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Giacinto Scoles | |
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| Born | (1935-04-02)2 April 1935 |
| Died | 25 September 2024(2024-09-25) (aged 89) Sassenheim, Netherlands |
| Education | University of Genoa |
| Scientific career | |
| Institutions | Leiden University University of Genoa University of Waterloo Princeton University International School for Advanced Studies Elettra Sincrotrone Trieste Temple University |
| Academic advisors | Jan Beenakker |
| Doctoral students | Brooks Pate |
Giacinto ScolesFRS (2 April 1935 – 24 September 2024) was an Italian-American chemist and physicist who was best known for his pioneering development of molecular beam methods for the study of weakvan der Waals forces between atoms, molecules, and surfaces. He developed the cryogenicbolometer as a universal detector of atomic and molecule beams that not only can detect a small flux of molecules, but also responds to the internal energy of the molecules. This is the basis for the optothermal spectroscopy technique which Scoles and others have used to obtain very high signal-to noise and high resolution ro-vibrational spectra.
Scoles was born inTurin, Italy, and was raised there throughout the Second World War. A few years after the war he moved, with his family, to Spain, where Scoles spent his adolescence. He returned to Italy and graduated theUniversity of Genoa in 1959 with a degree in Chemistry. His publication record started with “Vapour Pressure of Isotopic Liquids I” published 1959 in Il Nuovo Cimento. Starting his interdisciplinary research between chemistry and physics, in 1960 he was appointed Assistant Professorship in the Physics Department of the University of Genoa where he taught a lab course and conducted experiments onisotope separation during physical adsorption (physisorption).
In 1961, he changed research area and joinedJan Beenakker’s group at the Kamerlingh-Onnes Laboratorium ofLeiden University in the Netherlands. There he co-authored one of the first papers on what became soon known as theSenftleben-Beenakker effect:[citation needed] the influence of an external magnetic or electric field on the transport properties of dilute polyatomic gases.[1] The idea behind this effect is that every polyatomic molecule – even a simpleparamagnetic one like N2 – has amagnetic moment, due to its end-over-end rotation, which can be used as a handle to make it precess in an externalmagnetic field. If the precession frequency is sufficiently large compared to thecollision frequency, the average kineticcross section will change, and so will the transport properties. Likewise, for polar molecules one may employelectric fields to achieve the desired precession. This field has yielded a wealth of information on the non-spherical part (i.e. the angle dependence) of the intermolecular potential. In addition, several new phenomena were later discovered that had been believed to be non-existing in neutral gases, like transverse transport effects in a magnetic field, comparable to theHall effect in electrical conduction.
In 1964, Scoles returned to theUniversity of Genoa as Assistant Professor of Physics. In Genoa he stayed until 1971 and in those years established a renowned molecular beams laboratory devoted to the investigation of intermolecular forces in gases. Most significant was the development of the cryogenic bolometer to detect molecular beams. Bolometers detect tiny heat input (with noise on the order of 10−14watts persquare roothertz) and had previously been developed as detectors of Infrared Radiation but here they are used to measure the internal and translational energy of a beam of atoms or molecules. The test apparatus set up together with M. Cavallini and G. Gallinaro[2] offered great advantages with respect to conventional techniques used at that time and reduced the cost of building beam machines.[citation needed] Scoles and his colleagues published a series of key papers which include the determination of the energy dependence of the integral collision cross section of He scattered by He, the observation of “Rainbow Scattering“ between two crossed beams of Argon,[3] the first measurement of orbiting resonances in the scattering between two atoms (Hg and H).[4]
In 1971, Scoles moved to theUniversity of Waterloo, Canada as Professor of Chemistry and Physics. There, he set up the first successfulcrossed molecular beam laboratory in Canada. He help establish the WaterlooCentre for Molecular Beams and Laser Chemistry, theCentre for Surface Science in Technology, as well as the weekly chemical physics seminars and annual Symposium on Chemical Physics, both of which continue to this day. He was the initial (Acting) Director of theGuelph-Waterloo Centre for Graduate Work in Chemistry, the first true inter-university graduate program in Canada. Scoles performed crossed beam differential scattering cross-section studies of atom-atom, atom-molecule and molecule-molecule interactions,[5] using his bolometer detector. He also began using helium atom diffraction to study the structure of surfaces, both of pure crystals which often undergo change from the bulk structure (reconstruction) and also the structure ofoverlayers of atoms and molecules absorbed on surfaces. With Terry Gough and then graduate student Roger Miller, Scoles introduced the technique of bolometer-detected optothermal spectroscopy of molecular beams where vibrational excitation of a beam of molecules is detected by the bolometer. They used this technique to studies vibrational dissociation of a complex of two or more molecules held together by Van der Waals forces. By the early 1980s, Scoles began the first studies of the spectroscopy of molecules adsorbed in or on clusters of rare gas atoms.
In the mid-to-late 1970s Scoles spent part of his time at theUniversity of Trento, Italy where he established a new molecular beam laboratory. The activity of the Trento lab was mainly focused on opto-thermal spectroscopy and atomic hydrogen scattering experiments.
Scoles moved toPrinceton University in 1986. One of the experiments that Scoles brought to Princeton was the study of IR spectroscopy of molecules attached to inert gas clusters, particularly Ar and Xe clusters. In this work, he developed the now widely used “pickup technique”[6] and set the stage for his later pioneering work onsuperfluid helium nanodroplets, for which he recently shared theBenjamin Franklin Award in Physics. The helium experiments, started with students S. Goyal and D. Schutt, provided the first molecular spectra of solutes in liquid helium, a unique superfluid solvent.[7] Frank Stienkemeier joined the group as a postdoc and together with graduate students John Higgins and Carlo Callegari (and sabbatical visitor Wolfgang Ernst) established the “Alkali age” of the group which provided a rich vein to explore chemical dynamics in this fascinating state of matter.[8] Graduate student James Reho brought time resolved spectroscopy techniques into the mix.[9]Erik Kerstel did a thesis on subdoppler spectroscopy of hydrogen bonded complexes, including the first such spectra in the vibrational overtone region.[10]Brooks Pate brought Scoles andKevin K. Lehmann together for what proved to be a long series of experiments (and many Ph.D. theses) that characterized Intramolecular Vibrational energy Redistribution. They first studied the hydrogen stretching fundamental and first overtone spectral regions and observedLorentzian lineshapes due to irreversible relaxation for large molecules with a very highdensity of states.[11] They developed IR-microwave and later IR-IR double resonance methods to provide unambiguous quantum assignments of even highly congested spectra and to reach higher in energy.[12] The work by Andrea Callegari on benzene, long a model system for such studies is noted among many such studies. After this work, Carlo Callegari converted the apparatus into a helium droplet machine, which was used for the first study of overtone vibrational transitions in helium nanodroplets. Also, the pure rotational spectra ofHCCCN andHCN in helium were observed.[13] This established that a single droplet could absorb several thousand photons without "optically pumping" out of resonance.[citation needed]
Scoles was instrumental in the establishment of the Princeton Materials Institute and became a close collaborator of Peter Eisenberger, its first director. Scoles also brought to Princeton his Helium Diffraction Spectrometer for the study of surface structure.[14] His focus turned from inorganic overlayers to the study of self-assembled monolayers, particularly alkane thiols on Au(111).[15] Scoles collaborated with Eisenberger in using X-Rays as a complementary surface structure tool and showed the power of the combination of the two methods. Scoles developed expertise in atomic force microscopy (AFM) to study surface structure and more recently, tip induced surface modification using the nanografting technique [16,17] which had been previously developed by his former student Gang Yu Liu. In collaboration with Steve Bernasek, Scoles has also studied the influence of vibrational excitation (again for the first time in the first C-H overtone region) on the sticking probability of a molecule (methane) on a metal surface.[16]
Starting in 2003, Scoles returned part-time to Italy, taking appointments at the Trieste SynchrotronElettra and the International School for Advanced Studies (SISSA), In SISSA he joined the Condensed Matter group where he began collaborating on theoretical problems dealing with helium nanodroplets and with physisorption. At the same time, he started an experimental group in Elettra, focusing on nanoscience, with particular attention to self-assembled monolayers and their properties [19,20]. Later, Scoles expanded his research into nanoscale biological processes, biophysics, and nanomedicine, in connection with the local Consortium of Molecular Biomedicine.
Scoles died inSassenheim, Netherlands on 24 September 2024, at the age of 89.[17][18]
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