Acombustible material is a material that can burn (i.e., sustain aflame) in air under certain conditions. A material isflammable if it ignites easily at ambient temperatures. In other words, a combustible material ignites with some effort and a flammable material catches fire immediately on exposure to flame.
The degree of flammability in air depends largely upon the volatility of the material – this is related to its composition-specificvapour pressure, which is temperature dependent. The quantity of vapour produced can be enhanced by increasing thesurface area of the material forming a mist or dust. Take wood as an example. Finely dividedwood dust can undergoexplosive flames and produce a blast wave. A piece of paper (made fromwood) catches on fire quite easily. A heavy oak desk is much harder to ignite, even though the wood fibre is the same in all three materials.
Common sense (and indeedscientific consensus until the mid-1700s) would seem to suggest that material "disappears" when burned, as only the ash is left. Further scientific research has found thatconservation of mass holds for chemical reactions.Antoine Lavoisier, one of the pioneers in these early insights, stated: "Nothing is lost, nothing is created, everything is transformed." The burning of a solid material may appear to lose weight if the mass of combustion gases (such ascarbon dioxide andwater vapor) are not taken into account. The original mass of flammable material and the mass of the oxygen consumed (typically from the surrounding air) equals the mass of the flame products (ash, water, carbon dioxide, and other gases). Lavoisier used the experimental fact that some metals gained mass when they burned to support his ideas (because those chemical reactions capture oxygen atoms into solid compounds rather than gaseous water).
Historically,flammable,inflammable andcombustible meantcapable of burning.[1] The word "inflammable" came through French from the Latininflammāre = "to set fire to", where the Latin preposition "in-"[2] means "in" as in "indoctrinate", rather than "not" as in "invisible" and "ineligible".
The word "inflammable" may be erroneously thought to mean "non-flammable".[3] The erroneous usage of the word "inflammable" is a significantsafety hazard. Therefore, since the 1950s, efforts to put forward the use of "flammable" in place of "inflammable" were accepted by linguists, and it is now the accepted standard in American English and British English.[4][5] Antonyms of "flammable" or "inflammable" include:non-flammable,non-inflammable,incombustible,non-combustible,not flammable, andfireproof.
Flammable applies tocombustible materials that ignite easily and thus are more dangerous and more highly regulated. Less easily ignited less-vigorously burning materials arecombustible. For example, in the United Statesflammable liquids, by definition, have aflash point below 100 °F (38 °C)—where combustible liquids have a flash point above 100 °F (38 °C).Flammable solids are solids that are readily combustible, or may cause or contribute to fire through friction. Readily combustible solids arepowdered, granular, or pasty substances that easily ignite by brief contact with an ignition source, such as a burning match, and spread flame rapidly.[6] The technical definitions vary between countries so theUnited Nations created theGlobally Harmonized System of Classification and Labeling of Chemicals, which defines the flash point temperature of flammable liquids as between 0 and 140 °F (60 °C) and combustible liquids between 140 °F (60 °C) and 200 °F (93 °C).[6]
Flammability is the ease with which a combustible substance can be ignited, causingfire orcombustion or even an explosion. The degree of difficulty required to cause the combustion of a substance is quantified throughfire testing. Internationally, a variety of test protocols exist to quantify flammability. The ratings achieved are used inbuilding codes,insurance requirements,fire codes and other regulations governing the use of building materials as well as the storage and handling of highly flammable substances inside and outside of structures and in surface and air transportation. For instance, changing anoccupancy by altering the flammability of the contents requires the owner of abuilding to apply for a building permit to make sure that the overallfire protection design basis of the facility can take the change into account.
Globally Harmonized System of Classification and Labelling of Chemicals uses a four category system to classify flammable liquids using flash point and boiling point temperature.[7][8] This system is used internationally to evaluate and sort substances in industrial applications, workplaces and products distributed to consumers.
| Category | Category 1 | Category 2 | Category 3 | Category 4 |
|---|---|---|---|---|
| Flash Point | <23.0 °C (73.4 °F) | <23.0 °C (73.4 °F) | ≥23.0 °C (73.4 °F) - ≤60 °C (140 °F) | >60 °C (140 °F) - ≤93.0 °C (199.4 °F) |
| Boiling Point | ≤35 °C (95 °F) | >35 °C (95 °F) | — | — |
| Example Liquids | Gasoline (Petrol),Diethyl ether | Ethanol,Isopropyl alcohol | Kerosene,1-Butanol | Diesel fuel,Formic acid |
| GHSSignal Word and Hazard Statement | Danger - Extremely flammable liquid and vapor | Danger - Highly flammable liquid and vapor | Warning - Flammable liquid and vapor | Warning - Combustible liquid |
Prior to 2012, OSHA's classification of flammable and combustible liquids in regulation 1910.106, was nearly identical to the National Fire Protective Association (NFPA)Flammable and Combustible Liquids Code, NFPA 30.[a][9] While no longer used for occupational regulations, NFPA 30's definitions are still commonly used in fire codes and NFPA codes and standards.
| Class | I-A | I-B | I-C | II | III-A | III-B |
|---|---|---|---|---|---|---|
Flammable | Combustible | |||||
| Flash Point | <22.8 °C (73.0 °F) | <22.8 °C (73.0 °F) | ≥22.8 °C (73.0 °F) - <37.8 °C (100.0 °F) | ≥37.8 °C (100.0 °F) - ≤60 °C (140 °F) | ≥60 °C (140 °F) - <200 °F (93 °C) | ≥200 °F (93 °C) |
| Boiling Point | <37.8 °C (100.0 °F) | ≥37.8 °C (100.0 °F) | — | — | — | — |
| Example Liquids | Gasoline (Petrol),Diethyl ether | Ethanol,Isopropyl alcohol | Butyl alcohol,Turpentine | Diesel fuel,Mineral spirits | Fuel oil,Formic acid | Olive oil, oil based paints |
Other systems for classifications of flammable liquids exist for more specialist applications, such asNFPA 704, which uses five categories, intended foremergency workers to understand the hazard posed by a substance during an emergency, such as a spill.[10] In addition to GHS, flammability classifications are incorporated into various systems designed for communicating physical and health hazards in workplaces; such as American Coatings Association'sHazardous Materials Identification System (HMIS) and Lab Safety Supply's Hazardous Material Identification Guide (HMIG).[11]
Flammable substances include, but are not limited to:
Flammability of furniture is of concern as cigarettes and candle accidents can trigger domestic fires. In 1975, California began implementingTechnical Bulletin 117 (TB 117), which required that materials such aspolyurethane foam used to fill furniture be able to withstand a small open flame, equivalent to a candle, for at least 12 seconds.[12] In polyurethane foam, furniture manufacturers typically meet TB 117 with additive halogenated organicflame retardants. No other U.S. states had similar standards, but because California has such a large market,manufacturers meet TB 117 in products that they distribute across the United States. The proliferation of flame retardants, and especially halogenated organic flame retardants, in furniture across the United States is strongly linked to TB 117. When it became apparent that the risk-benefit ratio of this approach was unfavorable and industry had used falsified documentation (i.e. seeDavid Heimbach) for the use of flame retardants, California modified TB 117 to require that fabric covering upholstered furniture meet a smolder test replacing the openflame test.[13] Gov.Jerry Brown signed the modified TB117-2013, which became effective in 2014.[14]
Lightweight textiles with porous surfaces are the most flammable fabrics.[15] Wool is less flammable than cotton, linen, silk, or viscose (rayon).[15][16] Polyester and nylon resist ignition, and melt rather than catch fire.[15][16]Acrylic is the most flammable synthetic fiber.[15]
Afire test can be conducted to determine the degree of flammability. Test standards used to make this determination but are not limited to the following:
Combustibility is a measure of how easily a substance bursts into flame, throughfire orcombustion. This is an important property to consider when a substance is used forconstruction or is being stored. It is also important in processes that produce combustible substances as aby-product. Special precautions are usually required for substances that are easily combustible. These measures may include installation offire sprinklers or storage remote from possible sources of ignition.
Substances with low combustibility may be selected for construction where the fire risk must be reduced, such as apartment buildings, houses, or offices. If combustible resources are used there is greater chance of fire accidents and deaths.Fire resistant substances are preferred for building materials and furnishings.
A non-combustible material[17] is a substance that does not ignite, burn, support combustion, or release flammable vapors when subject to fire or heat, in the form in which it is used and under conditions anticipated. Any solid substance complying with either of two sets of passing criteria listed in Section 8 of ASTM E 136 when the substance is tested in accordance with the procedure specified in ASTM E 136 is considered to be non-combustible.[18]
A number of industrial processes produce combustible dust as a by-product. The most common beingwood dust. Combustible dust has been defined as:a solid material composed of distinct particles or pieces, regardless of size, shape, or chemical composition, which presents a fire or deflagrationhazard whensuspended in air or some other oxidizing medium over a range of concentrations.[19] In addition to wood, combustible dusts includemetals, especially magnesium, titanium and aluminum, as well as other carbon-based dusts.[19] There are at least 140 known substances that produce combustible dust.[20]: 38 [21] While the particles in a combustible dusts may be of any size, normally they have a diameter of less than 420 μm.[19][b] As of 2012[update], theUnited States Occupational Safety and Health Administration has yet to adopt a comprehensive set of rules on combustible dust.[22]
When suspended in air (or any oxidizing environment), the fine particles of combustible dust present a potential for explosions. Accumulated dust, even when not suspended in air, remains a fire hazard. The National Fire Protection Association (U.S.) specifically addresses the prevention of fires and dust explosions in agricultural and food products facilities in NFPA Code section 61,[23] and other industries in NFPA Code sections 651–664.[c]Collectors designed to reduce airborne dust account for more than 40 percent of all dust explosions.[24] Other important processes aregrinding andpulverizing, transporting powders, filing silos and containers (which produces powder), and the mixing and blending of powders.[25]
Investigation of 200 dust explosions and fires, between 1980 and 2005, indicatedapproximately 100 fatalities and 600 injuries.[20]: 105–106 In January 2003, a polyethylene powder explosion and fire at the West Pharmaceutical Services plant inKinston, North Carolina resulted in the deaths of six workers and injuries to 38 others.[20]: 104 In February 2008 anexplosion of sugar dust rocked theImperial Sugar Company's plant atPort Wentworth, Georgia,[26] resulting in thirteen deaths.[27]
A material'sflash point is a metric of how easy it is to ignite the vapor of the material as it evaporates into theatmosphere. It is defined as the lowest material temperature required for fuel oils in the materials to begin to give off flammable vapors in the quantity high enough to support a flash of fire when ignited by an external source.[28] A lower flash point indicates higher flammability. Materials with flash points below 100 °F (38 °C) are regulated in theUnited States byOSHA as potential workplacehazards.
Theflame point of a material is a temperature value at which sustained flame can be supported on the material once ignited by an external source.[28] Once the flame point of a material is reached, it produces enough fuel vapors or oils to support continuous burning.
Thelower flammability limit orlower explosive limit (LFL/LEL) represents the lowest air to fuel vapor concentration required for combustion to take place when ignited by an external source, for any particular chemical.[29] Any concentration lower than this could not produce a flame or result in combustion. Theupper flammability limit orupper explosive limit (UFL/UEL) represents the highest air to fuel vapor concentration at which combustion can take place when ignited by an external source.[29] Any fuel-air mixture higher than this would be too concentrated to result in combustion. The values existing between these two limits represent the flammable or explosive range. Within this threshold, give an external ignition source, combustion of the particular fuel would likely happen.
Thevapor pressure of a liquid, which varies with its temperature, is a measure of how much the vapor of the liquid tends to concentrate in the surrounding atmosphere as the liquid evaporates.[30] Vapor pressure is a major determinant of the flash point and flame point, with higher vapor pressures leading to lower flash points and higher flammability ratings.
TheInternational Code Council (ICC) developed fire code requirements to provide adequate protection to the building and occupants.[31] These codes specify the combustibility rating for materials, the entrance and exit requirements, as well as active fire protection requirements, along with numerous other things. In the U.S. other agencies have also developed building codes that specify combustibility ratings such as state and/or county governing bodies. Following the requirements of these fire codes are crucial for higher occupancy buildings.
For existing buildings, fire codes focus on maintaining theoccupancies as originally intended. In other words, if a portion of a building were designed as anapartment, one could not suddenly load it with flammable liquids and turn it into a gas storage facility, because the fire load and smoke development in that one apartment would be so immense as to overtax theactive fire protection as well as thepassive fire protection means for the building. The handling and use of flammable substances inside a building is subject to the local fire code, which is ordinarily enforced by the local fire prevention officer.
For anAuthority Having Jurisdiction, combustibility is defined by the local code. In theNational Building Code of Canada, it is defined as follows:
BS 476-4:1970 defines a test for combustibility in which atechnician heats three specimens of a material in a furnace. Combustibile materials are those for which any of the three specimens either:
Otherwise, the material is classified as non-combustible.
Various countries have tests for determining non-combustibility of materials. Most involve the heating of a specified quantity of the test specimen for a set duration. Usually, the material must not support combustion and must not lose more than a certain amount of mass. As a general rule of thumb, concrete, steel, and ceramics - in other words inorganic substances - pass these tests, so building codes list them as suitable and sometimes even mandate their use in certain applications. InCanada, for instance,firewalls must be made ofconcrete.
Materials can be tested for the degree of flammability and combustibility in accordance with the GermanDIN 4102. DIN 4102, as well as its British cousinBS 476 include for testing ofpassive fire protectionsystems, as well as some of its constituent materials.
The following are the categories in order of degree of combustibility and flammability:
| Rating | Degree of flammability | Examples |
|---|---|---|
| A1 | 100% noncombustible (nicht brennbar) | |
| A2 | ≈98% noncombustible (nicht brennbar) | |
| B1 | Difficult to ignite (schwer entflammbar) | intumescents and some high endsilicones |
| B2 | Normal combustibility | wood |
| B3 | Easily ignited (leicht entflammbar) | polystyrene |
A more recent industrial standard is the European EN 13501-1 - Fire classification of construction products and building elements—which roughly replaces A2 with A2/B, B1 with C, B2 with D/E and B3 with F.
B3 or F rated materials may not be used in building unless combined with another material that reduces the flammability of those materials.
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