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Even and odd atomic nuclei

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Nuclear physics
Nuclides' classification

Innuclear physics, properties of anucleus depend onevenness or oddness of itsatomic number (proton number)Z,neutron numberN and, consequently, of their sum, themass numberA. Most importantly, oddness of bothZ andN tends to lower thenuclear binding energy, making odd nuclei generally less stable. This effect is not only experimentally observed, but is included in thesemi-empirical mass formula and explained by some othernuclear models, such as thenuclear shell model. This difference of nuclear binding energy between neighbouring nuclei, especially of odd-Aisobars, has important consequences forbeta decay.

Thenuclear spin is zero for even-Z, even-N nuclei, integer for all even-A nuclei, and odd half-integer for all odd-A nuclei.

Even vs. odd mass number (A).
EvenOddTotal
Stable150101251
Long-lived27835
Allprimordial177109286

Theneutron–proton ratio is not the only factor affecting nuclear stability. Adding neutrons to isotopes can vary their nuclear spins and nuclear shapes, causing differences inneutron capturecross sections andgamma spectroscopy andnuclear magnetic resonance properties. If too many or too few neutrons are present with regard to thenuclear binding energy optimum, the nucleus becomes unstable and subject to certain types ofnuclear decay. Unstable nuclides with a nonoptimal number of neutrons or protons decay bybeta decay (including positron decay),electron capture, or other means, such asspontaneous fission andcluster decay.

Data on specific nuclides below is from NUBASE2020[1] unless otherwise stated. See alsoList of nuclides for a complete enumeration.

Even mass number

[edit]

Even-mass-number nuclides, which comprise 150/251 = ~60% of all stable nuclides, arebosons, i.e., they have integerspin. 145 of the 150 are even-proton, even-neutron (EE) nuclides, which necessarily have spin 0 because of pairing. The remainder of the stable bosonic nuclides are five odd-proton, odd-neutron stable nuclides (2
1
H
,6
3
Li
,10
5
B
,14
7
N
and180m
73
Ta
), all having a non-zero integer spin.

Pairing effects

[edit]
Even/oddZ,N (Hydrogen-1is OE)
p,nEEOOEOOETotal
Stable14555348251
Long-lived2343535
All primordial16895653286

Beta decay of aneven–even nucleus produces an odd–odd nucleus, and vice versa. An even number of protons or of neutrons are more stable (higherbinding energy) because ofpairing effects, so even–even nuclei are much more stable than odd–odd. One effect is that there are few stable odd–odd nuclides, but another effect is to prevent beta decay of many even–even nuclei into another even–even nucleus of the same mass number but lower energy, because decay proceeding one step at a time would have to pass through an odd–odd nucleus of higher energy.Double beta decay directly from even–even to even–even skipping over an odd–odd nuclide is only occasionally possible, and even then with ahalf-life more than a billion times theage of the universe. For example, the double beta emitter116
Cd
has a half-life of2.69×1019 years. This makes for a larger number of stable even–even nuclides, withsome mass numbers having two stable nuclides, and some elements (atomic numbers) having as many asseven.

For example, the extreme stability of helium-4 due to the double pairing (two protons, two neutrons, filling the lowestshell) prevents any nuclides containing five or eight nucleons from existing for long enough to serve as platforms for the buildup of heavier elements vianuclear fusion inBig Bang nucleosynthesis; only in stars is there enough time for this (seetriple-alpha process). This is also the reason why8
4
Be
decays so quickly into twoalpha particles, makingberyllium the only even-numbered element that ismonoisotopic.

Even-even (even proton, even neutron)

[edit]

There are 145 stable even–even nuclides, forming ~58% of the 251 stable nuclides. There are also 23 primordial even–even nuclides currently known to be radioactive. As a result, many of the 41 even-numbered elements from 2 to 82 havemany primordial isotopes. With 145 isotopes, they average 145/41 ~ 3.54 stable isotopes each. The lightest stable even-even isotope is4
2
He
and the heaviest is208
82
Pb
. These are also the lightest and heaviest knowndoubly magic nuclides.[2]208
82
Pb
is the final decay product of232
90
Th
, a primordial radionuclide with an even proton and neutron number.238
92
U
is another such primordial radionuclide with a half-life of 4.463 billion years; these two, with their decay products, each produce nearly half theradioactive heat within the Earth.[3]

All even–even nuclides havespin 0 in their ground state, due to thePauli exclusion principle (See thepairing effect for more details).

Odd-odd (odd proton, odd neutron)

[edit]

Only five stable nuclides contain both an odd number of protons and an odd number of neutrons. The first four "odd–odd" nuclides occur in light elements, for which changing a proton to a neutron or vice versa would lead to a very lopsided proton–neutron ratio (2
1
H
,6
3
Li
,10
5
B
, and14
7
N
; spins 1, 1, 3, 1). All four of these isotopes have the same number of protons and neutrons, and they all have an odd number for theirnuclear spin. The only other observationally stable odd–odd nuclide is180m
73
Ta
(spin 9), the only primordialnuclear isomer, which has not yet been observed to decay despite experimental attempts.[4] Also, four long-lived radioactive odd–odd nuclides –40
19
K
(the most common radioisotope in the human body[5][6]),50
23
V
,138
57
La
, and176
71
Lu
with spins 4, 6, 5, 7, respectively – occur naturally. As in the case of180m
73
Ta
decay of high spin nuclides bybeta decay (includingelectron capture),gamma decay, or (to a lesser extent)internal conversion is greatly inhibited if the only decay possible betweenisobar nuclides (or in the case of180m
73
Ta
between nuclear isomers) involves a large change in spin, the "preferred" change of spin that is associated with rapid decay being 0 or 1 forbeta decay and also 2 forgamma decay. This high-spin inhibition of decay is the cause of the five heavy stable or long-lived odd-proton, odd-neutron nuclides discussed above. For an example of this effect where the spin effect is subtracted, tantalum-180, the odd–odd low-spin (theoretical) decay product of primordial tantalum-180m, itself has a half-life of only 8.15 hours.

Many odd–odd radionuclides (like tantalum-180) with comparatively short half-lives are known. These almost always decay by positive or negative beta decay, in order to produce stable even–even isotopes which have paired protons and paired neutrons. In some odd–odd radionuclides where the ratio of protons to neutrons is near theline of stability, this decay can proceed in either direction, turning a proton into a neutron, or vice versa. An example is64
29
Cu
, which can decay by positron emission or electron capture to64
28
Ni
or by electron emission to64
30
Zn
.

Of the nine primordial odd–odd nuclides (five stable and four radioactive), only14
7
N
is the most common isotope of a common element. This is because proton capture on14
7
N
is the rate-limiting step of theCNO-I cycle.6
3
Li
and10
5
B
are minority isotopes of elements that are themselves rare compared to other light elements, while the other six isotopes make up only a tiny percentage of the natural abundance of their elements. For example,180m
73
Ta
is thought to be the rarest of all thestable nuclides.

No primordial odd–odd nuclide has spin 0 in the ground state. This is because the single unpaired neutron and unpaired proton have a largernuclear force attraction to each other if their spins are aligned (producing a total spin of at least 1 unit), instead of anti-aligned. Seedeuterium for the simplest case of this nuclear behavior.

Odd mass number

[edit]

For a given odd mass number, there is exactly onebeta-stable nuclide. There is not a difference in binding energy between even–odd and odd–even comparable to that between even–even and odd–odd, leaving other nuclides of the same mass number (isobars) free tobeta decay toward the lowest-mass nuclide. For mass numbers of 147, 151, and 209+, the beta-stable isobar of that mass number has been observed to undergoalpha decay. (In theory, mass numbers 143 to 155, 160 to 162, and 165+ can also alpha decay.) This gives a total of 101 stable nuclides with odd mass numbers. There are another nine radioactive primordial nuclides with odd mass numbers.

Odd-mass-number nuclides arefermions, i.e., havehalf-integerspin. Generally speaking, since odd-mass-number nuclides always have an even number of either neutrons or protons, the even-numbered particles usually form part of a "core" in the nucleus with a spin of zero. The unpaired nucleon with the odd number (whether proton or neutron) is then responsible for the nuclear spin, which is the sum of the orbital angular momentum and spin angular momentum of the remaining nucleon.

The odd-mass number stable nuclides are divided (roughly evenly) into odd-proton–even-neutron, and odd-neutron–even-proton nuclides, which are more thoroughly discussed below.

Odd-even (odd proton, even neutron)

[edit]

These 48 stable nuclides, stabilized by their even numbers of paired neutrons, form most of the stable isotopes of the odd-numbered elements; the very few odd–odd nuclides comprise the others. There are 41 odd-numbered elements withZ = 1 through 81, of which 30 (including hydrogen, sincezero is an even number) have one stable odd-even isotope, the elementstechnetium (
43
Tc
) andpromethium (
61
Pm
) have no stable isotopes, and nine elements:chlorine (
17
Cl
),potassium (
19
K
),copper (
29
Cu
),gallium (
31
Ga
),bromine (
35
Br
),silver (
47
Ag
),antimony (
51
Sb
),iridium (
77
Ir
), andthallium (
81
Tl
), have two odd–even stable isotopes each, for a total of 48 stable odd–even isotopes. The lightest example of this type of nuclide is1
1
H
(protium) while the heaviest example is205
81
Tl
. There are also five primordial radioactive odd–even isotopes,87
37
Rb
,115
49
In
,187
75
Re
,151
63
Eu
, and209
83
Bi
. The last two were only recently found to undergo alpha decay, and have half-lives greater than 1018 years.

Even-odd (even proton, odd neutron)

[edit]
Even–odd long-lived
DecayHalf-life
113
48
Cd
beta8.04×1015a
147
62
Sm
alpha1.066×1011a
235
92
U
alpha7.04×108a

These 53 stable nuclides have an even number of protons and an odd number of neutrons. By definition, they are all isotopes of even-Z elements, where they are a minority in comparison to the even–even isotopes which are about 3 times as numerous. Among the 41 even-Z elements that have a stable nuclide, only two elements (argon and cerium) have no even–odd stable nuclides. One element (tin) has three. There are 24 elements that have one even–odd nuclide and 13 that have two even–odd nuclides. The lightest example of this type of nuclide is3
2
He
and the heaviest is207
82
Pb
.

Of the 35 known primordial radionuclides there are three even–odd nuclides (see table at right), including thefissile235
92
U
. Because of their odd neutron numbers, the even–odd nuclides tend to have largeneutron capture cross sections, due to the energy that results from neutron-pairing effects.

These stable even-odd nuclides tend to be less common in nature, generally because in order to form and contribute to the primordial abundance, they must have escaped capturing neutrons to form yet other stable even–even isotopes, and are thus dispreferred during thes-process of nucleosynthesis in stars. For this reason, only195
78
Pt
(an almost whollyr-process element) and9
4
Be
are the most naturally abundant isotopes of their element, the former only by a small margin, and the latter only because the expectedberyllium-8 has lowerbinding energy than twoalpha particles and therefore immediatelyalpha decays.

Odd neutron number

[edit]
Neutron numberparity
NEvenOdd
Stable19358
Long-lived277
All primordial22065

Actinides with odd neutron numbers are generallyfissile (withthermal neutrons), while those with even neutron numbers are generally not, though they arefissionable withfast neutrons.Only9
4
Be
,14
7
N
, and195
78
Pt
have an odd neutron number and are the most naturally abundant isotopes of their element.

References

[edit]
  1. ^Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021)."The NUBASE2020 evaluation of nuclear properties"(PDF).Chinese Physics C.45 (3) 030001.doi:10.1088/1674-1137/abddae.
  2. ^Blank, B.; Regan, P.H. (2000)."Magic and doubly-magic nuclei".Nuclear Physics News.10 (4):20–27.doi:10.1080/10506890109411553.S2CID 121966707.
  3. ^Arevalo, Ricardo; McDonough, William F.; Luong, Mario (2009). "The K-U ratio of the silicate Earth: Insights into mantle composition, structure and thermal evolution".Earth and Planetary Science Letters.278 (3–4):361–369.Bibcode:2009E&PSL.278..361A.doi:10.1016/j.epsl.2008.12.023.
  4. ^Arnquist, I. J.; Avignone III, F. T.; Barabash, A. S.; Barton, C. J.; Bhimani, K. H.; Blalock, E.; Bos, B.; Busch, M.; Buuck, M.; Caldwell, T. S.; Christofferson, C. D.; Chu, P.-H.; Clark, M. L.; Cuesta, C.; Detwiler, J. A.; Efremenko, Yu.; Ejiri, H.; Elliott, S. R.; Giovanetti, G. K.; Goett, J.; Green, M. P.; Gruszko, J.; Guinn, I. S.; Guiseppe, V. E.; Haufe, C. R.; Henning, R.; Aguilar, D. Hervas; Hoppe, E. W.; Hostiuc, A.; Kim, I.; Kouzes, R. T.; Lannen V., T. E.; Li, A.; López-Castaño, J. M.; Massarczyk, R.; Meijer, S. J.; Meijer, W.; Oli, T. K.; Paudel, L. S.; Pettus, W.; Poon, A. W. P.; Radford, D. C.; Reine, A. L.; Rielage, K.; Rouyer, A.; Ruof, N. W.; Schaper, D. C.; Schleich, S. J.; Smith-Gandy, T. A.; Tedeschi, D.; Thompson, J. D.; Varner, R. L.; Vasilyev, S.; Watkins, S. L.; Wilkerson, J. F.; Wiseman, C.; Xu, W.; Yu, C.-H. (13 October 2023). "Constraints on the Decay of180mTa".Phys. Rev. Lett.131 (15) 152501.arXiv:2306.01965.doi:10.1103/PhysRevLett.131.152501.PMID 37897780.
  5. ^"Radiation and Radioactive Decay. Radioactive Human Body". Harvard Natural Sciences Lecture Demonstrations. RetrievedJuly 2, 2016.
  6. ^Winteringham, F. P. W; Effects, F.A.O. Standing Committee on Radiation, Land And Water Development Division, Food and Agriculture Organization of the United Nations (1989).Radioactive fallout in soils, crops and food: a background review. Food & Agriculture Org. p. 32.ISBN 978-92-5-102877-3.{{cite book}}: CS1 maint: multiple names: authors list (link)
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