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Decane

From Wikipedia, the free encyclopedia
For other uses, seeDečane (disambiguation).
Not to be confused withDecene orDecyne.
Alkane hydrocarbon; component of gasoline (petrol) and kerosene
Decane
Skeletal formula of decane
Skeletal formula of decane with all implicit carbons shown, and all explicit hydrogens added
Ball-and-stick model of the decane molecule
Names
Preferred IUPAC name
Decane[1]
Other names
Decyl hydride
Identifiers
3D model (JSmol)
1696981
ChEBI
ChEMBL
ChemSpider
DrugBank
ECHA InfoCard100.004.262Edit this at Wikidata
EC Number
  • 204-686-4
MeSHdecane
RTECS number
  • HD6550000
UNII
UN number2247
  • InChI=1S/C10H22/c1-3-5-7-9-10-8-6-4-2/h3-10H2,1-2H3 checkY
    Key: DIOQZVSQGTUSAI-UHFFFAOYSA-N checkY
  • CCCCCCCCCC
Properties
C10H22
Molar mass142.286 g·mol−1
AppearanceColorless liquid
OdorGasoline-like (in high concentrations)
Density0.730 g mL−1
Melting point−30.5 to −29.2 °C; −22.8 to −20.6 °F; 242.7 to 243.9 K
Boiling point173.8 to 174.4 °C; 344.7 to 345.8 °F; 446.9 to 447.5 K
logP5.802
Vapor pressure195 Pa[2]
2.1 nmol Pa−1 kg−1
−119.74·10−6 cm3/mol
Thermal conductivity0.1381 W m−1 K−1 (300 K)[3]
1.411–1.412
Viscosity
  • 0.850 mPa·s (25 °C)[4]
  • 0.920 mPa·s (20 °C)
Thermochemistry
315.46 J K−1 mol−1
425.89 J K−1 mol−1
−302.1 – −299.9 kJ mol−1
−6779.21 – −6777.45 kJ mol−1
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Flammable, moderately toxic
GHS labelling:
GHS02: FlammableGHS08: Health hazard
Danger
H226,H302,H304,H305
P301+P310,P331
NFPA 704 (fire diamond)
Flash point46.0 °C (114.8 °F; 319.1 K)
210.0 °C (410.0 °F; 483.1 K)
Explosive limits0.8–2.6%
Lethal dose or concentration (LD, LC):
  • >2 g kg−1(dermal, rabbit)
  • 601 mg/kg−1(oral, rat)
Safety data sheet (SDS)hazard.com
Related compounds
Related alkanes
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Chemical compound

Decane is analkanehydrocarbon with thechemical formula C10H22. Although 75 structuralisomers are possible for decane, the term usually refers to the normal-decane ("n-decane"), with the formula CH3(CH2)8CH3. All isomers, however, exhibit similar properties and little attention is paid to the composition.[5] These isomers areflammableliquids. Decane is present in small quantities (less than 1%) ingasoline (petrol) andkerosene.[6][7] Like other alkanes, it is anonpolar solvent, and does not dissolve inwater, and is readily combustible. Although it is a component offuels, it is of little importance as a chemical feedstock, unlike a handful of other alkanes.[8]

Reactions

[edit]

Decane undergoescombustion, just like otheralkanes. In the presence of sufficient oxygen, it burns to formwater andcarbon dioxide.

2 C10H22 + 31 O2 → 20 CO2 + 22 H2O

With insufficient oxygen,carbon monoxide is also formed.

It can be manufactured in the laboratory without fossil fuels.[9]

Physical properties

[edit]

It has asurface tension of 0.0238 N·m−1.[10]

See also

[edit]

References

[edit]
  1. ^"decane - Compound Summary".PubChem Compound. USA: National Center for Biotechnology Information. 16 September 2004. Identification and Related Records. Retrieved5 January 2012.
  2. ^Yaws, Carl L. (1999).Chemical Properties Handbook. New York: McGraw-Hill. pp. 159–179.ISBN 0-07-073401-1.
  3. ^Touloukian, Y.S., Liley, P.E., and Saxena, S.C. Thermophysical properties of matter - the TPRC data series. Volume 3. Thermal conductivity - nonmetallic liquids and gases. Data book. 1970.
  4. ^Dymond, J. H.; Oye, H. A. (1994). "Viscosity of Selected Liquid n-Alkanes".Journal of Physical and Chemical Reference Data.23 (1):41–53.Bibcode:1994JPCRD..23...41D.doi:10.1063/1.555943.ISSN 0047-2689.
  5. ^"75 Isomers of Decane".The Third Millennium Online! (in Latin). Retrieved26 July 2021.
  6. ^"Petroleum - Chemistry Encyclopedia - reaction, water, uses, elements, examples, gas, number, name".www.chemistryexplained.com. Retrieved2016-01-28.
  7. ^"n-Decane (Annotation)".Hazardous Substances Data Bank (HSDB). National Center for Biotechnology Information. Retrieved7 July 2022.
  8. ^Griesbaum, Karl; Behr, Arno; Biedenkapp, Dieter; Voges, Heinz-Werner; Garbe, Dorothea; Paetz, Christian; Collin, Gerd; Mayer, Dieter; Höke, Hartmut (15 June 2000), "Hydrocarbons",Ullmann's Encyclopedia of Industrial Chemistry, Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA,doi:10.1002/14356007.a13_227,ISBN 3527306730
  9. ^"Method for preparing n-decane at normal pressure".
  10. ^Website of KrüssArchived 2013-12-01 at theWayback Machine (8.10.2009)

External links

[edit]
Alkali metal
(Group 1) hydrides
Alkaline (Group 2)
earth hydrides
Monohydrides
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Group 13
hydrides
Boranes
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  • NhH
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(Group 16 hydrides)
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Hydrogen halides
(Group 17 hydrides)
  • HF
  • HCl
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  • HI
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  • Transition
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