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Bismuth iodate

From Wikipedia, the free encyclopedia
Bismuth iodate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.033.834Edit this at Wikidata
EC Number
  • 237-233-4
  • InChI=1S/Bi.3HIO3/c;3*2-1(3)4/h;3*(H,2,3,4)/q+3;;;/p-3
    Key: FGQDLCIITXBKAR-UHFFFAOYSA-K
  • dihydrate: InChI=1S/Bi.3HIO3.2H2O.6H/c;3*2-1(3)4;;;;;;;;/h;3*(H,2,3,4);2*1H2;;;;;;/q+3;;;;;;;;;;;/p-3
    Key: ZXENQEZTERBKRJ-UHFFFAOYSA-K
  • [Bi+3].[O-][I](=O)=O.[O-][I](=O)=O.[O-][I](=O)=O
  • dihydrate: [Bi+3].[O-][I](=O)=O.[O-][I](=O)=O.[O-][I](=O)=O.O.O
Properties
Bi(IO3)3
Molar mass733.69
Appearancecolourless crystals (dihydrate)[1]
Density6.096 g (anhydrous)[2]
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Bismuth iodate is an inorganic compound with the chemical formula Bi(IO3)3. Its anhydrate can be obtained by reactingbismuth nitrate andiodic acid, dissolving the resulting precipitate in 7.8 mol/Lnitric acid, and heating to volatilize and crystallize at 70 °C;[2] The dihydrate can be obtained by reacting bismuth nitrate andpotassium iodate orsodium iodate. It is obtained by evaporation and crystallization in 7 mol/L nitric acid at 50 °C.[1] Its basic salt BiOIO3 is known.[3]

References

[edit]
  1. ^abPhanon, D.; Gautier-Luneau, I. (Sep 2006)."Crystal structure of bismuth triiodate dihydrate, Bi[IO3]3 · 2H2O".Zeitschrift für Kristallographie - New Crystal Structures.221 (3):243–244.doi:10.1524/ncrs.2006.0056.ISSN 2197-4578.
  2. ^abBentria, Bachir; Benbertal, Djamal; Bagieu-Beucher, Muriel; Masse, René; Mosset, Alain (2003)."Crystal structure of anhydrous bismuth iodate, Bi(IO3)3".Journal of Chemical Crystallography.33 (11):867–873.doi:10.1023/A:1027409929990.
  3. ^Huang, Hongwei; Chen, Fang; Reshak, Ali Hussain; Auluck, Sushil; Zhang, Yihe (Nov 2018)."Insight into crystal-structure dependent charge separation and photo-redox catalysis: A combined experimental and theoretical study on Bi(IO3)3 and BiOIO3".Applied Surface Science.458:129–138.doi:10.1016/j.apsusc.2018.07.054.
Bismuth(III)
Organobismuth(III)
Bismuth(V)
Organobismuth(V)
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