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Immediately dangerous to life or health

From Wikipedia, the free encyclopedia
(Redirected fromIDLH)
Exposure to dangerous levels of airborne contaminants
Personal protective equipment for IDLH conditions: pressure-demand supplied-air respirator equipped with a full facepiece in combination with an auxiliary pressure-demand self-contained breathing apparatus

The termimmediately dangerous to life or health (IDLH) is defined by the USNational Institute for Occupational Safety and Health (NIOSH) as exposure to airborne contaminants that is "likely to cause death or immediate or delayed permanent adverse health effects or prevent escape from such an environment." Examples include smoke or other poisonous gases at sufficiently high concentrations. It is calculated using theLD50 or LC50.[1] TheOccupational Safety and Health Administration (OSHA) regulation (1910.134(b)) defines the term as "an atmosphere that poses an immediate threat to life, would cause irreversible adverse health effects, or would impair an individual's ability to escape from a dangerous atmosphere."[2]

IDLH values are often used to guide the selection of breathing apparatus that are made available to workers or firefighters in specific situations.[1]

The NIOSH definition does not includeoxygen deficiency (below 19.5%) although atmosphere-supplying breathing apparatus is also required.[3] Examples include high altitudes and unventilated,confined spaces.

The OSHA definition is arguably broad enough to include oxygen-deficient circumstances in the absence of "airborne contaminants", as well as many other chemical, thermal, or pneumatic hazards to life or health (e.g., pure helium, super-cooled or super-heated air, hyperbaric or hypo-baric or submerged chambers, etc.). It also uses the broader term "impair", rather than "prevent", with respect to the ability to escape. For example, blinding but non-toxic smoke could be considered IDLH under the OSHA definition if it would impair the ability to escape a "dangerous" but not life-threatening atmosphere (such as tear gas).

The OSHA definition is part of a legal standard, which is the minimum legal requirement. Users or employers are encouraged to apply proper judgment to avoid taking unnecessary risks, even if the only immediate hazard is "reversible", such as temporary pain, disorientation, nausea, or non-toxic contamination.

NIOSH respirator selection logic

[edit]
Personal protective equipment for IDLH conditions: pressure-demand self-contained breathing apparatus with a full facepiece

If the concentration of harmful substances is IDLH, the worker must use the most reliable respirators. Such respirators should not use cartridges or canister with the sorbent, as their lifetime is toopoorly predicted. In addition, the respirator must maintain positive pressure under the mask during inspiration, as this will prevent the leakage of unfiltered air through the gaps (which occur between the edges of the mask and the face sometimes).

Textbook NIOSH[4] recommended for use in IDLH conditions onlypressure-demand self-contained breathing apparatus with afull facepiece, or pressure-demand supplied-air respirator equipped with a full facepiece in combination with an auxiliary pressure-demand self-contained breathing apparatus.

IDLH values

[edit]

The following examples are listed in reference to IDLH values.[3]

Legend:[5]

Ca
NIOSH considers this substance to be a potential occupational carcinogen. Revised values may follow in parentheses.
N.D.
Not determined. That is, the level is unknown, not non-existent.
10%LEL
The IDLH value has been set at 10% of thelower explosive limit although other irreversible health effects or impairment of escape due to toxicology exist only at higher levels.
IDLH values for gases and vapors, used in industry
NumberSubstanceIDLH valueSource
CASICSCmg/m3ppm
75-07-00009Acetaldehyde3600 mg/m32000 ppm75070Archived 2015-10-02 at theWayback Machine
64-19-70363Acetic acid123 mg/m350 ppm64197
108-24-70209Acetic anhydride836 mg/m3200 ppm108247
67-64-10087Acetone5900 mg/m32500 ppm67641 (10% Lower explosive limit LEL)
75-05-80088Acetonitrile840 mg/m3500 ppm75058Archived 2015-10-02 at theWayback Machine
79-27-61235Acetylene tetrabromide113.1 mg/m38 ppm79276
107-02-80090Acrolein4.58 mg/m32 ppm107028
79-06-10091Acrylamide60 mg/m3-79061, carcinogenic substance
107-13-10092Acrylonitrile184.45 mg/m385 ppm107131
309-00-20774Aldrin25 mg/m3-309002, carcinogenic substance
107-18-60095Allyl alcohol47.6 mg/m320 ppm107186
107-05-10010Allyl chloride782.5 mg/m3250 ppm107051
106-92-30096Allyl glycidyl ether233.5 mg/m350 ppm106923
504-29-002142-Aminopyridine19.25 mg/m35 ppm504290
7664-41-70414Ammonia210 mg/m3300 ppm7664417
7773-06-01555Ammonium sulfamate1500 mg/m3-7773060
628-63-70218n-Amyl acetate5330 mg/m31000 ppm628637
626-38-00219sec-Amyl acetate5330 mg/m31000 ppm626380
62-53-30011Aniline381 mg/m3100 ppm62533, carcinogenic substance
90-04-00970o-Anisidine50 mg/m3-90040
104-94-90971p-Anisidine50 mg/m3-104949
7440-36-00775Antimony50 mg/m3-7440360
86-88-40973ANTU100 mg/m3-86884
7440-38-20013Arsenic5 mg/m3-7440382
7784-42-10222Arsine9.57 mg/m33 ppm7784421, carcinogenic substance
86-50-00826Azinphos-methyl10 mg/m3-86500
10361-37-20614Barium chloride50 mg/m3-7440393Archived 2015-10-02 at theWayback Machine
10022-31-81480Barium nitrate50 mg/m3-7440393Archived 2015-10-02 at theWayback Machine
71-43-20015Benzene1595 mg/m3500 ppm71432, carcinogenic substance
94-36-00225Benzoyl peroxide1500 mg/m3-94360
100-44-70016Benzyl chloride51.8 mg/m310 ppm100447
7440-41-70226Beryllium & beryllium compounds4 mg/m3-7440417
1303-86-20836Boron oxide2000 mg/m3-1303862
7637-07-20231Boron trifluoride69.3 mg/m325 ppm7637072
7726-95-60107Bromine19.6 mg/m33 ppm7726956
75-25-20108Bromoform8789 mg/m3850 ppm75252
106-99-000171,3-Butadiene4420 mg/m32000 ppm106990, (10% Lower explosive limit LEL); carcinogenic substance
78-93-301792-Butanone8850 mg/m33000 ppm78933
111-76-200592-Butoxyethanol3381 mg/m3700 ppm111762
123-86-40399n-Butyl acetate8075 mg/m31700 ppm123864, (10% Lower explosive limit LEL)
105-46-40840sec-Butyl acetate8075 mg/m31700 ppm105464 (10% Lower explosive limit LEL)
540-88-51445tert-Butyl acetate7125 mg/m31500 ppm540885, (10% Lower explosive limit LEL)
71-36-30111n-Butyl alcohol4242 mg/m31400 ppm71363
78-92-20112sec-Butyl alcohol6060 mg/m32000 ppm78922
75-65-00114tert-Butyl alcohol4848 mg/m31600 ppm75650
109-73-90374n-Butylamine897 mg/m3300 ppm109739
1189-85-11533tert-Butyl chromate15 mg/m3-1189851, carcinogenic substance
2426-08-60115n-Butyl glycidyl ether1332.5 mg/m3250 ppm2426086
109-79-50018n-Butyl mercaptan1845 mg/m3500 ppm109795
98-51-11068p-tert-Butyltoluene607 mg/m3100 ppm98511
7440-43-90020Cadmium dust9 mg/m3-7440439, carcinogenic substance
1306-19-00020Cadmium fume9 mg/m3-7440439, carcinogenic substance
7778-44-10765Calcium arsenate5 mg/m3-7778441, carcinogenic substance
1305-78-80409Calcium oxide25 mg/m3-1305788
76-22-21021Camphor200 mg/m3-76222
63-25-20121Carbaryl100 mg/m3-63252
1333-86-40471Carbon black1750 mg/m3-1333864
124-38-90021Carbon dioxide72000 mg/m340000 ppm124389
75-15-00022Carbon disulfide1555 mg/m3500 ppm75150
630-08-00023Carbon monoxide1380 mg/m31200 ppm630080
56-23-50024Carbon tetrachloride1258 mg/m3200 ppm56235, carcinogenic substance
57-74-90740Chlordane100 mg/m3-57749, carcinogenic substance
8001-35-20843Chlorinated camphene200 mg/m3-8001352, carcinogenic substance
31242–93–0-Chlorinated diphenyl oxide5 mg/m3-31242930
7782-50-50126Chlorine29 mg/m310 ppm7782505
10049-04-40127Chlorine dioxide13.35 mg/m35 ppm10049044
7790-91-20656Chlorine trifluoride75.6 mg/m320 ppm7790912
107-20-00706Chloroacetaldehyde144.5 mg/m345 ppm107200
532-27-40128α-Chloroacetophenone15 mg/m3-532274
108-90-70642Chlorobenzene4610 mg/m31000 ppm108907
2698-41-11065o-Chlorobenzylidene malonitrile2 mg/m3-2698411
74-97-50392Chlorobromomethane10580 mg/m32000 ppm74975
53469-21-90175Chlorodiphenyl (42% chlorine)5 mg/m3-53469219, carcinogenic substance
11097-69-10939Chlorodiphenyl (54% chlorine)5 mg/m3-53469219, carcinogenic substance
67-66-30027Chloroform2440 mg/m3500 ppm67663, carcinogenic substance
600-25-914231-Chloro-1-nitropropane5.06 mg/m3100 ppm600259
76-06-20750Chloropicrin13.44 mg/m32 ppm76062
126-99-80133β-Chloroprene10.86 mg/m3300 ppm126998, carcinogenic substance
1333-82-01194Chromium trioxide15 mg/m3-1333820, carcinogenic substance
--Chromium(II)250 mg/m3-cr2m3
--Chromium(III)25 mg/m3-cr3m3
7440-47-30029Chromium250 mg/m3-7440473
65996-93-21415Coal tar pitch volatiles80 mg/m3-65996932, carcinogenic substance
7440-48-40782Cobalt20 mg/m3-7440484
7440-50-80240Copper100 mg/m3-7440508
--Cotton dust (raw)100 mg/m3-cotdust
136-78-71142Crag® herbicide500 mg/m3-136787
108-39-40646m-Cresol1107.5 mg/m3250 ppmcresol
95-48-70030o-Cresol1107.5 mg/m3250 ppmcresol
106-44-50031p-Cresol1107.5 mg/m3250 ppmcresol
4170-30-30241Crotonaldehyde143.5 mg/m350 ppm123739
98-82-80170Cumene4428 mg/m3900 ppm98828 (10% Lower explosive limit LEL)
110-82-70242Cyclohexane4472 mg/m31300 ppm110827
108-93-00243Cyclohexanol1640 mg/m3400 ppm108930
108-94-10425Cyclohexanone2814 mg/m3700 ppm108941
110-83-81054Cyclohexene6720 mg/m32000 ppm110838
542-92-70857Cyclopentadiene2025 mg/m3750 ppm542927 (10% Lower explosive limit LEL)
13121-70-5-Cyhexatin80 mg/m3 (25 mg/m3 - for Sn)-tin-org
94-75-700332,4-D100 mg/m3-94757
50-29-30034DDT500 mg/m3-50293, carcinogenic substance
17702-41-90712Decaborane15 mg/m3-17702419
8065-48-30861Demeton10 mg/m3-8065483
123-42-20647Diacetone alcohol8550 mg/m31800 ppm123422
334-88-31256Diazomethane3.44 mg/m32 ppm334883 (10% Lower explosive limit LEL)
19287-45-70432Diborane16.95 mg/m315 ppm19287457
107-66-41278Dibutyl phosphate258 mg/m330 ppm107664
84-74-20036Dibutyl phthalate4000 mg/m3-84742
95-50-11066o-Dichlorobenzene1202 mg/m3200 ppm95501
106-46-70037p-Dichlorobenzene906 mg/m3150 ppm106467, carcinogenic substance
75-71-80048Dichlorodifluoromethane7425 mg/m315000 ppm75718
118-52-5-1,3-Dichloro-5,5-dimethylhydantoin5 mg/m3-118525
75-34-302491,1-Dichloroethane12150 mg/m33000 ppm75343
540-59-004361,2-Dichloroethylene3970 mg/m31000 ppm540590
111-44-40417Dichloroethyl ether585 mg/m3100 ppm111444, carcinogenic substance
75-43-41106Dichloromonofluoromethane21050 mg/m35000 ppm75434
594-72-90434Dichloronitroethane147.3 mg/m325 ppm594729
76-14-20649Dichlorotetrafluoroethane104850 mg/m315000 ppm76142
62-73-70872Dichlorvos100 mg/m3-62737
60-57-10787Dieldrin50 mg/m3-60571, carcinogenic substance
109-89-70444Diethylamine5980 mg/m3200 ppm109897
100-37-802572-Diethylaminoethanol479 mg/m3100 ppm100378
75-61-61419Difluorodibromomethane17160 mg/m32000 ppm75616
2238-07-50145Diglycidyl ether53.3 mg/m310 ppm2238075, carcinogenic substance
108-83-80713Diisobutyl ketone2910 mg/m3500 ppm108838
108-18-90449Diisopropylamine828 mg/m3200 ppm108189
127-19-50259Dimethyl acetamide1068 mg/m3300 ppm127195
124-40-31485Dimethylamine925 mg/m3500 ppm124403
121-69-70877N,N-Dimethylaniline4.96 mg/m3100 ppm121697
300-76-50925Naled200 mg/m3-300765
68-12-20457Dimethylformamide1495 mg/m3500 ppm68122
57-14-701471,1-Dimethylhydrazine371.5 mg/m315 ppm57147, carcinogenic substance
131-11-30261Dimethylphthalate2000 mg/m3-131113
77-78-10148Dimethyl sulfate36.1 mg/m37 ppm77781, carcinogenic substance
99-65-00691m-Dinitrobenzene50 mg/m3-528290
528-29-00460o-Dinitrobenzene50 mg/m3-528290
100-25-40692p-Dinitrobenzene50 mg/m3-528290
534-52-10462Dinitro-o-cresol5 mg/m3-534521
25321-14-60465Dinitrotoluene50 mg/m3-25321146, carcinogenic substance
117-81-70271Di-sec octyl phthalate5000 mg/m3-117817, carcinogenic substance
123-91-10041Dioxane1800 mg/m3500 ppm123911, carcinogenic substance
92-52-40106Diphenyl100 mg/m3-92524
34590-94-80884Dipropylene glycol methyl ether3636 mg/m3600 ppm34590948
72-20-81023Endrin2 mg/m3-72208
106-89-80043Epichlorohydrin283.5 mg/m375 ppm106898, carcinogenic substance
2104-64-50753EPN5 mg/m3-2104645
141-43-50152Ethanolamine75 mg/m330 ppm141435
110-80-500602-Ethoxyethanol1845 mg/m3500 ppm110805
111-15-903642-Ethoxyethyl acetate2705 mg/m3500 ppm111159
141-78-60367Ethyl acetate7200 mg/m32000 ppm141786 (10% Lower explosive limit LEL)
140-88-50267Ethyl acrylate1227 mg/m3500 ppm140885, carcinogenic substance
64-17-50044Ethyl alcohol6237 mg/m33300 ppm64175 (10% Lower explosive limit LEL)
75-04-71482Ethylamine1110 mg/m3600 ppm75047
100-41-40268Ethyl benzene3472 mg/m3800 ppm100414 (10% Lower explosive limit LEL)
74-96-41378Ethyl bromide8920 mg/m32000 ppm74964
106-35-40889Ethyl butyl ketone4670 mg/m31000 ppm106354
75-00-30132Ethyl chloride10032 mg/m33800 ppm75003 (10% Lower explosive limit LEL)
107-07-30236Ethylene chlorohydrin23 mg/m37 ppm107073
107-15-30269Ethylenediamine2460 mg/m31000 ppm107153
106-93-40045Ethylene dibromide769 mg/m3100 ppm106934, carcinogenic substance
107-06-20250Ethylene dichloride202.5 mg/m350 ppm107062, carcinogenic substance
628-96-61056Ethylene glycol dinitrate75 mg/m3-628966
151-56-40100Ethyleneimine176 mg/m3100 ppm151564, carcinogenic substance
75-21-80155Ethylene oxide1440 mg/m3800 ppmhtml, carcinogenic substance
60-29-70355Ethyl ether5757 mg/m31900 ppm60297 (10% Lower explosive limit LEL)
109-94-40623Ethyl formate4545 mg/m31500 ppm109944
75-08-10470Ethyl mercaptan1270 mg/m3500 ppm75081
100-74-30480N-Ethylmorpholine471 mg/m3100 ppm100743
78-10-40333Ethyl silicate5964 mg/m3700 ppm78104
14484-64-10792Ferbam800 mg/m3-14484641
12604-58-9-Ferrovanadium dust500 mg/m3-12604589
7782-41-40046Fluorine38.8 mg/m325 ppm7782414
75-69-40047Fluorotrichloromethane11240 mg/m32000 ppm75694
50-00-00695Formaldehyde24.6 mg/m320 ppm50000, carcinogenic substance
-0695Formalin24.6 mg/m320 ppm50000, carcinogenic substance
64-18-60485Formic acid56.4 mg/m330 ppm64186
98-01-10276Furfural393 mg/m3100 ppm98011
98-00-00794Furfuryl alcohol300.8 mg/m375 ppm98000
556-52-50159Glycidol454.5 mg/m3150 ppm556525
7782-42-50893Graphite (natural)1250 mg/m3-7782425
7440-58-60847Hafnium50 mg/m3-7440586
76-44-80743Heptachlor35 mg/m3-76448, carcinogenic substance
142-82-50657n-Heptane3075 mg/m3750 ppm142825
67-72-10051Hexachloroethane2904 mg/m3300 ppm67721, carcinogenic substance
1335-87-10997Hexachloronaphthalene2 mg/m3-1335871
110-54-30279n-Hexane3883 mg/m31100 ppm110543 (10% Lower explosive limit LEL)
591-78-604892-Hexanone6560 mg/m31600 ppm591786
108-10-10511Hexone2050 mg/m3500 ppm108101
108-84-91335sec-Hexyl acetate2950 mg/m3500 ppm108849
302-01-20281Hydrazine65.5 mg/m350 ppm302012, carcinogenic substance
10035-10-60282Hydrogen bromide99.3 mg/m330 ppm10035106
7647-01-00163Hydrogen chloride74.5 mg/m350 ppm7647010
74-90-80492Hydrogen cyanide55 mg/m350 ppm74908
7664-39-30283Hydrogen fluoride24.6 mg/m330 ppm7664393
7722-84-1-Hydrogen peroxide104 mg/m375 ppm772841
7783-07-50284Hydrogen selenide3.3 mg/m31 ppm7783075
7783-06-40165Hydrogen sulfide140 mg/m3100 ppm7783064
123-31-90166Hydroquinone50 mg/m3-123319
7553-56-20167Iodine20.76 mg/m32 ppm7553562
1309-37-11577Iron(III) oxide2500 mg/m3-1309371
123-92-20356Isoamyl acetate5330 mg/m31000 ppm123922
123-51-30798Isoamyl alcohol (primary)1805 mg/m3500 ppm123513
6032-29-7-Isoamyl alcohol (secondary)1805 mg/m3500 ppm123513
110-19-00494Isobutyl acetate6175 mg/m31300 ppm110190 (10% Lower explosive limit LEL)
78-83-10113Isobutyl alcohol4848 mg/m31600 ppm78831
78-59-10169Isophorone1130 mg/m3200 ppm78591
108-21-40907Isopropyl acetate7524 mg/m31800 ppm108214
67-63-00554Isopropyl alcohol4920 mg/m32000 ppm67630 (10% Lower explosive limit LEL)
75-31-00908Isopropylamine1815 mg/m3750 ppm75310
108-20-30906Isopropyl ether5852 mg/m31400 ppm108203 (10% Lower explosive limit LEL)
4016-14-20171Isopropyl glycidyl ether1900 mg/m3400 ppm4016142
463-51-40812Ketene8.6 mg/m35 ppm463514
7439-92-10052Lead100 mg/m3-7439921
58-89-90053Lindane50 mg/m3-58899
7580-67-80813Lithium hydride0.5 mg/m3-7580678
68476-85-7-L.P.G.3440–4740 mg/m32000 ppm68476857 (10% Lower explosive limit LEL)
1309-48-40504Magnesium oxide fume750 mg/m3-1309484
121-75-50172Malathion250 mg/m3-121755
108-31-60799Maleic anhydride10 mg/m3-108316
7439-96-50174Manganese500 mg/m3-7439965
7439-97-60056Mercury10 mg/m3-7439976
-1304Mercury (organo) alkyl compounds2 mg/m3-merc-hg
141-79-70814Mesityl oxide5628 mg/m31400 ppm141797 (10% Lower explosive limit LEL)
72-43-51306Methoxychlor5000 mg/m3-72435, carcinogenic substance
79-20-90507Methyl acetate9393 mg/m33100 ppm79209 (10% Lower explosive limit LEL)
74-99-70560Methyl acetylene2788 mg/m31700 ppm74997 (10% Lower explosive limit LEL)
59355-75-8-Methyl acetylene-propadiene mixture5576 mg/m33400 ppm59355758 (10% Lower explosive limit LEL)
96-33-30625Methyl acrylate880 mg/m3250 ppm96333
109-87-51152Methylal6842 mg/m32200 ppm109875 (10% Lower explosive limit LEL)
67-56-10057Methyl alcohol7860 mg/m36000 ppm67561
74-89-51483Methylamine127 mg/m3100 ppm74895
110-43-00920Methyl (n-amyl) ketone3736 mg/m3800 ppm110430
74-83-90109Methyl bromide972 mg/m3250 ppm74839, carcinogenic substance
109-86-40061Methyl Cellosolve622 mg/m3200 ppm109864
110-49-60476Methyl Cellosolve acetate966 mg/m3200 ppm110496
74-87-30419Methyl chloride4140 mg/m32000 ppm74873, carcinogenic substance
71-55-60079Methyl chloroform3822 mg/m3700 ppm71556
108-87-20923Methylcyclohexane4824 mg/m31200 ppm108872 (10% Lower explosive limit LEL)
25639-42-30292Methylcyclohexanol2335 mg/m3500 ppm25639423
583-60-8-2-Methylcyclohexanone2754 mg/m3600 ppm583608
101-68-80298Methylene bisphenyl isocyanate75 mg/m3-101688
75-09-20058Methylene chloride7981 mg/m32300 ppm75092, carcinogenic substance
107-31-30664Methyl formate11070 mg/m34500 ppm107313
541-85-513915-Methyl-3-heptanone524 mg/m3100 ppm541855
60-34-40180Methyl hydrazine37.8 mg/m320 ppm60344, carcinogenic substance
74-88-40509Methyl iodide580 mg/m3100 ppm74884, carcinogenic substance
108-11-20665Methyl isobutyl carbinol1672 mg/m3400 ppm108112
624-83-90004Methyl isocyanate7 mg/m33 ppm624839
74-93-10299Methyl mercaptan295.5 mg/m3150 ppm74931
80-62-60300Methyl methacrylate4090 mg/m31000 ppm80626
98-83-90732alpha-Methylstyrene3381 mg/m3700 ppm98839
12001-26-2-Mica1500 mg/m3-12001262
7439-98-71003Molybdenum5000 mg/m3-7439987
-1003Molybdenum, soluble compounds1000 mg/m3-moly-mo
100-61-80921Monomethyl aniline438 mg/m3100 ppm100618
110-91-80302Morpholine1400 mg/m34984 ppm110918 (10% Lower explosive limit LEL)
8030-30-6-Naphtha (coal tar)4500 mg/m31000 ppm8030306 (10% Lower explosive limit LEL)
91-20-30667Naphthalene1310 mg/m3250 ppm91203
13463-39-30064Nickel carbonyl14 mg/m32 ppm13463393, carcinogenic substance
7440-02-00062Nickel10 mg/m3-7440020, carcinogenic substance
54-11-50519Nicotine5 mg/m3-54115
7697-37-20183Nitric acid64.5 mg/m325 ppm7697372
10102-43-91311Nitric oxide123 mg/m3100 ppm10102439
100-01-60308p-Nitroaniline300 mg/m3-100016
98-95-30065Nitrobenzene1008 mg/m3200 ppm98953
100-00-50846p-Nitrochlorobenzene100 mg/m3-100005
79-24-30817Nitroethane3070 mg/m31000 ppm79243
10102-44-00930Nitrogen dioxide37.6 mg/m320 ppm10102440
7783-54-21234Nitrogen trifluoride2900 mg/m32000 ppm7783542
55-63-00186Nitroglycerine75 mg/m3-55630
75-52-50522Nitromethane1875 mg/m3750 ppm75525
108-03-210501-Nitropropane3640 mg/m31000 ppm108032
79-46-901872-Nitropropane354 mg/m3100 ppm79469, carcinogenic substance
99-08-11411m-Nitrotoluene1122 mg/m3200 ppm88722
88-72-20931o-Nitrotoluene1122 mg/m3200 ppm88722
99-99-00932p-Nitrotoluene1122 mg/m3200 ppm88722
2234-13-11059Octachloronaphthalene~1 mg/m3-2234131
111-65-90933Octane4670 mg/m31000 ppm111659 (10% Lower explosive limit LEL)
8012-95-1-Oil mist (mineral)2500 mg/m3-8012951
20816-12-00528Osmium tetroxide1 mg/m3-20816120
7783-41-70818Oxygen difluoride1 mg/m30.5 ppm7783417
10028-15-60068Ozone9.8 mg/m35 ppm10028156
1910-42-50005Paraquat1 mg/m3-1910425
56-38-20006Parathion10 mg/m3-56382
19624-22-70819Pentaborane2.6 mg/m31 ppm19624227
87-86-50069Pentachlorophenol2.5 mg/m3-87865
109-66-00534n-Pentane4425 mg/m31500 ppm109660 (10% Lower explosive limit LEL)
107-87-908162-Pentanone5280 mg/m31500 ppm107879
594-42-30311Perchloromethyl mercaptan10 mg/m376 ppm594423
7616-94-61114Perchloryl fluoride419 mg/m3100 ppm7616946
8002-05-9[1][permanent dead link]Petroleum distillates (naphtha)4455 mg/m31100 ppm8002059 (10% Lower explosive limit LEL)
108-95-20070Phenol962 mg/m3250 ppm108952
106-50-30805p-Phenylene diamine25 mg/m3-106503
101-84-80791Phenyl ether100 mg/m3696 ppm101848
122-60-10188Phenyl glycidyl ether614 mg/m3100 ppm122601, carcinogenic substance
100-63-00938Phenylhydrazine66.3 mg/m315 ppm100630, carcinogenic substance
7786-34-70924Phosdrin36.7 mg/m34 ppm7786347
75-44-50007Phosgene8.1 mg/m32 ppm75445
7803-51-20694Phosphine69.5 mg/m350 ppm7803512
7664-38-21008Phosphoric acid1000 mg/m3-7664382
7723-14-00628Phosphorus (yellow)5 mg/m3-7723140.html 7723140
10026-13-80544Phosphorus pentachloride70 mg/m3-10026138
1314-80-31407Phosphorus pentasulfide250 mg/m3-1314803
7719-12-20696Phosphorus trichloride140 mg/m325 ppm7719122
85-44-90315Phthalic anhydride60 mg/m3-85449
88-89-10316Picric acid75 mg/m3-88891
83-26-11515Pindone100 mg/m3-83261
--Platinum (soluble salts, as Pt)4 mg/m3-platinum
65997-15-11425Portland cement5000 mg/m3-65997151
151-50-80671Potassium cyanide25 mg/m3-cyanides
74-98-60319Propane3780 mg/m32100 ppm74986 (10% Lower explosive limit LEL)
109-60-40940n-Propyl acetate7106 mg/m31700 ppm109604
71-23-80553n-Propyl alcohol1968 mg/m3800 ppm71238
78-87-50441Propylene dichloride1848 mg/m3400 ppm78875, carcinogenic substance
75-55-80322Propylene imine234 mg/m3100 ppm75558, carcinogenic substance
75-56-90192Propylene oxide952 mg/m3400 ppm75569, carcinogenic substance
627-13-41513n-Propyl nitrate2150 mg/m3500 ppm627134
8003-34-71475Pyrethrum5000 mg/m3-8003347
110-86-10323Pyridine3240 mg/m31000 ppm110861
106-51-40779Quinone100 mg/m3-106514
7440-16-61247Rhodium (metal fume and insoluble compounds, as Rh)100 mg/m3-rhodium
--Rhodium (soluble compounds, as Rh)2 mg/m3-rhodium
299-84-30975Ronnel300 mg/m3-299843
83-79-40944Rotenone2500 mg/m3-83794
7782-49-20072Selenium1 mg/m3-7782492
7783-79-10947Selenium hexafluoride15.8 mg/m32 ppm7783791
7631-86-9-Silica, amorphous3000 mg/m3-7631869
14808-60-70808Silica, crystalline25/50 mg/m3-14808607, carcinogenic substance (25 mg/m3 – cristobalite, tridymite; 50 mg/m3 – crystalline silica)
7440-22-40810Silver10 mg/m3-7440224
--Soapstone (containing less than 1% quartz)3000 mg/m3-soapston
15096-52-31565Sodium aluminum fluoride250 mg/m3-fluoride
143-33-91118Sodium cyanide25 mg/m3-cyanides
7681-49-40951Sodium fluoride250 mg/m3-fluoride
62-74-80484Sodium fluoroacetate2.5 mg/m3-62748
1310-73-20360Sodium hydroxide10 mg/m3-1310732
7803-52-30776Stibine25.5 mg/m35 ppm7803523
8052-41-30361Stoddard solvent20 000 mg/m3-8052413
57-24-90197Strychnine3 mg/m3-57249
100-42-50073Styrene2982 mg/m3700 ppm100425
7446-09-50074Sulfur dioxide262 mg/m3100 ppm7446095
7664-93-90362Sulfuric acid15 mg/m3-7664939
10025-67-90958Sulfur monochloride27.6 mg/m35 ppm10025679
5714-22-7-Sulfur pentafluoride10.4 mg/m31 ppm5714227
2699-79-81402Sulfuryl fluoride836 mg/m3200 ppm2699798
93-76-500752,4,5-Trichlorophenoxyacetic acid250 mg/m3-93765
14807-96-60329Talc1000 mg/m3-14807966
7440-25-71596Tantalum2500 mg/m3-7440257
3689-24-50985TEDP10 mg/m3-3689245
13494-80-90986Tellurium25 mg/m3-13494809
7783-80-4-Tellurium hexafluoride9.9 mg/m31 ppm7783804
107-49-31158TEPP5 mg/m3-107493
92-06-8-m-Terphenyl500 mg/m3-26140603
84-15-11525o-Terphenyl500 mg/m3-26140603
92-94-4-p-Terphenyl500 mg/m3-26140603
76-11-914201,1,1,2-Tetrachloro-2,2-difluoroethane16680 mg/m32000 ppm76119
76-12-01421Freon 11216680 mg/m32000 ppm76120
79-34-503321,1,2,2-Tetrachloroethane687 mg/m3100 ppm79345, carcinogenic substance
127-18-40076Tetrachloroethylene1017 mg/m3150 ppm127184, carcinogenic substance
78-00-20008Tetraethyl lead40 mg/m3-78002
109-99-90578Tetrahydrofuran5900 mg/m32000 ppm109999 (10% Lower explosive limit LEL)
75-74-10200Tetramethyl lead40 mg/m3-75741
3333-52-61121Tetramethyl succinonitrile27.9 mg/m35 ppm3333526
509-14-81468Tetranitromethane32 mg/m34 ppm509148
479-45-80959Tetryl750 mg/m3-479458
--Thallium (soluble compounds)15 mg/m3-thallium
137-26-80757Thiram100 mg/m3-137268
7440-31-51535Tin100 mg/m3-7440315
--Tin (organic compounds)25 mg/m3-tin-org
13463-67-70338Titanium dioxide5000 mg/m3-13463677, carcinogenic substance
108-88-30078Toluene1885 mg/m3500 ppm108883
584-84-90339Toluene-2,4-diisocyanate17.8 mg/m32.5 ppm584849, carcinogenic substance
95-53-40341o-Toluidine219 mg/m350 ppm95534, carcinogenic substance
126-73-80584Tributyl phosphate327 mg/m330 ppm126738
79-00-500801,1,2-Trichloroethane546 mg/m3100 ppm79005, carcinogenic substance
79-01-60081Trichloroethylene5370 mg/m31000 ppm79016, carcinogenic substance
96-18-406831,2,3-Trichloropropane603 mg/m3100 ppm96184, carcinogenic substance
76-13-100501,1,2-Trichloro-1,2,2-trifluoroethane15340 mg/m32000 ppm76131
121-44-80203Triethylamine828 mg/m3200 ppm121448
75-63-80837Trifluorobromomethane243 600 mg/m340 000 ppm75638
118-96-709672,4,6-Trinitrotoluene500 mg/m3-118967
78-30-80961Triorthocresyl phosphate40 mg/m3-78308
115-86-61062Triphenyl phosphate1000 mg/m3-115866
8006-64-21063Turpentine4448 mg/m38000 ppm8006642
7440-61-11251Uranium (insoluble compounds)10 mg/m3-7440611, carcinogenic substance
--Uranium (soluble compounds)10 mg/m3-uranium, carcinogenic substance
7440-62-2-Vanadium dust35 mg/m3-vandust
1314-62-1-Vanadium fume35 mg/m3-vanfume
25013-15-40514Vinyl toluene1932 mg/m3400 ppm25013154
81-81-20821Warfarin100 mg/m3-81812
108-38-30085m-Xylene3906 mg/m3900 ppm95476
95-47-60084o-Xylene3906 mg/m3900 ppm95476
106-42-30086p-Xylene3906 mg/m3900 ppm95476
1300-73-80600Xylidine248 mg/m350 ppm1300738
7440-65-5-Yttrium500 mg/m3-7440655
7646-85-71064Zinc chloride fume50 mg/m3-7646857
1314-13-20208Zinc oxide500 mg/m3-1314132
7440-67-71405Zirconium compounds25 mg/m3-7440677
IDLH values for several gases and vapors(military)
NumberSubstanceIDLH valueSource
CASICSCmg/m3ppm
7782-50-50126Chlorine29 mg/m310 ppm7782505
100-44-70016Benzyl chloride (used in chemical weapons)[6]51.8 mg/m310 ppm100447
77-78-10148Dimethyl sulfate (used in chemical weapons)[7]36.1 mg/m37 ppm77781, carcinogenic substance
76-06-20750Chloropicrin13.44 mg/m32 ppm76062
75-44-50007Phosgene (used in chemical weapons)8.1 mg/m32 ppm75445
5714-22-7-Sulfur pentafluoride~10.4 mg/m31 ppm5714227
505-60-20418Sulfur mustard~4.7 mg/m30.7 ppm29750008
77-81-6-Tabun~0.7 mg/m30.1 ppmnerve
77-81-6-Sarin~0.6 mg/m30.1 ppmnerve
96-64-0-Soman (Zoman)~0.4 mg/m30.05 ppmnerve
329-99-7-Cyclosarin~0.4 mg/m30.05 ppmnerve
50782-69-9 51848-47-6 53800-40-1-VX~0.034 mg/m30.003 ppmnerve

See also

[edit]

References

[edit]
  1. ^ab"Immediately Dangerous To Life or Health (IDLH) Introduction". NIOSH. 4 December 2014.Archived from the original on 18 September 2017.
  2. ^"Occupational Safety and Health Standards". Occupational Safety & Health Administration.Archived from the original on 9 July 2012. Retrieved7 July 2012.
  3. ^ab"Chemical Listing and Documentation of Revised IDLH Values".NIOSH Publications and Products. Centers for Disease Control and Prevention.Archived from the original on 17 November 2012. Retrieved7 July 2012.
  4. ^Bollinger, Nancy; et al. (1987).NIOSH Respirator Selecion Logic. DHHS (NIOSH) Publication No. 87-108. Cincinnati, OH: National Institute for Occupational Safety and Health. p. 32.doi:10.26616/NIOSHPUB2005100.Archived from the original on 23 June 2017.
  5. ^"CDC - NIOSH Pocket Guide to Chemical Hazards (NPG) Introduction".www.cdc.gov. 2 December 2019.Archived from the original on 10 December 2017.
  6. ^"Benzyl Chloride | Technology Transfer Network Air Toxics Web site | US EPA". Archived fromthe original on 2014-07-12. Retrieved2014-08-17.
  7. ^"Dimethyl Sulfate | Technology Transfer Network Air Toxics Web site | US EPA". Archived fromthe original on 2012-05-11. Retrieved2012-05-03.

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