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Barium sulfite

From Wikipedia, the free encyclopedia
Barium sulfite
Structure of barium sulfite
Structure of barium sulfite
Names
IUPAC name
Barium sulfite
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.029.193Edit this at Wikidata
UNII
  • InChI=1S/Ba.H2O3S/c;1-4(2)3/h;(H2,1,2,3)/q+2;/p-2 checkY
    Key: ARSLNKYOPNUFFY-UHFFFAOYSA-L checkY
  • InChI=1/Ba.H2O3S/c;1-4(2)3/h;(H2,1,2,3)/q+2;/p-2
    Key: ARSLNKYOPNUFFY-NUQVWONBAA
  • [Ba+2].[O-]S([O-])=O
Properties
BaSO3
Molar mass217.391 g/mol
Appearancewhitemonoclinic crystals
Density4.44 g/cm3
Melting pointdecomposes
0.0011 g/100 mL
Solubilityinsoluble inethanol[1]
Related compounds
Otheranions
Barium sulfate
Barium fluoride
Barium chloride
Barium bromide
Barium iodide
Othercations
Calcium sulfite
Magnesium sulfite
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Chemical compound

Barium sulfite is theinorganic compound with thechemical formula BaSO3. It is a white powder that finds few applications. It is an intermediate in thecarbothermal reduction ofbarium sulfate tobarium sulfide:[2]

BaSO4 + CO → BaSO3 + CO2

References

[edit]
  1. ^Lide, David R. (1998),Handbook of Chemistry and Physics (87 ed.), Boca Raton, Florida: CRC Press, pp. 4–45,ISBN 0-8493-0594-2
  2. ^Kresse, Robert; Baudis, Ulrich; Jäger, Paul; Riechers, H. Hermann; Wagner, Heinz; Winkler, Jochen; Wolf, Hans Uwe (2007). "Barium and Barium Compounds".Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH.doi:10.1002/14356007.a03_325.pub2.ISBN 978-3527306732.
Compounds containing thesulfite group (SO2−3)
H2SO3He
Li2SO3BeBC(NH4)2SO3
NSO2
OSO2FNe
Na2SO3MgSO3·x(H2O)AlSiP+SO4+ClAr
K2SO3CaSO3·x(H2O)ScTiVCrMnFeCoNiCuSO3·Cu2SO3·x(H2O)ZnGaGeAsSeBrKr
RbSrYZrNbMoTcRuRhPdAg2SO3CdInSnSbTeIXe
CsBaSO3*LuHfTaWReOsIrPtAuHgTlPbBiPoAtRn
FrRa**LrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
 
*LaCePrNdPmSmEuGdTbDyHoErTmYb
**AcThPaUNpPuAmCmBkCfEsFmMdNo


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