Thedebye (/dɪˈbaɪ/dib-EYE,[1]Dutch:[dəˈbɛiə]; symbol:D) is aCGS unit[2] (a non-SImetric unit) ofelectric dipole moment[note 1] named in honour of the physicistPeter J. W. Debye. It is defined as10−18statcoulomb-centimetres.[note 2] Historically the debye was defined as the dipole moment resulting from two charges of opposite sign but an equal magnitude of 10−10 statcoulomb[note 3] (generally called e.s.u. (electrostatic unit) in older scientific literature), which were separated by 1 ångström.[note 4] This gave a convenient unit for molecular dipole moments.
| 1 D | = 10−18 statC·cm |
| = 10−18 cm5/2⋅g1/2⋅s−1[note 5] | |
| = 10−10 statC·Å[note 2] | |
| ≘1/299792458×10−21 C·m[note 6] | |
| ≈3.33564×10−30 C·m[note 7] | |
| ≈0.3934303 e·a0[note 8] | |
| ≈0.2081943 e⋅Å | |
| ≈0.02081943 e·nm |
Typical dipole moments for simple diatomic molecules are in the range of 0 to 11 D. Molecules with symmetry point groups or containing inversion symmetry will not have a permanent dipole moment, while highly ionic molecular species have a very large dipole moment, e.g. gas-phasepotassium bromide, KBr, with a dipole moment of 10.41 D.[3] A proton and an electron 1 Å apart have a dipole moment of 4.8 D.
The debye is still used inatomic physics andchemistry because SI units have until recently been inconveniently large. The smallest SI unit of electric dipole moment is the quectocoulomb-metre,[note 9] which corresponds closely to 0.3 D.