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Cyanocarbon

From Wikipedia, the free encyclopedia
Class of organic compounds containing cyanide

Inorganic chemistry,cyanocarbons are a group ofchemical compounds that contain several cyanidefunctional groups. Such substances generally are classified asorganic compounds, since they are formally derived fromhydrocarbons by replacing one or morehydrogen atoms with acyanide group.[1] One of the simplest member isC(CN)4 (tetracyanomethane, also known as carbon tetracyanide). Organic chemists often refer to cyanides asnitriles.

In general, cyanide is anelectronegative substituent. Thus, for example, cyanide-substitutedcarboxylic acids tend to be stronger than the parents. The cyanide group can also stabilize anions bydelocalizing negativecharge as revealed byresonance structures.

Definition and examples

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Cyanocarbons are organic compounds bearing enough cyano functional groups to significantly alter their chemical properties.[1]

Illustrative cyanocarbons:

References

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  1. ^abWebster, Owen W. "Cyanocarbons: a classic example of discovery-driven research" Journal of Polymer Science, Part A: Polymer Chemistry 2001, volume, 40, pp. 210-221.doi:10.1002/pola.10087
  2. ^Linn, W. J. (1969). "Tetracyanoethylene Oxide".Organic Syntheses.49: 103.doi:10.15227/orgsyn.049.0103.
  3. ^Middleton, W. J.; Wiley, D. W. (1961). "Tetramethylammonium 1,1,2,3,3-Pentacyanopropenide".Org. Synth.41: 99.doi:10.15227/orgsyn.041.0099.


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