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Iron-55

From Wikipedia, the free encyclopedia
Artificial radioisotope of iron
Iron-55, 55Fe
General
Symbol55Fe
Namesiron-55, 55Fe, Fe-55
Protons(Z)26
Neutrons(N)29
Nuclide data
Half-life(t1/2)2.737 years
Decay products55Mn
Decay modes
Decay modeDecay energy (MeV)
Electron capture0.00519
Isotopes of iron
Complete table of nuclides

Iron-55 (55Fe) is aradioactive isotope ofiron with anucleus containing 26protons and 29neutrons. It decays byelectron capture tomanganese-55 and this process has a half-life of 2.737 years. The emittedX-rays can be used as an X-ray source for various scientific analysis methods, such asX-ray diffraction. Iron-55 is also a source forAuger electrons, which are produced during the decay.

Decay

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Iron-55 decays viaelectron capture tomanganese-55 with a half-life of 2.737 years.[1] The electrons around the nucleus rapidly adjust themselves to the lowered charge without leaving their shell, and shortly thereafter the vacancy in the "K" shell left by the nuclear-captured electron is filled by an electron from a higher shell. The difference in energy is released by emittingAuger electrons of 5.19 keV, with a probability of about 60%,K-alpha-1X-rays with energy of 5.89875 keV and a probability about 16.2%,K-alpha-2X-rays with energy of 5.88765 keV and a probability of about 8.2%, orK-betaX-rays with nominal energy of 6.49045 keV and a probability about 2.85%. The energies of the K-alpha-1 and -2 X-rays are so similar that they are often specified as mono-energetic radiation with 5.9 keV photon energy. Its probability is about 28%.[2] The remaining 12% is accounted for by lower-energy Auger electrons and a few photons from other, minor transitions.

Use

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The K-alpha X-rays emitted by themanganese-55 after the electron capture have been used as a laboratory source of X-rays in variousX-ray scattering techniques. The advantages of the emitted X-rays are that they are monochromatic and are continuously produced over a years-long period.[3] No electrical power is needed for this emission, which is ideal for portable X-ray instruments, such asX-ray fluorescence instruments.[4] TheExoMars mission ofESA used, in 2016,[5][6] such an iron-55 source for its combinedX-ray diffraction/X-ray fluorescence spectrometer.[7] The 2011 Mars missionMSL used a functionally similar spectrometer, but with a traditional, electrically powered X-ray source.[8]

The Auger electrons can be applied inelectron capture detectors forgas chromatography. The more widely usednickel-63 sources provide electrons from beta decay.[9]

Occurrence

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Iron-55 is most effectively produced by irradiation of iron withneutrons. The reaction (54Fe(n,γ)55Fe and56Fe(n,2n)55Fe) of the two most abundant isotopesiron-54 andiron-56 with neutrons yields iron-55. Most of the observed iron-55 is produced in these irradiation reactions, and it is not a primary fission product.[10] As a result ofatmospheric nuclear tests in the 1950s, and untilthe test ban in 1963, considerable amounts of iron-55 have been released into thebiosphere.[11] People close to the test ranges, for exampleIñupiat (Alaska Natives) and inhabitants of theMarshall Islands, accumulated significant amounts of radioactive iron. However, the shorthalf-life and the test ban decreased, within several years, the available amount of iron-55 nearly to the pre-nuclear test levels.[11][12]

References

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  1. ^Georges, Audi (2003). "The NUBASE Evaluation of Nuclear and Decay Properties".Nuclear Physics A.729 (1):3–128.Bibcode:2003NuPhA.729....3A.CiteSeerX 10.1.1.692.8504.doi:10.1016/j.nuclphysa.2003.11.001.
  2. ^Esam M. A. Hussein (2003).Handbook on radiation probing, gauging, imaging and analysis. Springer. p. 26.ISBN 978-1-4020-1294-5.
  3. ^Preuss, Luther E. (1966). "Demonstration of X-ray Diffraction by LiF using the Mn Kα X-rays Resulting From55Fe decay".Applied Physics Letters.9 (4):159–161.Bibcode:1966ApPhL...9..159P.doi:10.1063/1.1754691.
  4. ^Himmelsbach, B. (1982). "Portable X-ray Survey Meters forIn Situ Trace element Monitoring of Air Particulates".Toxic Materials in the Atmosphere, Sampling and Analysis.ISBN 978-0-8031-0603-1.
  5. ^"The ESA-NASA ExoMars Programme Rover, 2018". ESA. Archived fromthe original on 2009-12-23. Retrieved2010-03-12.
  6. ^"The ExoMars instrument suite". ESA. Retrieved2010-03-12.
  7. ^Marinangeli, L.; Hutchinson, I.; Baliva, A.; Stevoli, A.; Ambrosi, R.; Critani, F.; Delhez, R.; Scandelli, L.; Holland, A.; Nelms, N.; Mars-Xrd Team (March 12–16, 2007).An European XRD/XRF Instrument for the ExoMars Mission. 38th Lunar and Planetary Science Conference.Lunar and Planetary Science Conference. No. 1338. League City, Texas. p. 1322.Bibcode:2007LPI....38.1322M.
  8. ^Chemistry & Mineralogy (CheMin), NASA
  9. ^D.J. Dwight; E.A. Lorch; J.E. Lovelock (1976)."Iron-55 as an auger electron emitter : Novel source for gas chromatography detectors".Journal of Chromatography A.116 (2):257–261.doi:10.1016/S0021-9673(00)89896-9.
  10. ^Preston, A. (1970). "Concentrations of iron-55 in commercial fish species from the North Atlantic".Marine Biology.6 (4):345–349.doi:10.1007/BF00353667.S2CID 91254200.
  11. ^abPalmer, H. E.; Beasley, T. M. (1965). "Iron-55 in Humans and Their Foods".Science.149 (3682):431–2.Bibcode:1965Sci...149..431P.doi:10.1126/science.149.3682.431.PMID 17809410.S2CID 206565239.
  12. ^Beasley, T. M.; Held, E. E.; Conard, R. M.E. (1965). "Iron-55 in Rongelap people, fish and soils".Health Physics.22 (3):245–50.doi:10.1097/00004032-197203000-00005.PMID 5062744.

See also

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