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Gadolinium(III) nitrate

From Wikipedia, the free encyclopedia
Gadolinium(III) nitrate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.030.385Edit this at Wikidata
  • InChI=1S/Gd.3NO3/c;3*2-1(3)4/q+3;3*-1 checkY
    Key: MWFSXYMZCVAQCC-UHFFFAOYSA-N checkY
  • InChI=1/Gd.3NO3/c;3*2-1(3)4/q+3;3*-1
    Key: MWFSXYMZCVAQCC-UHFFFAOYAX
  • [Gd+3].O=[N+]([O-])[O-].[O-][N+]([O-])=O.[O-][N+]([O-])=O
Properties
Gd(NO3)3
Molar mass343.26 g/mol
AppearanceWhite crystalline solid
Density2.3 g/cm3
Melting point91 °C (196 °F; 364 K)
Soluble
Hazards
Safety data sheet (SDS)External MSDS
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Chemical compound

Gadolinium(III) nitrate is an inorganic compound ofgadolinium. This salt is used as a water-solubleneutron poison innuclear reactors.[1] Gadolinium nitrate, like all nitrate salts, is anoxidizing agent.

The most common form of this substance is hexahydrate Gd(NO3)3•6H2O with molecular weight 451.36 g/mol and CAS Number: 19598-90-4.[1]

Use

[edit]

Gadolinium nitrate was used at theSavannah River Site heavy water nuclear reactors and had to be separated from the heavy water for storage or reuse.[2][3]The CanadianCANDU reactor, a pressurized heavy water reactor, also uses gadolinium nitrate as a water-soluble neutron poison inheavy water.

Gadolinium nitrate is also used as a raw material in the production of other gadolinium compounds, for production of specialty glasses and ceramics and as aphosphor.

References

[edit]
  1. ^DOE Fundamentals Handbook: Nuclear Physics and Reactor Theory(PDF).U.S. Department of Energy. January 1993. p. 31. Archived fromthe original(PDF) on 2008-04-23. Retrieved2007-09-26.
  2. ^E. Wilde; C. Berry."Novel Method for Removing Gadolinium from Used Heavy Water Reactor Moderator".
  3. ^E.W. Wilde; M.B. Goli; C.J. Berry; J.W. Santo Domingo; H.L. Martin."Novel Method for Removing Gadolinium from Used Heavy Water Reactor Moderator"(PDF).
Salts and covalent derivatives of thenitrate ion
HNO3He
LiNO3Be(NO3)2B(NO3)4RONO2
+CO3
+C2O4
NO3
NH4NO3
HOONO2FNO3
+F
Ne
NaNO3Mg(NO3)2Al(NO3)3
Al(NO3)4
SiP+SO4ClONO2
+Cl
Ar
KNO3Ca(NO3)2Sc(NO3)3Ti(NO3)4VO(NO3)3Cr(NO3)3Mn(NO3)2Fe(NO3)2
Fe(NO3)3
Co(NO3)2
Co(NO3)3
Ni(NO3)2CuNO3
Cu(NO3)2
Zn(NO3)2Ga(NO3)3GeAs+SeO3BrNO3
+Br
Kr
RbNO3Sr(NO3)2Y(NO3)3Zr(NO3)4NbO(NO3)3MoO2(NO3)2TcRu(NO3)3Rh(NO3)3Pd(NO3)2AgNO3Cd(NO3)2In(NO3)3Sn(NO3)4Sb4O4(OH)2(NO3)2TeINO3
+IO3
Xe(NO3)2
CsNO3Ba(NO3)2*Lu(NO3)3Hf(NO3)4TaO(NO3)3WO2(NO3)2ReO3NO3OsIr3O(NO3)10Pt(NO3)2
Pt(NO3)4
Au(NO3)4Hg2(NO3)2
Hg(NO3)2
TlNO3
Tl(NO3)3
Pb(NO3)2Bi(NO3)3
BiO(NO3)
Po(NO3)4AtRn
FrNO3Ra(NO3)2**LrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
 
*La(NO3)3Ce(NO3)3
Ce(NO3)4
Pr(NO3)3Nd(NO3)3Pm(NO3)3Sm(NO3)3Eu(NO3)3Gd(NO3)3Tb(NO3)3Dy(NO3)3Ho(NO3)3Er(NO3)3Tm(NO3)3Yb(NO3)3
**Ac(NO3)3Th(NO3)4PaO(NO3)3U(NO3)4
UO2(NO3)2
Np(NO3)4
NpO(NO3)3
NpO2NO3
NpO2(NO3)2
Pu(NO3)3
Pu(NO3)4
PuO2(NO3)2
Am(NO3)3
AmO2(NO3)2
Cm(NO3)3Bk(NO3)3Cf(NO3)3Es(NO3)3FmMdNo
Gadolinium(III)
Organogadolinium(III)
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