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Indium(I) iodide

From Wikipedia, the free encyclopedia
Indium(I) iodide
Names
IUPAC name
iodoindium
Other names
Indium monoiodide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.034.301Edit this at Wikidata
EC Number
  • 237-746-3
  • InChI=1S/HI.In/h1H;/q;+1/p-1
    Key: FOVZCYAIUZHXGB-UHFFFAOYSA-M
  • [In]I
Properties
IIn
Molar mass241.722 g·mol−1
Appearancered-brown solid
Density5.32 g/cm3
Melting point365 °C (689 °F; 638 K)
insoluble
Hazards
GHS labelling:
GHS07: Exclamation markGHS08: Health hazard
Danger
H302,H315,H319,H334,H335
P301,P302,P305,P312,P330,P338,P351,P352
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Indium monoiodide is a binaryinorganic compound ofindium metal andiodine with the chemical formulaInI.[1][2]

Preparation

[edit]

Indium(I) iodide can be obtained by reacting indium with iodine orindium(III) iodide in vacuum at 300 °C to 400 °C or withmercury(II) iodide at 350 °C.[3]

2In + I2 → 2InI[4]
2In + InI3 → 3InI
2In + HgI2 → 2InI + Hg

Physical properties

[edit]

Indium(I) iodide forms a brown-reddiamagnetic solid. Its melt is black. The compound has anorthorhombic crystal structure in the space groupCmcm (space group no. 63) with the lattice parameters a = 475 pm, b = 1276 pm, c = 491 pm.[5]

Chemical properties

[edit]

Decomposes slowly with hot water:

2InI + H2O → InOH + HI

Reacts with water in the presence of oxygen:[6]

2InI + O + 3H2O → 2In(OH)2 + 2HI

References

[edit]
  1. ^"Indium(I) Iodide".American Elements. Retrieved29 March 2024.
  2. ^"Indium(I) iodide".Sigma Aldrich. Retrieved29 March 2024.
  3. ^Gasanov, A. A.; Lobachev, E. A.; Kuznetsov, S. V.; Fedorov, P. P. (1 November 2015)."Indium monoiodide: Preparation and deep purification".Russian Journal of Inorganic Chemistry.60 (11):1333–1336.doi:10.1134/S0036023615110066.ISSN 1531-8613. Retrieved29 March 2024.
  4. ^Rieke, Reuben D. (30 November 2016).Chemical Synthesis Using Highly Reactive Metals.John Wiley & Sons. p. 242.ISBN 978-1-118-92914-8. Retrieved29 March 2024.
  5. ^Fedorov, P P; Popov, A I; Simoneaux, R L (31 March 2017)."Indium iodides".Russian Chemical Reviews.86 (3):240–268.Bibcode:2017RuCRv..86..240F.doi:10.1070/RCR4609.
  6. ^Satya, Prakash (2013).Advanced Chemistry of Rare Elements. S. Chand Publishing. p. 244.ISBN 978-81-219-4254-6. Retrieved29 March 2024.
Iodine(−I)
Iodine(I)
Iodine(II)
Iodine(III)
Iodine(IV)
Iodine(V)
Iodine(VII)
Indium(I)
Organoindium(I) compounds
Indium(I,III)
Indium(III)
Organoindium(III) compounds
Salts and covalent derivatives of theiodide ion
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