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Energy density

From Wikipedia, the free encyclopedia
(Redirected fromEnergy capacity)
Energy per volume
Energy density
SI unitJ/m3
Other units
J/L, W⋅h/L,Pa
InSI base unitskg⋅m−1⋅s−2
Derivations from
other quantities
U =E/V
DimensionL1MT2{\displaystyle {\mathsf {L}}^{-1}{\mathsf {M}}{\mathsf {T}}^{-2}}

Inphysics,energy density is the quotient between the amount ofenergy stored in a given system or contained in a given region of space and thevolume of the system or region considered. Often only theuseful or extractable energy is measured. It is sometimes confused with stored energy per unitmass, which is calledspecific energy orgravimetric energy density.

There are different types of energy stored, corresponding to a particular type of reaction. In order of the typical magnitude of the energy stored, examples of reactions are:nuclear,chemical (includingelectrochemical),electrical,pressure,material deformation or inelectromagnetic fields.Nuclear reactions take place in stars and nuclear power plants, both of which derive energy from the binding energy of nuclei.Chemical reactions are used by organisms to derive energy from food and by automobiles from thecombustion of gasoline. Liquid hydrocarbons (fuels such as gasoline, diesel and kerosene) are today the densest way known to economically store and transport chemical energy at a large scale (1 kg of diesel fuel burns with the oxygen contained in ≈ 15 kg of air). Burning localbiomass fuels supplies household energy needs (cooking fires,oil lamps, etc.) worldwide.Electrochemical reactions are used by devices such as laptop computers and mobile phones to release energy from batteries.

Energy per unit volume has the same physical units as pressure, and in many situations issynonymous. For example, the energy density of a magnetic field may be expressed as and behaves like a physical pressure. The energy required to compress a gas to a certain volume may be determined by multiplying the difference between the gas pressure and the external pressure by the change in volume. Apressure gradient describes thepotential to performwork on the surroundings by convertinginternal energy to work until equilibrium is reached.

Incosmological and other contexts ingeneral relativity, the energy densities considered relate to the elements of thestress–energy tensor and therefore do include therest mass energy as well as energy densities associated withpressure.

Chemical energy

[edit]

When discussing the chemical energy contained, there are different types which can be quantified depending on the intended purpose. One is the theoretical total amount ofthermodynamic work that can be derived from a system, at a given temperature and pressure imposed by the surroundings, calledexergy. Another is the theoretical amount of electrical energy that can be derived fromreactants that are at room temperature and atmospheric pressure. This is given by the change in standardGibbs free energy. But as a source ofheat or for use in aheat engine, the relevant quantity is the change in standardenthalpy or theheat of combustion.

There are two kinds of heat of combustion:

  • The higher value (HHV), or gross heat of combustion, includes all the heat released as the products cool to room temperature and whatever water vapor is present condenses.
  • The lower value (LHV), or net heat of combustion, does not include the heat which could be released by condensing water vapor, and may not include the heat released on cooling all the way down to room temperature.

A convenient table of HHV and LHV of some fuels can be found in the references.[1]

In energy storage and fuels

[edit]
Selected energy densities plot[2][3][4][5][6][7][8]

Forenergy storage, the energy density relates the storedenergy to the volume of the storage equipment, e.g. thefuel tank. The higher the energy density of the fuel, the more energy may be stored or transported for the same amount of volume. The energy of a fuel per unit mass is called itsspecific energy.

The adjacent figure shows thegravimetric andvolumetric energy density of some fuels and storage technologies (modified from theGasoline article). Some values may not be precise because ofisomers or other irregularities. Theheating values of the fuel describe their specific energies more comprehensively.

The density values for chemical fuels do not include the weight of the oxygen required for combustion. Theatomic weights of carbon and oxygen are similar, while hydrogen is much lighter. Figures are presented in this way for those fuels where in practice air would only be drawn in locally to the burner. This explains the apparently lower energy density of materials that contain their own oxidizer (such as gunpowder and TNT), where the mass of the oxidizer in effect adds weight, and absorbs some of the energy of combustion to dissociate and liberate oxygen to continue the reaction. This also explains some apparent anomalies, such as the energy density of a sandwich appearing to be higher than that of a stick of dynamite.

Given the high energy density of gasoline, the exploration of alternative media to store the energy of powering a car, such as hydrogen or battery, is strongly limited by the energy density of the alternative medium. The same mass of lithium-ion storage, for example, would result in a car with only 2% the range of its gasoline counterpart. If sacrificing the range is undesirable, much more storage volume is necessary. Alternative options are discussed for energy storage to increase energy density and decrease charging time, such assupercapacitors.[9][10][11][12]

No single energy storage method boasts the best inspecific power,specific energy, and energy density.Peukert's law describes how the amount of useful energy that can be obtained (for a lead-acid cell) depends on how quickly it is pulled out.

Efficiency

[edit]

In general anengine will generate lesskinetic energy due toinefficiencies andthermodynamic considerations—hence thespecific fuel consumption of an engine will always be greater than its rate of production of the kinetic energy of motion.

Energy density differs fromenergy conversion efficiency (net output per input) orembodied energy (the energy output costs to provide, asharvesting,refining, distributing, and dealing withpollution all use energy). Large scale, intensive energy use impacts and is impacted byclimate,waste storage, andenvironmental consequences.

Nuclear energy

[edit]

The greatest energy source by far is matter itself, according to themass–energy equivalence. This energy is described byE =mc2, wherec is the speed of light. In terms of density,m =ρV, whereρ is the volumetric mass density,V is the volume occupied by the mass. This energy can be released by the processes ofnuclear fission (~ 0.1%),nuclear fusion (~ 1%), or theannihilation of some or all of the matter in the volumeV by matter–antimatter collisions (100%).[citation needed]

The most effective ways of accessing this energy, aside from antimatter, arefusion andfission. Fusion is the process by which the sun produces energy which will be available for billions of years (in the form of sunlight and heat). However as of 2024, sustainedfusion power production continues to be elusive. Power from fission innuclear power plants (using uranium and thorium) will be available for at least many decades or even centuries because of the plentiful supply of the elements on earth,[13] though the full potential of this source can only be realized throughbreeder reactors, which are, apart from theBN-600 reactor, not yet used commercially.[14]

Fission reactors

[edit]

Nuclear fuels typically have volumetric energy densities at least tens of thousands of times higher than chemical fuels. A 1 inch tall uranium fuel pellet is equivalent to about 1 ton of coal, 120 gallons of crude oil, or 17,000 cubic feet of natural gas.[15] Inlight-water reactors, 1 kg of natural uranium – following a corresponding enrichment and used for power generation– is equivalent to the energy content of nearly 10,000 kg of mineral oil or 14,000 kg of coal.[16] Comparatively,coal,gas, andpetroleum are the current primary energy sources in the U.S.[17] but have a much lower energy density.

The density of thermal energy contained in the core of alight-water reactor (pressurized water reactor (PWR) orboiling water reactor (BWR)) of typically1 GW (1000 MW electrical corresponding to ≈ 3000 MW thermal) is in the range of 10 to 100 MW of thermal energy per cubic meter of cooling water depending on the location considered in the system (the core itself (≈ 30 m3), the reactor pressure vessel (≈ 50 m3), or the whole primary circuit (≈ 300 m3)). This represents a considerable density of energy that requires a continuous water flow at high velocity at all times in order to removeheat from the core, even after an emergency shutdown of the reactor.

The incapacity to cool the cores of three BWRs atFukushima after the 2011tsunami and the resulting loss of external electrical power and cold source caused the meltdown of the three cores in only a few hours, even though the three reactors were correctly shut down just after theTōhoku earthquake. This extremely high power density distinguishes nuclear power plants (NPP's) from any thermal power plants (burning coal, fuel or gas) or any chemical plants and explains the large redundancy required to permanently control theneutron reactivity and to remove the residual heat from the core of NPP's.

Antimatter–matter annihilation

[edit]

Because antimatter–matter interactions result in complete conversion of the rest mass to radiant energy, the energy density of this reaction depends on the density of the matter and antimatter used. Aneutron star would approximate the most dense system capable of matter-antimatter annihilation. Ablack hole, although denser than a neutron star, does not have an equivalent anti-particle form, but would offer the same 100% conversion rate of mass to energy in the form ofHawking radiation. Even in the case of relatively small black holes (smaller than astronomical objects) the power output would be tremendous.

Electric and magnetic fields

[edit]
Main article:Radiant energy density

Electric andmagnetic fields can store energy and its density relates to the strength of the fields within a given volume. This (volumetric) energy density is given byu=ε2E2+12μB2{\displaystyle u={\frac {\varepsilon }{2}}\mathbf {E} ^{2}+{\frac {1}{2\mu }}\mathbf {B} ^{2}}whereE is theelectric field,B is themagnetic field, andε andµ are the permittivity and permeability of the surroundings respectively. The SI unit is the joule per cubic metre.

In ideal (linear and nondispersive) substances, the energy density isu=12(ED+HB){\displaystyle u={\frac {1}{2}}(\mathbf {E} \cdot \mathbf {D} +\mathbf {H} \cdot \mathbf {B} )}whereD is theelectric displacement field andH is themagnetizing field. In the case of absence of magnetic fields, by exploitingFröhlich's relationships it is also possible to extend these equations toanisotropic andnonlinear dielectrics, as well as to calculate the correlatedHelmholtz free energy andentropy densities.[18]

In the context ofmagnetohydrodynamics, the physics of conductive fluids, the magnetic energy density behaves like an additionalpressure that adds to thegas pressure of aplasma.

Pulsed sources

[edit]

When a pulsedlaser impacts a surface, theradiant exposure, i.e. the energy deposited per unit of surface, may also be calledenergy density or fluence.[19]

Table of material energy densities

[edit]
See also:Energy density Extended Reference Table
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The following unit conversions may be helpful when considering the data in the tables: 3.6 MJ = 1 kW⋅h ≈ 1.34 hp⋅h. Since 1 J = 10−6 MJ and 1 m3 = 103 L, dividejoule/m3 by 109 to getMJ/L = GJ/m3. Divide MJ/L by 3.6 to getkW⋅h/L.

Chemical reactions (oxidation)

[edit]
See also:Energy content of biofuel andFood energy

Unless otherwise stated, the values in the following table arelower heating values forperfect combustion, not counting oxidizer mass or volume. When used to produce electricity in afuel cell or to dowork, it is theGibbs free energy of reaction (ΔG) that sets the theoretical upper limit. If the producedH2O is vapor, this is generally greater than the lower heat of combustion, whereas if the producedH
2
O
is liquid, it is generally less than the higher heat of combustion. But in the most relevant case of hydrogen, ΔG is 113 MJ/kg if water vapor is produced, and 118 MJ/kg if liquid water is produced, both being less than the lower heat of combustion (120 MJ/kg).[20]

Energy released by chemical reactions (oxidation)
MaterialSpecific energy
(MJ/kg)
Energy density
(MJ/L)
Specific energy
(W⋅h/kg)
Energy density
(W⋅h/L)
Comment
Hydrogen, liquid141.86 (HHV)
119.93 (LHV)
10.044 (HHV)
8.491 (LHV)
39405.6 (HHV)
33,313.9 (LHV)
2790.0 (HHV)
2,358.6 (LHV)
Energy figures applyafter reheating to 25 °C.[21]

See note above about use in fuel cells.

Hydrogen, gas (681 atm, 69 MPa, 25 °C)141.86 (HHV)
119.93 (LHV)
5.323 (HHV)
4.500 (LHV)
39405.6 (HHV)
33313.9 (LHV)
1478.6 (HHV)
1250.0 (LHV)
Data from same reference as for liquid hydrogen.[21]

High-pressure tanks weigh much more than the hydrogen they can hold. The hydrogen may be around 5.7% of the total mass,[22] giving just 6.8 MJ per kg total mass for the LHV.

See note above about use in fuel cells.

Hydrogen, gas (1 atm or 101.3 kPa, 25 °C)141.86 (HHV)
119.93 (LHV)
0.01188 (HHV)
0.01005 (LHV)
39405.6 (HHV)
33313.9 (LHV)
3.3 (HHV)
2.8 (LHV)
[21]
Diborane78.288.421722.224600.0[23]
Beryllium67.6125.118777.834750.0
Lithium borohydride65.243.418111.112055.6
Boron58.9137.816361.138277.8[24][better source needed]
Methane (101.3 kPa, 15 °C)55.60.037815444.510.5
LNG (NG at −160 °C)53.6[25]22.214888.96166.7
CNG (NG compressed to 247 atm, 25 MPa ≈3,600 psi)53.6[25]914888.92500.0
Natural gas53.6[25]0.036414888.910.1
LPGpropane49.625.313777.87027.8[26]
LPGbutane49.127.713638.97694.5[26]
Petrol (Gasoline)46.434.212888.99500.0[26]
Polypropylene plastic46.4[27]41.712888.911583.3
Polyethylene plastic46.3[27]42.612861.111833.3
Residentialheating oil46.237.312833.310361.1[26]
Diesel fuel45.638.612666.710722.2[26]
100LLAvgas44.0[28]31.5912222.28775.0
Jet fuel (e.g.kerosene)43[29][30][31]3511944.49722.2aircraft engine
Gasohol E10 (10% ethanol 90% gasoline by volume)43.5433.1812094.59216.7
Lithium43.123.011972.26388.9
Biodiesel oil (vegetable oil)42.203311,722.29,166.7
DMF (2,5-dimethylfuran)42[32]37.811,666.710,500.0[clarification needed]
Paraffin wax42[33]37.81170010500
Crude oil (tonne of oil equivalent)41.86837[25]1163010278
Polystyrene plastic41.4[27]43.511500.012083.3
Body fat383510555.69722.2metabolism in human body (22% efficiency[34])
Butanol36.629.210166.78111.1
GasoholE85 (85% ethanol 15% gasoline by volume)33.125.65[citation needed]9194.57125.0
Graphite32.772.99083.320250.0
Coal,anthracite26–3334–437222.29166.79444.511944.5Figures represent perfect combustion not counting oxidizer, but efficiency of conversion to electricity is ≈36%[5]
Silicon32.675.99,05621,080See Table 1[35]
Aluminium31.083.88611.123277.8
Ethanol30248333.36666.7
DME31.7 (HHV)
28.4 (LHV)
21.24 (HHV)
19.03 (LHV)
8805.6 (HHV)
7888.9 (LHV)
5900.0 (HHV)
5286.1 (LHV)
[36][37]
Polyester plastic26.0[27]35.67222.29888.9
Magnesium24.743.06861.111,944.5
Phosphorus (white)24.3044.30675012310[38]
Coal,bituminous24–3526–496666.79722.27222.213611.1[5]
PET plastic (impure)23.5[39]< ~32.46527.8< ~9000
Methanol19.715.65472.24333.3
Titanium19.7488.93548024700burned totitanium dioxide
Hydrazine19.519.35416.75361.1burned tonitrogen andwater
Liquidammonia18.611.55166.73194.5burned to nitrogen and water
Potassium18.616.551604600burned to drypotassium oxide
PVC plastic (improper combustion toxic)18.0[27]25.25000.07000.0[clarification needed]
Wood18.05000.0[40]
Peatbriquette17.74916.7[41]
Sugars, carbohydrates, and protein1726.2 (dextrose)4722.27277.8metabolism in human body (22% efficiency[42])[citation needed]
Calcium15.924.64416.76833.3[citation needed]
Glucose15.5523.94319.56638.9
Drycow dung andcamel dung15.5[43]4305.6
Coal,lignite10–202777.85555.6[citation needed]
Sodium13.312.83694.53555.6burned to wetsodium hydroxide
Peat12.83,555.6
Nitromethane11.312.853138.93570
Manganese9.4668.2263018900burned tomanganese dioxide
Sulfur9.2319.112563.95308.3burned tosulfur dioxide[44]
Sodium9.18.82527.82444.5burned to drysodium oxide
Household waste8.0[45]2222.2
Iron7.457.72052.916004.1burned toiron(III) oxide[46]
Iron6.752.21858.314487.2burned toIron(II,III) oxide[46]
Zinc5.338.01472.210555.6
Teflon plastic5.111.21416.73111.1combustion toxic, but flame retardant
Iron4.938.21361.110611.1burned toiron(II) oxide[46]
Gunpowder4.7–11.3[47]5.9–12.916003580
TNT4.1846.9211621920
Barium3.9914.011103890burned tobarium dioxide
ANFO3.71027.8

Electrochemical reactions (batteries)

[edit]
Energy released by electrochemical reactions or similar means
MaterialSpecific energy
(MJ/kg)
Energy density
(MJ/L)
Specific energy
(W⋅h/kg)
Energy density
(W⋅h/L)
Comment
Zinc-air battery1.59[48]6.02441.71672.2controlled electric discharge
Lithium air battery (rechargeable)9.0[49]2,500.0controlled electric discharge
Sodium sulfur battery0.54–0.86150–240
Lithium metal battery1.84.325001200controlled electric discharge
Lithium-ion battery0.36–0.875[52]0.9–2.63100.00–243.06250.00–730.56controlled electric discharge
Lithium-ion battery withsilicon nanowireanodes1.5664.32435[53]1,200[53]controlled electric discharge
Alkaline battery0.48[54]1.3[55]controlled electric discharge
Nickel-metal hydride battery0.41[56]0.504–1.46[56]controlled electric discharge
Lead-acid battery0.170.5647.2156controlled electric discharge
Supercapacitor (EDLC)0.01–0.030[57][58][59][60][61][62][63]0.006–0.06[57][58][59][60][61][62]up to 8.57[63]controlled electric discharge
Electrolytic capacitor0.000010.0002[64]0.000010.001[64][65][66]controlled electric discharge

Common battery formats

[edit]
Battery energy capacities
Storage deviceEnergy content
(J)
Energy content
(W⋅h)
Typical
mass (g)
Typical dimensions
(diameter × height in mm)
Typical volume (mL)Specific energy (MJ/kg)Energy density (MJ/L)
AlkalineAA battery[67]93602.62414.2 × 507.920.391.18
AlkalineC battery[67]344169.56526 × 4624.420.531.41
NiMH AA battery90722.52614.2 × 507.920.351.15
NiMH C battery194405.48226 × 4624.420.240.80
Lithium-ion18650 battery28800468008–1344–49[68]18 × 6516.540.59–1.061.74–2.83

Nuclear reactions

[edit]
Energy released by nuclear reactions
MaterialSpecific energy
(MJ/kg)
Energy density
(MJ/L)
Specific energy
(W⋅h/kg)
Energy density
(W⋅h/L)
Comment
Antimatter8987551787490 PJ/kgDepends on the density of the antimatter's form24965421631578 ≈ 25 TW⋅h/kgDepends on the density of the antimatter's formAnnihilation, counting both the consumed antimatter mass and ordinary matter mass
Hydrogen (fusion)639780320[69] but at least 2% of this is lost toneutrinos.Depends on conditions177716755600Depends on conditionsReaction 4H→4He
Deuterium (fusion)
571,182,758[70]Depends on conditions158661876600Depends on conditionsProposedfusion scheme for D+D→4He, by combining D+D→T+H, T+D→4He+n, n+H→D and D+D→3He+n,3He+D→4He+H, n+H→D
Deuterium+tritium (fusion)337387388[69]Depends on conditions93718718800Depends on conditionsD + T →4He + n
Being developed.
Lithium-6 deuteride (fusion)268848415[69]Depends on conditions74680115100Depends on conditions6LiD → 24He
Used in weapons.
Plutonium-2398361000013000000001,700,000,000 (depends oncrystallographic phase)23222915000370000000000460000000000 (depends oncrystallographic phase)Heat produced inFission reactor
Plutonium-23931,000,000490000000620000000 (Depends oncrystallographic phase)8700000000140000000000170000000000 (depends oncrystallographic phase)Electricity produced inFission reactor
Uranium80620000[71]153984200022394000000Heat produced inbreeder reactor
Thorium79420000[71]92921400022061000000Heat produced inbreeder reactor (experimental)
Plutonium-238223900043277631621900000Radioisotope thermoelectric generator. The heat is only produced at a rate of 0.57 W/g.

In material deformation

[edit]

The mechanical energy storage capacity, orresilience, of aHookean material when it is deformed to the point of failure can be computed by calculating tensile strength times the maximum elongation dividing by two. The maximum elongation of a Hookean material can be computed by dividing stiffness of that material by its ultimate tensile strength. The following table lists these values computed using the Young's modulus as measure of stiffness:

Mechanical energy capacities
MaterialEnergy density by mass

(J/kg)

Resilience: Energy density by volume

(J/L)

Density

(kg/L)

Young's modulus

(GPa)

Tensile yieldstrength

(MPa)

Rubber band16516605[72]22008900[72]1.35[72]
Steel,ASTM A228 (yield, 1 mm diameter)1440177011200138007.80[73]210[73]21702410[73]
Acetals9087540.831[74]2.8[75]65 (ultimate)[75]
Nylon-6233–1,870253–2,0301.0842–4[75]45–90 (ultimate)[75]
Copper Beryllium 25-1/2 HT (yield)6845720[76]8.36[77]131[76]1224[76]
Polycarbonates433–615520–7401.2[78]2.6[75]52–62 (ultimate)[75]
ABS plastics241–534258–5711.071.4–3.1[75]40 (ultimate)[75]
Acrylic15303.2[75]70 (ultimate)[75]
Aluminium 7077-T8 (yield)3991120[76]2.81[79]71.0[76]400[76]
Steel,stainless, 301-H (yield)3012410[76]8.0[80]193[76]965[76]
Aluminium 6061-T6 (yield @ 24 °C)2055532.70[81]68.9[81]276[81]
Epoxy resins113–18102–3[75]26–85 (ultimate)[75]
Douglas fir Wood158–200960.4810.609[82]13[75]50 (compression)[75]
Steel, MildAISI 101842.43347.87[83]205[83]370 (440 Ultimate)[83]
Aluminium (not alloyed)32.587.72.70[84]69[75]110 (ultimate)[75]
Pine (American Eastern White,flexural)31.8–32.811.1–11.50.350[85]8.30–8.56 (flexural)[85]41.4 (flexural)[85]
Brass28.6–36.5250–3068.4–8.73[86]102–125[75]250 (ultimate)[75]
Copper23.12078.93[86]117[75]220 (ultimate)[75]
Glass5.56–10.013.9–25.02.5[87]50–90[75]50 (compression)[75]

Other release mechanisms

[edit]
Energy released by other means
MaterialSpecific energy
(MJ/kg)
Energy density
(MJ/L)
Specific energy
(W⋅h/kg)
Energy density
(W⋅h/L)
Comment
Silicon (phase change)1.7904.55001,285Energy stored through solid to liquid phase change of silicon[88]
Strontium bromide hydrate0.814[89]1.93628Thermal energy of phase change at 88.6 °C (361.8 K)
Liquid nitrogen0.77[90]0.62213.9172.2Maximum reversible work at 77.4 K with 300 K reservoir
Compressed air at 30 MPa (4,400 psi)0.50.2138.955.6Potential energy
Latent heat of fusion of ice (thermal)0.3340.33493.193.1
Flywheel0.36–0.55.3Kinetic energy
Water at 100 m dam height0.0009810.0009780.2720.272Figures represent potential energy, but efficiency of conversion to electricity is 85–90%[91][92]

See also

[edit]

References

[edit]
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Further reading

[edit]
  • The Inflationary Universe: The Quest for a New Theory of Cosmic Origins by Alan H. Guth (1998)ISBN 0-201-32840-2
  • Cosmological Inflation and Large-Scale Structure by Andrew R. Liddle, David H. Lyth (2000)ISBN 0-521-57598-2
  • Richard Becker, "Electromagnetic Fields and Interactions", Dover Publications Inc., 1964
  • ^ "Aircraft Fuels".Energy, Technology and the Environment Ed. Attilio Bisio. Vol. 1. New York: John Wiley and Sons, Inc., 1995. 257–259
  • "Fuels of the Future for Cars and Trucks" – Dr. James J. Eberhardt – Energy Efficiency and Renewable Energy, U.S. Department of Energy – 2002 Diesel Engine Emissions Reduction (DEER) Workshop San Diego, California - August 25–29, 2002
  • "Heat values of various fuels – World Nuclear Association".www.world-nuclear.org. Retrieved4 November 2018.
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