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Florencite-(Sm)

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Mineral of the plumbogummite group
Florencite-(Sm)
General
CategoryPhosphate mineral
FormulaSmAl3(PO4)2(OH)6
IMA symbolFlo-Sm[1]
Crystal systemTrigonal
Crystal classHexagonal scalenohedral (3m)
H-M symbol: (3 2/m)
Space groupR3m
Unit cella = 6.972, c = 16.182 [Å]; Z = 3
Identification
ColorColorless, pale pink, pale yellow
Crystal habitSub-mm zones in florencite-(Ce) crystals
Cleavage{0001}, distinct
FractureUneven
Mohs scale hardness5.5-6
LusterVitreous to greasy
StreakWhite
Density3.6 (measured)
Optical propertiesUniaxal(+)
Refractive indexnω=1.70, nε=1.71
References[2][3][4]

Florencite-(Sm) is a very rare mineral of theplumbogummite group (alunite supergroup) with simplified formula SmAl3(PO4)2(OH)6.[4]Samarium in florencite-(Sm) is substituted by otherrare earth elements, mostlyneodymium. It does not form separate crystals, but is found as zones in florencite-(Ce),[2] which iscerium-dominant member of the plumbogummite group.[5] Florencite-(Sm) is also a samarium-analogue of florencite-(La) (lanthanum-dominant) and waylandite (bismuth-dominant), both being aluminium-rich minerals.[4]

Occurrence and association

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Florencite-(Sm) was revealed in quartz veins in theMaldynyrd Range,Subpolar Urals, Russia. It associates withxenotime-(Y).[2]

Notes on chemistry

[edit]

Florencite-(Sm) has admixtures ofneodymium, and small amounts ofcerium,gadolinium,sulfur,strontium,praseodymium,calcium,lanthanum,europium, andsilicon.[2]

References

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  1. ^Warr, L.N. (2021)."IMA–CNMNC approved mineral symbols".Mineralogical Magazine.85 (3):291–320.Bibcode:2021MinM...85..291W.doi:10.1180/mgm.2021.43.S2CID 235729616.
  2. ^abcdRepina, S.A., Popova, V.I., Churin, E.I., Belogub, E.V., and Khiller, V.V., 2014. Florencite-(Sm)—(Sm,Nd)Al3(PO4)2(OH)6: A new mineral species of the alunite-jarosite group from the Subpolar Urals. Geology of Ore Deposits 53(7), 564-574
  3. ^"Florencite-(Sm) - Handbook of Mineralogy"(PDF).Handbookofmineralogy.org. Retrieved2016-03-08.
  4. ^abc"Florencite-(Sm): Florencite-(Sm) mineral information and data".Mindat.org. Retrieved2016-03-04.
  5. ^"Florencite-(Ce): Florencite-(Ce) mineral information and data".Mindat.org. Retrieved2016-03-09.l
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