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Critical points of the elements (data page)

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Chemical data page
Main article:Critical point

Critical point

[edit]
refTc(K)Tc(°C)Pc(MPa)Pc(other)Vc(cm3/mol)ρc(g/cm3)
1 Hhydrogen
use32.97−240.181.293
CRC.a32.97−240.181.29365
KAL33.21.29765.0
SMI−239.913.2kgf/cm20.0310
1 Hhydrogen (equilibrium)
LNG−240.171.29412.77 atm65.40.0308
1 Hhydrogen (normal)
LNG−239.911.29712.8 atm65.00.0310
1 Ddeuterium
KAL38.21.6560
1 Ddeuterium (equilibrium)
LNG−234.81.65016.28 atm60.40.0668
1 Ddeuterium (normal)
LNG−234.71.66516.43 atm60.30.0669
2 Hehelium
use5.19−267.960.227
CRC.a5.19−267.960.22757
KAL5.190.22757.2
SMI−267.92.34 kgf/cm20.0693
2 Hehelium (equilibrium)
LNG−267.960.22892.261 atm0.06930
2 Hehelium-3
LNG−269.850.11821.13 atm72.50.0414
2 Hehelium-4
LNG−267.960.2272.24 atm57.30.0698
3 Lilithium
use(3223)(2950)(67)
CRC.b(3223)2950(67)(66)
7 Nnitrogen
use126.21−146.943.39
CRC.a126.21−146.943.3990
KAL126.23.3989.5
SMI−147.134.7 kgf/cm20.3110
7 Nnitrogen-14
LNG−146.943.3933.5 atm89.50.313
7 Nnitrogen-15
LNG−146.83.3933.5 atm90.40.332
8 Ooxygen
use154.59−118.565.043
CRC.a154.59−118.565.04373
LNG−118.565.04349.77 atm73.40.436
KAL154.65.0473.4
SMI−118.851.4 kgf/cm20.430
9 Ffluorine
use144.13−129.025.172
CRC.a144.13−129.025.17266
LNG−129.05.21551.47 atm66.20.574
KAL144.35.2266
10 Neneon
use44.4−228.72.76
CRC.a44.4−228.72.7642
LNG−228.712.7727.2 atm41.70.4835
KAL44.42.7641.7
SMI−228.726.8 kgf/cm20.484
11 Nasodium
use(2573)(2300)(35)
CRC.b(2573)2300(35)(116)
15 Pphosphorus
use994721
CRC.a994721
LNG721
16 Ssulfur
use1314104120.7
CRC.a1314104120.7
LNG104111.7116 atm
KAL131420.7
SMI1040
17 Clchlorine
use416.9143.87.991
CRC.a416.9143.87.991123
LNG143.87.7176.1 atm1240.573
KAL416.97.98124
SMI144.078.7 kgf/cm20.573
18 Arargon
use150.87−122.284.898
CRC.a150.87−122.284.89875
LNG−122.34.8748.1 atm74.60.536
KAL150.94.9074.6
SMI−12249.7 kgf/cm20.531
19 Kpotassium
use(2223)(1950)(16)
CRC.b(2223)1950(16)(209)
33 Asarsenic
use16731400
CRC.a1673140035
LNG1400
34 Seselenium
use1766149327.2
CRC.a1766149327.2
LNG1493
35 Brbromine
use58831510.34
CRC.a58831510.34127
LNG31510.3102 atm1351.184
KAL58810.3127
SMI3021.18
36 Krkrypton
use209.41−63.745.50
CRC.a209.41−63.745.5091
LNG−63.755.5054.3 atm91.20.9085
KAL209.45.5091.2
37 Rbrubidium
use(2093)(1820)(16)
CRC.b(2093)1820(16)(247)
LNG18322500.34
53 Iiodine
use81954611.7
CRC.a819546155
LNG54611.7115 atm1550.164
KAL819155
SMI553
54 Xexenon
use289.7716.625.841
CRC.c289.7716.625.841118
LNG16.5835.8457.64 atm1181.105
KAL289.75.84118
SMI16.660.2 kgf/cm21.155
55 Cscaesium
use193816659.4
CRC.d193816659.4341
LNG18063000.44
80 Hgmercury
use17501477172.00
CRC.a17501477172.0043
LNG1477160.81587 atm
KAL175017242.7
SMI1460±201640±50 kgf/cm20.5
86 Rnradon
use3771046.28
CRC.a3771046.28
LNG1046.2862 atm1391.6
KAL3776.3
SMI10464.1 kgf/cm2

References

[edit]

CRC.a-d

[edit]

David R. Lide (ed),CRC Handbook of Chemistry and Physics, 85th Edition, online version.CRC Press. Boca Raton, Florida, 2003; Section 6, Fluid Properties; Critical Constants. Also agrees with Celsius values from Section 4: Properties of the Elements and Inorganic Compounds, Melting, Boiling, Triple, and Critical Point Temperatures of the Elements

Estimated accuracy forTc andPc is indicated by the number of digits. Above 750 KTc values may be in error by 10 K or more.Vc values are not assumed accurate more than to a few percent. Parentheses indicate extrapolated values. From these sources:
  • (a) D. Ambrose,Vapor-Liquid Constants of Fluids, in R.M. Stevenson, S. Malanowski,Handbook of the Thermodynamics of Organic Compounds, Elsevier, New York, (1987).
  • (b) I.G. Dillon, P.A. Nelson, B.S. Swanson,J. Chem. Phys.44, 4229, (1966).
  • (c) O. Sifner, J. Klomfar,J. Phys. Chem. Ref. Data23, 63, (1994).
  • (d) N.B. Vargaftik,Int. J. Thermophys.11, 467, (1990).

LNG

[edit]

J.A. Dean (ed),Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6; Table 6.5 Critical Properties

KAL

[edit]

National Physical Laboratory,Kaye and Laby Tables of Physical and Chemical Constants; D. Ambrose, M.B. Ewing, M.L. McGlashan,Critical constants and second virial coefficients of gases (retrieved Dec 2005)

SMI

[edit]

W.E. Forsythe (ed.),Smithsonian Physical Tables 9th ed., online version (1954; Knovel 2003). Table 259, Critical Temperatures, Pressures, and Densities of Gases

See also

[edit]
Elements
Data
Periodic table forms
Sets of elements
By periodic table structure
Groups
Periods
Blocks
Bymetallicity
Metals
Metalloids
Nonmetals
Other sets
Elements
Lists
Properties
Data pages
History
See also
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