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Cerium(III) sulfate

From Wikipedia, the free encyclopedia
Cerium(III) sulfate
Cerium(III) sulfate
Cerium(III) sulfate
Names
IUPAC name
Cerium(III) sulfate
Other names
Cerous sulfate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.033.299Edit this at Wikidata
EC Number
  • 236-644-6, 246-392-9
UNII
  • InChI=1S/2Ce.3H2O4S/c;;3*1-5(2,3)4/h;;3*(H2,1,2,3,4)/q2*+3;;;/p-6
    Key: OZECDDHOAMNMQI-UHFFFAOYSA-H
  • [O-]S(=O)(=O)[O-].[O-]S(=O)(=O)[O-].[O-]S(=O)(=O)[O-].[Ce+3].[Ce+3]
Properties
Ce2(SO4)3
Molar mass568.42 g/mol (anhydrous)
AppearanceWhite to off white solid (anhydrous)
Density2.886 g/mL at (25 °C)
Melting point920 °C (1,690 °F; 1,190 K) (decomposes)
Boiling pointNA
9.25 g/100 mL (20 °C) Hygroscopic
Hazards
GHS labelling:
GHS07: Exclamation mark
Warning
H315,H319,H335
P261,P264,P271,P280,P302+P352,P304+P340,P305+P351+P338,P312,P321,P332+P313,P337+P313,P362,P403+P233,P405,P501
Safety data sheet (SDS)External MSDS
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound

Cerium(III) sulfate, also calledcerous sulfate, is aninorganic compound with the formula Ce2(SO4)3. It is one of the few salts whosesolubility in water decreases with rising temperature.[1]

Cerium(III) sulfate (anhydrous) is ahygroscopic white solid, which begins to decompose above 600°C. It has amonocliniccrystal structure.

Cerium(III) sulfate tetrahydrate is a white solid that releases itswater of crystallisation at 220 °C. It has (like the white octahydrate) a monoclinic crystal structure with the space groupP21/c (space group 14). The nonahydrate has a hexagonal crystal structure with the space groupP63/m (space group 176). Hydrates of this compound are known with 12, 9, 8, 5, 4 and 2 parts of water of crystallisation.

References

[edit]
  1. ^Daniel L. Reger; Scott R. Goode; David Warren Ball (2 January 2009).Chemistry: Principles and Practice. Cengage Learning. p. 482.ISBN 978-0-534-42012-3. Retrieved23 March 2013.

See also

[edit]
Cerium(II)
Cerium(III)
Organocerium(III)
Cerium(III,IV)
Cerium(IV)
Compounds containing thesulfate group (SO2−4)
H2SO4He
Li2SO4BeSO4B2S2O9
-BO3
+BO3
esters
ROSO3
(RO)2SO2
+CO3
+C2O4
(NH4)2SO4
[N2H5]HSO4
(NH3OH)2SO4
NOHSO4
+NO3
H2OSO4+FNe
Na2SO4
NaHSO4
MgSO4Al2(SO4)3
Al2SO4(OAc)4
Si+PO4SO2−4
HSO3HSO4
(HSO4)2
+SO3
+ClAr
K2SO4
KHSO4
CaSO4Sc2(SO4)3TiOSO4VSO4
V2(SO4)3
VOSO4
CrSO4
Cr2(SO4)3
MnSO4FeSO4
Fe2(SO4)3
CoSO4
Co2(SO4)3
NiSO4
Ni2(SO4)3
CuSO4
Cu2SO4
[Cu(NH3)4(H2O)]SO4
ZnSO4Ga2(SO4)3Ge(SO4)2+AsO4+SeO3+BrKr
RbHSO4
Rb2SO4
SrSO4Y2(SO4)3Zr(SO4)2Nb2O2(SO4)3MoO(SO4)2
MoO2(SO4)
TcRu(SO4)2Rh2(SO4)3PdSO4Ag2SO4
AgSO4
CdSO4In2(SO4)3SnSO4
Sn(SO4)2
Sb2(SO4)3TeOSO4I2(SO4)3
(IO)2SO4
+IO3
Xe
Cs2SO4
CsHSO4
BaSO4*Lu2(SO4)3Hf(SO4)2Ta(SO4)67–WO(SO4)2Re2O5(SO4)2OsSO4
Os2(SO4)3
Os(SO4)2
IrSO4
Ir2(SO4)3
Pt2(SO4)54–AuSO4
Au2(SO4)3
Hg2SO4
HgSO4
Tl2SO4
Tl2(SO4)3
PbSO4
Pb(SO4)2
Bi2(SO4)3PoSO4
Po(SO4)2
AtRn
FrRaSO4**LrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
 
*La2(SO4)3Ce2(SO4)3
Ce(SO4)2
Pr2(SO4)3Nd2(SO4)3Pm2(SO4)3Sm2(SO4)3EuSO4
Eu2(SO4)3
Gd2(SO4)3Tb2(SO4)3Dy2(SO4)3Ho2(SO4)3Er2(SO4)3Tm2(SO4)3Yb2(SO4)3
**Ac2(SO4)3Th(SO4)2(PaO)2(SO4)3
H3PaO(SO4)3
U2(SO4)3
U(SO4)2
UO2SO4
Np(SO4)2
(NpO2)2SO4
NpO2SO4
Pu(SO4)2
PuO2SO4
Am2(SO4)3
Am2O2SO4
Cm2(SO4)3
Cm2O2SO4
Bk2O2SO4Cf2(SO4)3
Cf2O2SO4
EsFmMdNo
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