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Bromoiodomethane

From Wikipedia, the free encyclopedia
Bromoiodomethane
Stereo, skeletal formula of bromoiodomethane
Stereo, skeletal formula of bromoiodomethane
Spacefill model of bromoiodomethane
Spacefill model of bromoiodomethane
Names
Preferred IUPAC name
Bromo(iodo)methane
Other names
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.156.567Edit this at Wikidata
  • InChI=1S/CH2BrI/c2-1-3/h1H2 checkY
    Key: TUDWMIUPYRKEFN-UHFFFAOYSA-N checkY
  • BrCI
Properties
CH2BrI
Molar mass220.835 g·mol−1
AppearanceColourless liquid
Density2.93 g mL−1
Melting point1 °C; 34 °F; 274 K
Boiling point138 to 141 °C (280 to 286 °F; 411 to 414 K)
1.6382
Hazards
GHS labelling:
GHS05: CorrosiveGHS07: Exclamation mark
Danger
H315,H318,H335
P261,P280,P305+P351+P338
Related compounds
Related alkanes
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Chemical compound

Bromoiodomethane is ahalomethane with the formula BrCH2I. It is a colorless liquid, although older samples appear yellow. The compound has been investigated as a reagent forcyclopropanation by theSimmons-Smith reaction, butdiiodomethane andchloroiodomethane are preferred. It also occurs naturally as the result of microbial action.[1]

Its critical point is at 367.85 °C and 6.3 MPa and refractive index is 1.6382 (20 °C, D).

Additional reading

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References

[edit]
  1. ^Lim, Y.-K.; Phang, S.-M.; Rahman, N. Abdul; Sturges, W. T.; Malin, G. (2017). "REVIEW: Halocarbon Emissions from Marine Phytoplankton and Climate Change".Int. J. Environ. Sci. Technol.:1355–1370.doi:10.1007/s13762-016-1219-5.S2CID 99300836.

External links

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Unsubstituted
Monosubstituted
Disubstituted
Trisubstituted
Tetrasubstituted
*Chiral compound.


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