GOC
No.
| First Lady or Gentlemen | Tenure | Governor
(Husband or wife, unless noted) |
|---|
| 1 | | January 1, 1991
–
December 31, 1994 | Jorge Manzur |
|---|
| 2 | María Cristina de la Espriella | January 1, 1995
–
December 31, 1997 | Carlos Buelvas |
|---|
| 3 | | January 1, 1998
–
December 31, 2000 | Ángel Villadiego |
|---|
| 4 | María Victoria Peña | January 1, 2001
–
December 31, 2003 | Jesús María López |
|---|
| 5 | Alicia Jiménez | January 1, 2004
–
December 31, 2007 | Libardo José López |
|---|
| 6 | Jairo Ruiz Chica | January 1, 2008
–
December 31, 2011 | Marta Sáenz |
|---|
| 7 | Johanna Elías Vidal | January 1, 2012
–
December 31, 2015 | Alejandro Lyons |
|---|
| 8 | Roxana Zuleta | January 1, 2016
–
December 31, 2019 | Edwin Besaile |
|---|
| 9 | Marta Ruiz | January 1, 2020
–
December 31, 2023 | Orlando Benítez |
|---|
| 10 | Valeria Vega | January 1, 2024
–
present | Erasmo Zuleta |
|---|
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