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Formaldoxime

From Wikipedia, the free encyclopedia
Formaldoxime
Names
Preferred IUPAC name
N-Hydroxymethanimine
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.000.769Edit this at Wikidata
EC Number
  • 200-845-7
UNII
  • InChI=1S/CH3NO/c1-2-3/h3H,1H2
    Key: SQDFHQJTAWCFIB-UHFFFAOYSA-N
  • C=NO
Properties
H2C=N−OH
Molar mass45.041 g·mol−1
Appearancecolorless liquid
Melting point2.5 °C (36.5 °F; 275.6 K)
Boiling point84 °C (183 °F; 357 K)
Hazards
GHS labelling:
GHS07: Exclamation mark
Warning
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Formaldoxime is theorganic compound with the formulaH2C=N−OH. It is theoxime offormaldehyde. A colorless liquid, the pure compound tends topolymerize into a cyclictrimer. Aqueous solutions are stable as is the formaldoxime hydrochloride ([H2C=N(−H)(−OH)]+Cl). It is a reagent inorganic synthesis for the conversion of aryldiazonium salts to arylaldehydes.[1]

It is generated by combininghydroxylamine and formaldehyde.[2]

Synonyms

[edit]

Source:[3]

  • Formoxime
  • Nitrone
  • Formaldehyde oxime
  • formaldoxim
  • methylenenitrone

References

[edit]
  1. ^De Kimpe, Norbert (2001). "Formaldoxime".E-EROS Encyclopedia of Reagents for Organic Synthesis.doi:10.1002/047084289X.rf023.ISBN 0-471-93623-5.
  2. ^S. D. Jolad, S. Rajagopalan (1966). "2-Bromo-4-methylbenzaldehyde".Org. Synth.46: 13.doi:10.15227/orgsyn.046.0013.
  3. ^https://pubchem.ncbi.nlm.nih.gov/compound/Formaldoxime#section=Depositor-Supplied-Synonyms&fullscreen=true
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