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Iron(II) molybdate

From Wikipedia, the free encyclopedia
Iron(II) molybdate
Names
IUPAC name
Iron(II) molybdate
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/Fe.Mo.4O/q+2;;;;2*-1
    Key: QQOCLJJWXLOEJE-UHFFFAOYSA-N
  • [O-][Mo](=O)(=O)[O-].[Fe+2]
Properties
FeMoO4
Molar mass215.78 g/mol
AppearanceTan brown powder or crystals[1]
Density5.6 g/cm3 (20 °C)
Melting point1,115 °C (2,039 °F; 1,388 K)
0.00766 g/100 mL (20 °C)
0.038 g/100 mL (100 °C)
Thermochemistry
118.5 J/mol K
−1075 kJ/mol
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Iron(II) molybdate is aninorganic compound with thechemical formula FeMoO4.[2]

Synthesis

[edit]

Iron(II) molybdate is prepared by the reaction ofiron(II) chloride oriron(II) sulfate[3] andsodium molybdate.

Na2MoO4 + FeSO4 → Na2SO4 + FeMoO4
Na2MoO4 + FeCl2 → 2 NaCl + FeMoO4

Due to its very low aqueous solubility, iron(II) molybdate precipitates out as a brown powder from the above reactions, which can then be obtained by filtration.

Applications

[edit]

FeMoO4 has been used as relatively stable active material foranodes inLi-ion batteries for conversion reaction,[4] as anode material inaqueoussupercapacitors due to fastredox reactions[3] and ascatalyst foroxygen evolution inalkaline solutions.[5]

Safety

[edit]

Iron(II) molybdate is toxic and may cause irritation. It should not be released into the environment. Inhalation of dusts should be avoided.

References

[edit]
  1. ^"Iron(II) Molybdate". American Elements. Archived fromthe original on 2023-01-17. Retrieved2023-01-17.
  2. ^University of Akron Chemical Database[permanent dead link]
  3. ^abSenthilkumar, Baskar; Kalai Selvan, Ramakrishnan (2014-07-15). "Hydrothermal synthesis and electrochemical performances of 1.7 V NiMoO4⋅xH2O||FeMoO4 aqueous hybrid supercapacitor".Journal of Colloid and Interface Science.426:280–286.doi:10.1016/j.jcis.2014.04.010.PMID 24863794.
  4. ^Zhang, Zhenyu; Li, Wenyue; Ng, Tsz-Wai; Kang, Wenpei; Lee, Chun-Sing; Zhang, Wenjun (2015-10-13). "Iron(ii) molybdate (FeMoO4) nanorods as a high-performance anode for lithium ion batteries: structural and chemical evolution upon cycling".J. Mater. Chem. A.3 (41):20527–20534.doi:10.1039/c5ta05723j.ISSN 2050-7496.
  5. ^Singh, R. N.; Singh, J. P.; Singh, A. (2008-08-01). "Electrocatalytic properties of new spinel-type MMoO4 (M = Fe, Co and Ni) electrodes for oxygen evolution in alkaline solutions".International Journal of Hydrogen Energy.33 (16):4260–4264.Bibcode:2008IJHE...33.4260S.doi:10.1016/j.ijhydene.2008.06.008.
Fe(−II)
Fe(0)
Organoiron(0) compounds
Fe(I)
Organoiron(I) compounds
Fe(0,II)
Fe(II)
Organoiron(II) compounds
Fe(0,III)
Fe(II,III)
Fe(III)
Organoiron(III) compounds
Fe(IV)
Fe(VI)
Purported
Molybdates
Chloromolybdates
Dimolybdates
Related
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