uue; its expected granddaughter286Mc was synthesised in a preparatory experiment at the JINR in 2021, using the reaction243Am(48Ca,5n)286Mc.[2]

The team at the Heavy Ion Research Facility inLanzhou (HIRFL), which is operated by theInstitute of Modern Physics (IMP) of theChinese Academy of Sciences, also plans to try the243Am+54Cr reaction.[6][7]

248Cm(51V,xn)299−xUue

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The team at RIKEN inWakō, Japan began bombardingcurium-248 targets with avanadium-51 beam in January 2018[8] to search for element 119. Curium was chosen as a target, rather than heavierberkelium orcalifornium, as these heavier targets are difficult to prepare.[9] The reduced asymmetry of the reaction is expected to approximately halve the cross section, requiring a sensitivity "on the order of at least 30 fb".[10] The248Cm targets were provided byOak Ridge National Laboratory. RIKEN developed a high-intensity vanadium beam.[11] The experiment began at a cyclotron while RIKEN upgraded its linear accelerators; the upgrade was completed in 2020.[12] Bombardment may be continued with both machines until the first event is observed; the experiment is currently running intermittently for at least 100 days per year.[13][9] The RIKEN team's efforts are being financed by theEmperor of Japan.[14]

248
96
Cm
+51
23
V
299
119
Uue
* → no atoms yet

The produced isotopes of ununennium are expected to undergo two alpha decays to known isotopes ofmoscovium (288Mc and287Mc respectively),[8] which would anchor them to a known sequence of five further alpha decays and corroborate their production. In 2022, the optimal reaction energy for synthesis of ununennium in this reaction was experimentally estimated as234.8±1.8 MeV at RIKEN.[15] The cross section is probably below 10 fb.[11]

As of September 2023, the team at RIKEN had run the248Cm+51V reaction for 462 days. A report by the RIKEN Nishina Center Advisory Committee noted that this reaction was chosen because of the availability of the target and projectile materials, despite predictions favoring the249Bk+50Ti reaction, owing to the50Ti projectile being closer to doubly magic48Ca and having an even atomic number (22); reactions with even-Z projectiles have generally been shown to have greater cross-sections. The report recommended that if the 5 fb cross-section limit is reached without any events observed, then the team should "evaluate and eventually reconsider the experimental strategy before taking additional beam time."[16] As of August 2024, the team at RIKEN was still running this reaction "24/7".[17]

249Bk(50Ti,xn)299−xUue

[edit]

From April to September 2012, an attempt to synthesize the isotopes295Uue and296Uue was made by bombarding a target ofberkelium-249 withtitanium-50 at theGSI Helmholtz Centre for Heavy Ion Research inDarmstadt, Germany.[18][19] This reaction between249Bk and50Ti was predicted to be the most favorable practical reaction for formation of ununennium,[19] as it is rather asymmetrical,[20] though also somewhat cold.[21] (The reaction between254Es and48Ca would be superior, but preparing milligram quantities of254Es for a target is difficult.)[20] Moreover, as berkelium-249 decays tocalifornium-249 (the next element) with a short half-life of 327 days, this allowed elements 119 and 120 to be searched for simultaneously.[10] Nevertheless, the necessary change from the "silver bullet"48Ca to50Ti divides the expected yield of ununennium by about twenty, as the yield is strongly dependent on the asymmetry of the fusion reaction.[20] Due to the predicted short half-lives, the GSI team used new "fast" electronics capable of registering decay events within microseconds.[19][20]

249
97
Bk
+50
22
Ti
299
119
Uue
* → no atoms
249
98
Cf
+50
22
Ti
299
120
Ubn
* → no atoms

Neither element 119 nor element 120 was observed. This implied a limiting cross-section of 65 fb for producing element 119 in these reactions, and 200 fb for element 120.[21][10] The predicted actual cross section for producing element 119 in this reaction is around 40 fb, which is at the limits of current technology.[20] (The record lowest cross section of an experimentally successful reaction is 30 fb for the reaction between209Bi and70Zn producingnihonium.)[20] The experiment was originally planned to continue to November 2012,[22] but was stopped early to make use of the249Bk target to confirm the synthesis oftennessine (thus changing the projectiles to48Ca).[21]

The team at theJoint Institute for Nuclear Research inDubna, Russia, planned to attempt this reaction.[23][24][25][26][27][28]

254Es(48Ca,xn)302−xUue

[edit]

The synthesis of ununennium was first attempted in 1985 by bombarding a sub-microgram target of einsteinium-254 withcalcium-48 ions at the superHILAC accelerator at Berkeley, California:

254
99
Es
+48
20
Ca
302
119
Uue
* → no atoms

No atoms were identified, leading to a limitingcross section of 300nb.[29] Later calculations suggest that the cross section of the 3n reaction (which would result in299Uue and three neutrons as products) would actually be six hundred thousand times lower than this upper bound, at 0.5 pb.[30] Tens of milligrams of einsteinium, an amount that cannot presently be produced, would be needed for this reaction to have a reasonable chance of succeeding.[11]

References

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  1. ^Isospin dependence in heavy-element synthesis in fusion-evaporation reactions with neutron-rich radioactive ion-beams, A. Yakushev et al.
  2. ^ab"Superheavy Element Factory: overview of obtained results". Joint Institute for Nuclear Research. 24 August 2023. Retrieved7 December 2023.
  3. ^Hoffman, Ghiorso & Seaborg 2000, p. 431.
  4. ^Public Affairs Department (21 July 2001)."Results of element 118 experiment retracted". Berkeley Lab. Archived fromthe original on 29 January 2008. Retrieved18 January 2008.
  5. ^abLoveland, W. (2007)."Synthesis of transactinide nuclei using radioactive beams"(PDF).Physical Review C.76 (1) 014612.Bibcode:2007PhRvC..76a4612L.doi:10.1103/PhysRevC.76.014612.
  6. ^Geng, Chang; Chen, Peng-Hui; Niu, Fei; Yang, Zu-Xing; Zeng, Xiang-Hua; Feng, Zhao-Qing (23 February 2024). "Assessing the Impact of Nuclear Mass Models on the Prediction of Synthesis Cross Sections for Superheavy Elements".Physical Review C.109 (5) 054611.arXiv:2402.15304v1.Bibcode:2024PhRvC.109e4611G.doi:10.1103/PhysRevC.109.054611.
  7. ^Gan, Z. G.; Huang, W. X.; Zhang, Z. Y.; Zhou, X. H.; Xu, H. S. (2022). "Results and perspectives for study of heavy and super-heavy nuclei and elements at IMP/CAS".The European Physical Journal A.58 (158) 158.Bibcode:2022EPJA...58..158G.doi:10.1140/epja/s10050-022-00811-w.
  8. ^abSakai, Hideyuki; Haba, Hiromitsu; Morimoto, Kouji; Sakamoto, Naruhiko (9 December 2022)."Facility upgrade for superheavy-element research at RIKEN".The European Physical Journal A.58 (238): 238.Bibcode:2022EPJA...58..238S.doi:10.1140/epja/s10050-022-00888-3.PMC 9734366.PMID 36533209.S2CID 254530675.
  9. ^abSakai, Hideyuki (27 February 2019)."Search for a New Element at RIKEN Nishina Center"(PDF).infn.it. Retrieved17 December 2019.
  10. ^abcKhuyagbaatar, J.; Yakushev, A.; Düllmann, Ch. E.; et al. (2020)."Search for elements 119 and 120"(PDF).Physical Review C.102 (6). 064602.Bibcode:2020PhRvC.102f4602K.doi:10.1103/PhysRevC.102.064602.hdl:1885/289860.S2CID 229401931. Retrieved25 January 2021.
  11. ^abcGates, J.; Pore, J.; Crawford, H.; Shaughnessy, D.; Stoyer, M. A. (25 October 2022)."The Status and Ambitions of the US Heavy Element Program".osti.gov.doi:10.2172/1896856.OSTI 1896856.S2CID 253391052. Retrieved13 November 2022.
  12. ^Sakurai, Hiroyoshi (1 April 2020)."Greeting | RIKEN Nishina Center".With the completion of the upgrade of the linear accelerator and BigRIPS at the beginning of 2020, the RNC aims to synthesize new elements from element 119 and beyond.
  13. ^Ball, P. (2019)."Extreme chemistry: experiments at the edge of the periodic table"(PDF).Nature.565 (7741):552–555.Bibcode:2019Natur.565..552B.doi:10.1038/d41586-019-00285-9.ISSN 1476-4687.PMID 30700884.S2CID 59524524.We started the search for element 119 last June," says RIKEN researcher Hideto En'yo. "It will certainly take a long time — years and years — so we will continue the same experiment intermittently for 100 or more days per year, until we or somebody else discovers it.
  14. ^Chapman, Kit; Turner, Kristy (13 February 2018)."The hunt is on".Education in Chemistry. Royal Society of Chemistry. Retrieved28 June 2019.The hunt for element 113 was almost abandoned because of lack of resources, but this time Japan's emperor is bankrolling Riken's efforts to extend the periodic table to its eighth row.
  15. ^Tanaka, Masaomi; Brionnet, Pierre; Du, Miting; et al. (2022)."Probing Optimal Reaction Energy for Synthesis of Element 119 from51V+248Cm Reaction with Quasielastic Barrier Distribution Measurement".Journal of the Physical Society of Japan.91 (8): 042081–1–11.Bibcode:2022JPSJ...91h4201T.doi:10.7566/JPSJ.91.084201.S2CID 250399446.
  16. ^"RIKEN Nishina Center Advisory Committee Report"(PDF).riken.jp. Riken. 7 September 2023. Retrieved11 April 2024.
  17. ^Nelson, Felicity (15 August 2024)."How Japan Took the Lead in the Race to Discover Element 119".ACS Central Science.10 (9):1669–1673.doi:10.1021/acscentsci.4c01266.PMC 11539895.PMID 39507239.
  18. ^Modern alchemy: Turning a line,The Economist, May 12, 2012.
  19. ^abcDÜLLMANN, CHRISTOPH E. (2013)."Superheavy Element Research at Tasca at Gsi".Fission and Properties of Neutron-Rich Nuclei. WORLD SCIENTIFIC:271–277.doi:10.1142/9789814525435_0029.ISBN 978-981-4525-42-8. Retrieved21 March 2022.
  20. ^abcdefZagrebaev, Karpov & Greiner 2013.
  21. ^abc"Superheavy Element Research at TASCA"(PDF).
  22. ^"Search for element 119: Christoph E. Düllmann for theTASCA E119 collaboration"(PDF). Archived fromthe original(PDF) on 2016-03-04. Retrieved2015-09-15.
  23. ^"Scientists will begin experiments on the synthesis of element 119 in 2019".jinr.ru. JINR. 28 September 2016. Retrieved31 March 2017."The discovery of elements 115, 117 and 118 is an accomplished fact; they were placed in the periodic table, though still unnamed and will be confirmed only at the end of the year. The D.I.Mendeleev Periodic Table is not infinite. In 2019, scientists will begin the synthesis of elements 119 and 120 which are the first in the 8th period," said S.N. Dmitriev.
  24. ^Dmitriev, Sergey; Itkis, Mikhail; Oganessian, Yuri (2016).Status and perspectives of the Dubna superheavy element factory(PDF). Nobel Symposium NS160 – Chemistry and Physics of Heavy and Superheavy Elements.doi:10.1051/epjconf/201613108001.
  25. ^"What it takes to make a new element".Chemistry World. Retrieved2016-12-03.
  26. ^Roberto, J. B. (31 March 2015)."Actinide Targets for Super-Heavy Element Research"(PDF).cyclotron.tamu.edu. Texas A & M University. Retrieved28 April 2017.
  27. ^Morita, Kōsuke (5 February 2016)."The Discovery of Element 113".Archived from the original on 2021-11-18. Retrieved28 April 2017 – via YouTube.
  28. ^Morimoto, Kouji (2016).The discovery of element 113 at RIKEN(PDF). 26th International Nuclear Physics Conference. Archived fromthe original(PDF) on 9 December 2021. Retrieved14 May 2017.
  29. ^Lougheed, R.; Landrum, J.; Hulet, E.; et al. (3 June 1985)."Search for superheavy elements using the48Ca +254Esg reaction".Physical Review C.32 (5) (published 1 November 1985):1760–1763.Bibcode:1985PhRvC..32.1760L.doi:10.1103/PhysRevC.32.1760.PMID 9953034. Retrieved21 March 2022.
  30. ^Feng, Z.; Jin, G.; Li, J.; Scheid, W. (2009). "Production of heavy and superheavy nuclei in massive fusion reactions".Nuclear Physics A.816 (1): 33.arXiv:0803.1117.Bibcode:2009NuPhA.816...33F.doi:10.1016/j.nuclphysa.2008.11.003.S2CID 18647291.

Sources

[edit]
Group12 3456789101112131415161718
PeriodHydrogen and
alkali metals
Alkaline
earth metals
Pnicto­gensChal­co­gensHalo­gensNoble gases
12
345678910
1112131415161718
192021222324252627282930313233343536
373839404142434445464748495051525354
55561 asterisk71727374757677787980818283848586
87881 asterisk103104105106107108109110111112113114115116117118
119120
1 asterisk5758596061626364656667686970 
1 asterisk8990919293949596979899100101102
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