Borate sulfate

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Mixed anion compound containing separate borate and sulfate anions

Borate sulfates aremixed anion compounds containing separateborate andsulfate anions. They are distinct from theborosulfates where the borate is linked to a sulfate via a common oxygen atom.

List

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	chem	mw	crystal system	space group	unit cell Å	volume	density	comment	references
sulfoborite	Mg₃(OH)[B(OH)₄]₂(SO₄)F		orthorhombic	Pnma	a=10.132, b=12.537, c=7.775	987.6		Biaxial (-)n_α=1.527,n_β=1.536,n_γ=1.551 2V 79° Maxbirefringence δ=0.024	^[1]
Heidornite	Na₂Ca₃B₅O₈(OH)₂(SO₄)₂Cl		monoclinic	C2/c	a=10.19, b=7.76, c=18.81 β=93.33°Z=4	1,485	2.753	Biaxial (+)n_α=1.579,n_β=1.588,n_γ=1.604 2V 63° to 77° Max birefringence δ=0.025	^[2]
Charlesite	Ca₆Al(SO₄)₂B(OH)₄(O,OH)₁₂·26H₂O		trigonal	P3₁c	a = 11.161, c = 21.212	2,288	1.77	Uniaxial (-)n_ω=1.492(3),n_ε=1.475(3) Max birefringence δ=0.017	^[3]
Vitimite	Ca₆B₁₄O₁₉(SO₄)(OH)₁₄·5H₂O		monoclinic	P2/m	a=14.10, b=19.53, c=14.05 β=120.39°Z=4	3,337		Biaxial (-)n_α=1.532(3),n_β=1.537(1),n_γ=1.540(1) Max birefringence δ=0.008	^[4]
Harkerite	Ca₁₂Mg₄Al(BO₃)₃(SiO₄)₄(CO₃)₅·H₂O		trigonal	R3m	a=18.131 α=33.46°	1,614		Uniaxialn_α=1.651±2,n_β=1.651±2	^[5]
Tatarinovite	Ca₃Al(SO₄)[B(OH)₄](OH)₆·12H₂O		Hexagonal	P6₃	a=11.1110, c=10.6294	1,136	1.79	colourless Uniaxial (+)n_ω=1.475,n_ε=1.496 Max birefringence δ=0.021	^[6]
Sturmanite	Ca₆Fe3+2(SO₄)_2.5[B(OH)₄](OH)₁₂·25H₂O		trigonal	P3₁c	a=11.16, c=21.79 Z=2	2,350		yellow Uniaxial (+/-)n_ω=1.499-1.500,n_ε=1.501±4 Max birefringence δ=0.002	^[7]
	[Ni(atta)(SO₄)_0.5]·[B₅O₆(OH)₄]	514.13	monoclinic	P2₁/c	a=9.0512, b=15.2776, c=15.0142 β=90.325°Z=4	2076.14	1.645		^[8]
Buryatite	Ca₃(Si,Fe,Al)(SO₄)[B(OH₄)]O(OH)₅·12H₂O		trigonal	P3₁c	a=11.14, c=20.99 Z=4	2,256	1.89	Uniaxial (-)n_ω=1.523(3),n_ε=1.532(3) Max birefringence δ=0.009	^[9]
	Rb₃H(SO₄)₂(B₂O₃)₂		hexagonal	P6₃/m	a=6.502, c=19.02 Z=2		2.803		^[10]
Fontarnauite	Na₂Sr(SO₄)B₅O₈(OH)·2H₂O		monoclinic	P2₁/c	a=6.458, b=22.299, c=8.571 β=103.05°Z=4	1,203			^[11]
	Y(SO₄)[B(OH₄)](H₂O)·H₂O		triclinic	P1	a=5.9679, b=6.8559, c=10.1698 α=79.608°, β=76.673°, γ=89.220° Z=2	398.02	2.502		^[12]
	Cs₃H(SO₄)₂(B₂O₃)₂		hexagonal	P6₃/m	a = 6.5648, c = 19.5669 Z = 2		3.322		^[10]
	La(SO₄)[B(OH)₄](H₂O)	331.83	triclinic	P1	a=6.2808, b=6.8321, c=8.6830 α=82.475°, β=76.758°, γ=87.300° Z=2	359.51	3.065		^[12]
	Pr(SO₄)[B(OH)₄](H₂O)₂	351.84	monoclinic	P2₁/m	a=6.2359, b=9.5542, c=6.8236 β=93.852° Z=2	405.64	2.881		^[12]
	Nd(SO₄)[B(OH)₄](H₂O)₂	355.17	monoclinic	P2₁/m	a=6.2119, b=9.5328, c=6.7923 β=93.755° Z=2	401.35	2.939		^[12]
	Sm(SO₄)[B(OH)₄](H₂O)	343.27	triclinic	P1	a=6.1467, b=6.7280, c=8.6068 α=81.769°, β=76.653°, γ=87.259° Z=2	342.71	3.326		^[12]
	Sm(SO₄)[B(OH)₄](H₂O)₂	361.30	monoclinic	P2₁/m	a=6.1601, b=9.5416, c=6.7589 β=93.816° Z=2	396.39	3.027		^[12]
	Eu(SO₄)[B(OH)₄](H₂O)	344.88	triclinic	P1	a=6.1205, b=6.7090, c=8.5844 α=81.713°, β=76.680°, γ=87.294° Z=2	339.40	3.375		^[12]
	Eu(SO₄)[B(OH)₄](H₂O)₂	362.89	monoclinic	P2₁/m	a=6.1322, b=9.5139, c=6.7343 β=93.683° Z=2	392.08	3.074		^[12]
	Gd(SO₄)[B(OH)₄](H₂O)₂	368.19	monoclinic	P2₁/m	a=6.1148, b=9.5078, c=6.7164 β=93.611° Z=2	389.70	3.138		^[12]
	Tb(SO₄)[B(OH)₄](H₂O)·H₂O	369.87	triclinic	P1	a=6.0139, b=6.8972, c=10.1753 α=79.616°, β=76.590°, γ=89.106° Z=2	403.42	3.045		^[12]
	Dy(SO₄)[B(OH)₄](H₂O)·H₂O	373.43	triclinic	P1	a=5.9880, b=6.8728, c=10.1638 α=79.652°, β=76.597°, γ=89.153°Z=2	400.12	3.100		^[12]
	Ho(SO₄)[B(OH)₄](H₂O)·H₂O	375.86	triclinic	P1	a=5.9701, b=6.8570, c=10.1580 α=79.588°, β=76.636°, γ=89.193°Z=2	397.75	3.138		^[12]
	Er(SO₄)[B(OH)₄](H₂O)·H₂O	378.19	triclinic	P1	a=5.9529, b=6.8401, c=10.1553 α=79.598°, β=76.642°, γ=89.198° Z=2	395.54	3.175		^[12]
	Tm(SO₄)[B(OH)₄](H₂O)·H₂O	379.86	triclinic	P1	a=5.9289, b=6.8232, c=10.1422 α=79.531°, β=76.663°, γ=89.263° Z=2	392.40	3.215		^[12]
	Yb(SO₄)[B(OH)₄](H₂O)·H₂O	383.97	triclinic	P1	a=5.9150, b=6.8090, c=10.1454 α=79.541°, β=76.669°, γ=89.243° Z=2	390.82	3.263		^[12]
	Lu(SO₄)[B(OH)₄](H₂O)·H₂O	385.91	triclinic	P1	a=5.8992, b=6.7954, c=10.1322 α=79.551°, β=76.691°, γ=89.266° Z=2	388.53	3.299		^[12]
	Pb₂[(BO₂)(OH)](SO₄)	570.26	monoclinic	P2₁/m	a=6.982, b=5.3917, c=8.167 β=98.643°	303.9	6.231	decompose 335 °C (635 °F); band gap4.08 eV	^[13]
	Pb₄(BO₃)₂(SO₄)	1042.44	monoclinic	P2₁/c	a=6.9363, b=15.8784, c=9.6053 β=110.770° Z=4	989.15	7.000	melt 689 °C (1,272 °F); band gap4.03 eV	^[13]^[14]
	Na₂PbB₆O₁₀SO₄		orthorhombic	Pnma	a=12.9566, b=9.9289, c=7.8800 Z=4	1013.7	3.762		^[15]
	Ca_2.58Pb_0.42B₆O₁₁SO₄		monoclinic	P12₁/c1	a=6.4716, b=17.2900, c=9.1455 β=90.411°Z=4	1023.30	3.423		^[15]

References

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^"Sulfoborite".www.mindat.org. Retrieved2020-12-15.
^"Heidornite".www.mindat.org. Retrieved2020-12-15.
^"Charlesite".www.mindat.org. Retrieved2020-12-15.
^"Vitimite".www.mindat.org. Retrieved2020-12-14.
^"Harkerite".www.mindat.org. Retrieved2020-12-14.
^"Tatarinovite".www.mindat.org. Retrieved2020-12-15.
^"Sturmanite".www.mindat.org. Retrieved2020-12-15.
^Li, Wei; Deng, Yan-Ling; Pan, Chun-Yang (2022-05-11)."Structural Characterization and ORR Activity of a Copper Complex Borate and an Unexpected [Ni(atta)(SO₄)_0.5] + Borate-Sulfate".Inorganic Chemistry.61 (20):7787–7793.doi:10.1021/acs.inorgchem.2c00187.ISSN 0020-1669.PMID 35543612.S2CID 248695560.
^"Buryatite".www.mindat.org. Retrieved2020-12-15.
^^a ^bDaub, Michael; Hillebrecht, Harald (September 2015). "Borosulfates Cs₂B₂S₃O₁₃, Rb₄B₂S₄O₁₇, and A₃HB₄S₂O₁₄ (A = Rb, Cs) - Crystalline Approximants for Vitreous B₂O₃".European Journal of Inorganic Chemistry.2015 (25):4176–4181.doi:10.1002/ejic.201500603.
^Cooper, Mark A.; Hawthorne, Frank C.; García-Veigas, Javier; Alcobé, Xavier; Helvaci, Cahit; Grew, Edward S.; Ball, Neil A. (September 2015)."Fontarnauite, (Na,K)₂(Sr,Ca)(SO₄)[B₅O₈(OH)](H₂O)₂, A New Sulfate-Borate Mineral From Doğanlar (Emet), Kütahya Province, Western Anatolia, Turkey".The Canadian Mineralogist.53 (5):803–820.Bibcode:2015CaMin..53..803C.doi:10.3749/canmin.1400088.ISSN 0008-4476.
^^a ^b ^c ^d ^e ^f ^g ^h ⁱ ^j ^k ^l ^m ⁿ ^o ^pWang, Wen-Wen; Xu, Xiang; Kong, Jin-Tao; Mao, Jiang-Gao (2018-01-02)."RE(SO₄)[B(OH)₄](H₂O), RE(SO₄)[B(OH)₄](H₂O)₂, and RE(SO₄)[B(OH)₄](H₂O)·H₂O: Rare-Earth Borate-Sulfates Featuring Three Types of Layered Structures".Inorganic Chemistry.57 (1):163–174.doi:10.1021/acs.inorgchem.7b02317.ISSN 0020-1669.PMID 29240405.
^^a ^bRuan, Ting-Ting; Wang, Wen-Wen; Hu, Chun-Li; Xu, Xiang; Mao, Jiang-Gao (April 2018)."Pb₄(BO₃)₂(SO₄) and Pb₂[(BO₂)(OH)](SO₄): New lead(II) borate-sulfate mixed-anion compounds with two types of 3D network structures".Journal of Solid State Chemistry.260:39–45.Bibcode:2018JSSCh.260...39R.doi:10.1016/j.jssc.2018.01.013.
^Xie, Huiyuan; Wang, Fu; Liao, Biru; Liao, Xiaomin; Chen, Jiayu; Yu, Yang; Hou, Seng; Fan, Xiaoyun (September 2021). "A novel double anion layered photocatalyst Pb₄(BO₃)₂SO₄ with enhanced photocatalytic performance for antibiotic degradation".Chemical Engineering Journal.429 132344.doi:10.1016/j.cej.2021.132344.ISSN 1385-8947.S2CID 239660006.
^^a ^bPei, Huan; Li, Zijian; Liu, Shaohuan; Hou, Xueling; Zhang, Fangfang (2025)."Na2PbB6O10SO4 and Ca2.58Pb0.42B6O11SO4: First Borate-Sulfates Featuring 3D Porous Borate Anionic Frameworks".Inorganic Chemistry Frontiers.doi:10.1039/D5QI00394F.ISSN 2052-1553.

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