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Standard atomic weightAr°(Gd) | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Naturally occurringgadolinium (64Gd) is composed of 6 stableisotopes,154Gd,155Gd,156Gd,157Gd,158Gd and160Gd, and 1radioisotope,152Gd, with158Gd being the most abundant (24.84%natural abundance). The predicteddouble beta decay of160Gd hasnever been observed; only a lower limit on itshalf-life of more than 1.3×1021 years has been set experimentally.[5]
Thirty-three radioisotopes have been characterized, with the most stable being alpha-decaying152Gd (naturally occurring) with a half-life of 1.08×1014 years, and150Gd with a half-life of 1.79×106 years. All of the remaining radioactive isotopes have half-lives less than 100 years, the majority of these having half-lives less than 24.6 seconds. Gadolinium isotopes have 10 metastableisomers, with the most stable being143mGd (t1/2 = 110 seconds),145mGd (t1/2 = 85 seconds) and141mGd (t1/2 = 24.5 seconds).
The primarydecay mode at atomic weights lower than the most abundant stable isotope,158Gd, iselectron capture, and the primary mode at higher atomic weights isbeta decay. The primarydecay products for isotopes lighter than158Gd areisotopes of europium and the primary products of heavier isotopes areisotopes of terbium.
Nuclide [n 1] | Z | N | Isotopic mass(Da)[6] [n 2][n 3] | Half-life[1] [n 4][n 5] | Decay mode[1] [n 6] | Daughter isotope [n 7][n 8] | Spin and parity[1] [n 9][n 5] | Natural abundance(mole fraction) | |||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Excitation energy[n 5] | Normal proportion[1] | Range of variation | |||||||||||||||||
135Gd | 64 | 71 | 134.95250(43)# | 1.1(2) s | β+ (98%) | 135Eu | (5/2+) | ||||||||||||
β+,p (98%) | 134Sm | ||||||||||||||||||
136Gd | 64 | 72 | 135.94730(32)# | 1# s [>200 ns] | β+? | 136Eu | 0+ | ||||||||||||
β+, p? | 135Sm | ||||||||||||||||||
137Gd | 64 | 73 | 136.94502(32)# | 2.2(2) s | β+ | 137Eu | (7/2)+# | ||||||||||||
β+,p? | 136Sm | ||||||||||||||||||
138Gd | 64 | 74 | 137.94025(22)# | 4.7(9) s | β+ | 138Eu | 0+ | ||||||||||||
138mGd | 2232.6(11) keV | 6.2(0.2) μs | IT | 138Gd | (8−) | ||||||||||||||
139Gd | 64 | 75 | 138.93813(21)# | 5.7(3) s | β+ | 139Eu | 9/2−# | ||||||||||||
β+, p? | 138Sm | ||||||||||||||||||
139mGd[n 10] | 250(150)# keV | 4.8(9) s | β+ | 139Eu | 1/2+# | ||||||||||||||
β+, p? | 138Sm | ||||||||||||||||||
140Gd | 64 | 76 | 139.933674(30) | 15.8(4) s | β+ (67(8)%) | 140Eu | 0+ | ||||||||||||
EC (33(8)%) | |||||||||||||||||||
141Gd | 64 | 77 | 140.932126(21) | 14(4) s | β+ (99.97%) | 141Eu | (1/2+) | ||||||||||||
β+, p (0.03%) | 140Sm | ||||||||||||||||||
141mGd | 377.76(9) keV | 24.5(5) s | β+ (89%) | 141Eu | (11/2−) | ||||||||||||||
IT (11%) | 141Gd | ||||||||||||||||||
142Gd | 64 | 78 | 141.928116(30) | 70.2(6) s | EC (52(5)%) | 142Eu | 0+ | ||||||||||||
β+ (48(5)%) | |||||||||||||||||||
143Gd | 64 | 79 | 142.92675(22) | 39(2) s | β+ | 143Eu | 1/2+ | ||||||||||||
β+, p? | 142Sm | ||||||||||||||||||
β+,α? | 139Pm | ||||||||||||||||||
143mGd | 152.6(5) keV | 110.0(14) s | β+ | 143Eu | 11/2− | ||||||||||||||
β+, p? | 142Sm | ||||||||||||||||||
β+,α? | 139Pm | ||||||||||||||||||
144Gd | 64 | 80 | 143.922963(30) | 4.47(6) min | β+ | 144Eu | 0+ | ||||||||||||
144mGd | 3433.1(5) keV | 145(30) ns | IT | 144Gd | (10+) | ||||||||||||||
145Gd | 64 | 81 | 144.921710(21) | 23.0(4) min | β+ | 145Eu | 1/2+ | ||||||||||||
145mGd | 749.1(2) keV | 85(3) s | IT (94.3%) | 145Gd | 11/2− | ||||||||||||||
β+ (5.7%) | 145Eu | ||||||||||||||||||
146Gd | 64 | 82 | 145.9183185(44) | 48.27(10) d | EC | 146Eu | 0+ | ||||||||||||
147Gd | 64 | 83 | 146.9191010(20) | 38.06(12) h | β+ | 147Eu | 7/2− | ||||||||||||
147mGd | 8587.8(5) keV | 510(20) ns | IT | 147Gd | 49/2+ | ||||||||||||||
148Gd | 64 | 84 | 147.9181214(16) | 86.9(39) y[2] | α[n 11] | 144Sm | 0+ | ||||||||||||
149Gd | 64 | 85 | 148.9193477(36) | 9.28(10) d | β+ | 149Eu | 7/2− | ||||||||||||
α (4.3×10−4%) | 145Sm | ||||||||||||||||||
150Gd | 64 | 86 | 149.9186639(65) | 1.79(8)×106 y | α[n 12] | 146Sm | 0+ | ||||||||||||
151Gd | 64 | 87 | 150.9203549(32) | 123.9(10) d | EC | 151Eu | 7/2− | ||||||||||||
α (1.1×10−6%) | 147Sm | ||||||||||||||||||
152Gd[n 13] | 64 | 88 | 151.9197984(11) | 1.08(8)×1014 y | α[n 14] | 148Sm | 0+ | 0.0020(1) | |||||||||||
153Gd | 64 | 89 | 152.9217569(11) | 240.6(7) d | EC | 153Eu | 3/2− | ||||||||||||
153m1Gd | 95.1737(8) keV | 3.5(4) μs | IT | 153Gd | 9/2+ | ||||||||||||||
153m2Gd | 171.188(4) keV | 76.0(14) μs | IT | 153Gd | (11/2−) | ||||||||||||||
154Gd | 64 | 90 | 153.9208730(11) | Observationally Stable[n 15] | 0+ | 0.0218(2) | |||||||||||||
155Gd[n 16] | 64 | 91 | 154.9226294(11) | Observationally Stable[n 17] | 3/2− | 0.1480(9) | |||||||||||||
155mGd | 121.10(19) keV | 31.97(27) ms | IT | 155Gd | 11/2− | ||||||||||||||
156Gd[n 16] | 64 | 92 | 155.9221301(11) | Stable | 0+ | 0.2047(3) | |||||||||||||
156mGd | 2137.60(5) keV | 1.3(1) μs | IT | 156Gd | 7- | ||||||||||||||
157Gd[n 16] | 64 | 93 | 156.9239674(10) | Stable | 3/2− | 0.1565(4) | |||||||||||||
157m1Gd | 63.916(5) keV | 460(40) ns | IT | 157Gd | 5/2+ | ||||||||||||||
157m2Gd | 426.539(23) keV | 18.5(23) μs | IT | 157Gd | 11/2− | ||||||||||||||
158Gd[n 16] | 64 | 94 | 157.9241112(10) | Stable | 0+ | 0.2484(8) | |||||||||||||
159Gd[n 16] | 64 | 95 | 158.9263958(11) | 18.479(4) h | β− | 159Tb | 3/2− | ||||||||||||
160Gd[n 16] | 64 | 96 | 159.9270612(12) | Observationally Stable[n 18] | 0+ | 0.2186(3) | |||||||||||||
161Gd | 64 | 97 | 160.9296763(16) | 3.646(3) min | β− | 161Tb | 5/2− | ||||||||||||
162Gd | 64 | 98 | 161.9309918(43) | 8.4(2) min | β− | 162Tb | 0+ | ||||||||||||
163Gd | 64 | 99 | 162.93409664(86) | 68(3) s | β− | 163Tb | 7/2+ | ||||||||||||
163mGd | 138.22(20) keV | 23.5(10) s | IT? | 163Gd | 1/2− | ||||||||||||||
β− | 163Tb | ||||||||||||||||||
164Gd | 64 | 100 | 163.9359162(11) | 45(3) s | β− | 164Tb | 0+ | ||||||||||||
164mGd | 1095.8(4) keV | 589(18) ns | IT | 164Gd | (4−) | ||||||||||||||
165Gd | 64 | 101 | 164.9393171(14) | 11.6(10) s | β− | 165Tb | 1/2−# | ||||||||||||
166Gd | 64 | 102 | 165.9416304(17) | 5.1(8) s | β− | 166Tb | 0+ | ||||||||||||
166mGd | 1601.5(11) keV | 950(60) ns | IT | 166Gd | (6−) | ||||||||||||||
167Gd | 64 | 103 | 166.9454900(56) | 4.2(3) s | β− | 167Tb | 5/2−# | ||||||||||||
168Gd | 64 | 104 | 167.94831(32)# | 3.03(16) s | β− | 168Tb | 0+ | ||||||||||||
169Gd | 64 | 105 | 168.95288(43)# | 750(210) ms | β− | 169Tb | 7/2−# | ||||||||||||
β−, n? (<0.7%)[7] | 168Tb | ||||||||||||||||||
170Gd | 64 | 106 | 169.95615(54)# | 675+94 −75 ms[7] | β− | 170Tb | 0+ | ||||||||||||
β−, n? (<3%)[7] | 169Tb | ||||||||||||||||||
171Gd | 64 | 107 | 170.96113(54)# | 392+145 −136 ms[7] | β− | 171Tb | 9/2+# | ||||||||||||
β−, n? (<10%)[7] | 170Tb | ||||||||||||||||||
172Gd | 64 | 108 | 171.96461(32)# | 163+113 −99 ms[7] | β− | 172Tb | 0+# | ||||||||||||
β−, n? (<50%)[7] | 171Tb | ||||||||||||||||||
This table header & footer: |
EC: | Electron capture |
IT: | Isomeric transition |
With a half-life of86.9±3.9 year via alpha decay alone,[2] gadolinium-148 would be ideal forradioisotope thermoelectric generators. However, gadolinium-148 cannot be economically synthesized in sufficient quantities to power a RTG.[8]
Gadolinium-153 has a half-life of240.4±10 d and emits gamma radiation with strong peaks at 41keV and 102 keV. It is used as a gamma ray source forX-ray absorptiometry and fluorescence, for bone density gauges forosteoporosis screening, and for radiometric profiling in the Lixiscope portable x-ray imaging system, also known as the Lixi Profiler. Innuclear medicine, it serves to calibrate the equipment needed likesingle-photon emission computed tomography systems (SPECT) to makex-rays. It ensures that the machines work correctly to produce images of radioisotope distribution inside the patient. This isotope is produced in a nuclear reactor fromeuropium orenriched gadolinium.[9] It can also detect the loss ofcalcium in the hip and back bones, allowing the ability to diagnose osteoporosis.[10]