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High pressure

From Wikipedia, the free encyclopedia
Great force distributed over a small area
For the related geology term, seeUltrahigh-pressure metamorphism. For the meteorology term, seeHigh-pressure area. For the 1932 film, seeHigh Pressure (film). For the Red Garland album, seeHigh Pressure (Red Garland album).

Inscience andengineering, the study ofhigh pressure examines its effects on materials and the design and construction of devices, such as adiamond anvil cell, which can create highpressure.High pressure usually means pressures of thousands (kilobars) or millions (megabars) of timesatmospheric pressure (about 1bar or 100kilopascals).

History and overview

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Percy Williams Bridgman receiveda Nobel Prize in 1946 for advancing this area of physics by two magnitudes of pressure (400 megapascals (MPa) to 40 gigapascals (GPa)). The founders of this field include alsoHarry George Drickamer,Tracy Hall,Francis P. Bundy,Leonid F. Vereschagin [ru], andSergey M. Stishov [ru].

It was by applying high pressure as well as high temperature tocarbon thatsynthetic diamonds were first produced alongside many other interesting discoveries. Almost any material when subjected to high pressure will compact itself into a denser form; for example,quartz (also calledsilica orsilicon dioxide) will first adopt a denser form known ascoesite, then upon application of even higher pressure, formstishovite. These two forms of silica were first discovered by high-pressure experimenters, but then found in nature at the site of ameteor impact.

Chemical bonding is liable to change under high pressure, when theP * V term in the free energy becomes comparable to the energies of typical chemical bonds at around100 GPa. Among the most striking changes are metallization ofoxygen at 96 GPa (rendering oxygen asuperconductor), and transition ofsodium from a nearly-free-electron metal to a transparent insulator at ~200 GPa. At ultimately high compression, however, all materials will metallize (seemetallization pressure).‍[1]

High-pressure experimentation has led to the discovery of the types of minerals which are believed to exist in thedeep mantle of the Earth, such assilicate perovskite, which is thought to make up half of the Earth's bulk, andpost-perovskite, which occurs at thecore-mantle boundary and explains many anomalies inferred for that region.[citation needed]

Pressure "landmarks"

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See also

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References

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  1. ^Grochala, Wojciech; Hoffmann, Roald; Feng, Ji; Ashcroft, Neil W. (May 4, 2007). "The Chemical Imagination at Work in Very Tight Places".Angewandte Chemie International Edition [Applied Chemistry International Edition].46 (20).Wiley-VCH:3620–3642.doi:10.1002/anie.200602485.eISSN 1521-3773.ISSN 1433-7851.PMID 17477335.CODEN ACIEF5.
  2. ^Dubrovinskaia, Natalia; Dubrovinsky, Leonid; Solopova, Natalia A.; Abakumov, Artem; Turner, Stuart; Hanfland, Michael; Bykova, Elena; Bykov, Maxim; Prescher, Clemens; Prakapenka, Vitali B.; Petitgirard, Sylvain; Chuvashova, Irina; Gasharova, Biliana; Mathis, Yves-Laurent; Ershov, Petr; Snigireva, Irina; Snigirev, Anatoly (July 20, 2016)."Terapascal static pressure generation with ultrahigh yield strength nanodiamond".Science Advances.2 (7) e1600341.American Association for the Advancement of Science.Bibcode:2016SciA....2E0341D.doi:10.1126/sciadv.1600341.ISSN 2375-2548.LCCN 2014203143.OCLC 892343396.PMC 4956398.PMID 27453944.
  3. ^Jeanloz, Raymond; Celliers, Peter M.; Collins, Gilbert W.; Eggert, Jon H.; Lee, Kanani K. M.; McWilliams, R. Stewart; Brygoo, Stéphanie; Loubeyre, Paul (May 29, 2007)."Achieving high-density states through shock-wave loading of precompressed samples".Proceedings of the National Academy of Sciences.104 (22):9172–9177.Bibcode:2007PNAS..104.9172J.doi:10.1073/pnas.0608170104.eISSN 1091-6490.ISSN 0027-8424.JSTOR 00278424.LCCN 16010069.OCLC 43473694.PMC 1890466.PMID 17494771.CODEN PNASA6.

Further reading

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