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Dipotassium phosphate

From Wikipedia, the free encyclopedia
Dipotassium phosphate
Names
IUPAC name
Potassium hydrogen phosphate
Other names
Potassium monohydrogen phosphate
Phosphoric acid dipotassium salt
Potassium phosphate dibasic
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard100.028.940Edit this at Wikidata
EC Number
  • 231-834-5
E numberE340(ii)(antioxidants, ...)
UNII
  • InChI=1S/2K.H3O4P/c;;1-5(2,3)4/h;;(H3,1,2,3,4)/q2*+1;/p-2 checkY
    Key: ZPWVASYFFYYZEW-UHFFFAOYSA-L checkY
  • InChI=1/2K.H3O4P/c;;1-5(2,3)4/h;;(H3,1,2,3,4)/q2*+1;/p-2
    Key: ZPWVASYFFYYZEW-NUQVWONBAH
  • [K+].[K+].[O-]P([O-])(=O)O
Properties
K2HPO4
Molar mass174.2 g/mol
Appearancewhite powder
deliquescent
Odorodorless
Density2.44 g/cm3
Melting point> 465 °C (869 °F; 738 K) decomposes
149.25 g/100 mL (20 °C)
Solubilityslightly soluble inalcohol
Acidity (pKa)12.4
Basicity (pKb)6.8
Hazards
NFPA 704 (fire diamond)
Flash pointNon-flammable
Related compounds
Othercations
Disodium phosphate
Diammonium phosphate
Related compounds
Monopotassium phosphate
Tripotassium phosphate
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Chemical compound

Dipotassium phosphate (alsodipotassium hydrogen orthophosphate orpotassium phosphate dibasic) is theinorganic compound with the formula K2HPO4.(H2O)x (x = 0, 3, 6). Together withmonopotassium phosphate (KH2PO4.(H2O)x), it is often used as afertilizer,food additive, andbuffering agent.[1] It is a white or colorless solid that is soluble in water.

It is produced commercially by partial neutralization ofphosphoric acid with two equivalents ofpotassium chloride:[1]

H3PO4 + 2 KCl → K2HPO4 + 2 HCl

Uses

[edit]

As a food additive, dipotassium phosphate is used inimitation dairy creamers, dry powder beverages, mineral supplements, and starter cultures.[2] It functions as an emulsifier, stabilizer and texturizer; it is also a buffering agent, and chelating agent especially for the calcium in milk products.[3]

As afood additive, dipotassium phosphate isgenerally recognized as safe by the United StatesFood and Drug Administration,[4] and is commonly used (in conjunction with other inorganic salts) to add taste to some brands ofbottled water.[5]

References

[edit]
  1. ^abKlaus Schrödter; Gerhard Bettermann; Thomas Staffel; Friedrich Wahl; Thomas Klein; Thomas Hofmann (2012). "Phosphoric Acid and Phosphates".Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH.doi:10.1002/14356007.a19_465.pub3.ISBN 978-3-527-30673-2.
  2. ^John H. Thorngate III; Seppo Salminen; Larry A. Branen; Michael P. Davidson, eds. (2001). "Food Phosphates".Food Additives. Food Science and Technology. Vol. 116. CRC Press.doi:10.1201/9780824741709.ch25 (inactive 12 July 2025).ISBN 978-0-8247-9343-2.{{cite book}}: CS1 maint: DOI inactive as of July 2025 (link)
  3. ^"What is dipotassium phosphate?". 30 April 2018. Retrieved2020-09-09.
  4. ^"Database of Select Committee on GRAS Substances (SCOGS) Reviews". Archived fromthe original on 2007-05-21. Retrieved2008-03-22. (listed as "potassium phosphate, dibasic")
  5. ^"Brands Of Bottled Water With Electrolytes (Confirmed By Lab Tests) - Water Purification Guide". 3 July 2021.
H, (pseudo)halogens
chalcogens
pnictogens
B, C group
transition metals
organic


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