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Attosecond

From Wikipedia, the free encyclopedia
One quintillionth of a second

attosecond
Unit systemSI
Unit oftime
Symbolas
Conversions
1 asin ...... is equal to ...
   SI units   10−18 s

Anattosecond (abbreviated asas) is aunit of time in theInternational System of Units (SI) equal to 10−18 or11 000 000 000 000 000 000 (one quintillionth) of asecond.[1]

An attosecond is to a second, as a second is to approximately 31.69 billion years.[2]

The attosecond is a tiny unit, but it has various potential applications: it can observe oscillating molecules, the chemical bonds formed by atoms in chemical reactions, and other extremely tiny and extremely fast things.

One attosecond is equal to 1000zeptoseconds, or 1/1000femtosecond. Because the next SI unit is 1000 times larger, measurements of 10−17 and 10−16 second are typically expressed as tens or hundreds of attoseconds.

Common measurements

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  • 0.247 attoseconds: travel time of aphoton across "the average bond length of molecular hydrogen"[3]
  • 24.189... attoseconds: theatomic unit of time[4]
  • 43 attoseconds: the shortest pulses of laser light yet created[5]
  • 53 attoseconds: the shortest electron laser pulse ever created[6][7]
  • 53 attoseconds: the second-shortest pulses of laser light created[8][9]
  • 82 attoseconds (approximately):half-life ofberyllium-8, maximum time available for thetriple-alpha process for the synthesis of carbon and heavier elements in stars[10]
  • 84 attoseconds: the approximatehalf-life of aneutral pion
  • 100 attoseconds: fastest-ever view of molecular motion[11]
  • 320 attoseconds: the estimated time it takeselectrons to transfer between atoms[12][13]

Historical development

[edit]

In 2001,Ferenc Krausz and his team at theTechnical University of Vienna fired an ultrashort wavelength (7 femtoseconds) red laser pulse into a stream ofneon atoms, where the stripped electrons were carried by the pulse and almost immediately re-ejected into the neon nucleus.[14]

While capturing the attosecond pulse, the physicists also demonstrated its utility. They aimed attosecond and longer-wavelength red pulses at a type of krypton atom simultaneously: first, the electrons were knocked off; then, the red light pulse hit the electrons; finally, the energy was tested. Judging from the difference in the timing of these two pulses, the scientists obtained a very precise measurement of how long it took the electron to decay (how many attoseconds). Never before have scientists used such a short time scale to study the energy of electrons.[15]

Applications

[edit]

Need for more precise units

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Thecrystal lattice vibrates and molecules rotate on a scale ofpicoseconds. The creation and breaking of chemical bonds and molecular vibration happen in femtoseconds. Observing the motion of electrons happens on the attosecond scale.[16]

The number of electrons in an atom and theirconfiguration define anelement. Because attosecond pulses are faster than the motion of electrons in atoms and molecules, attosecond provides a new tool for controlling and measuringquantum states of matter.[17] These pulses have been used to explore the detailed physics of atoms and molecules and have potential applications in fields ranging from electronics to medicine.[18]

Directly observing the wave oscillations of light

[edit]

Using a method calledattosecond streaking, people can see the electrical components ofEM waves. Scientists start with a gas of neon atoms and ionize them with a single ultrashort burst ofUV radiation measured in attoseconds. The electric field of theinfrared can then strongly influence the motion of the electrons. The electrons will be forced up and down as the field oscillates. Depending on when the electron is released, this process will emit different final energies. The final measurement of the electron's energy, as a function of the relative delay between the two pulses, clearly shows the traces of the electric field of the attosecond pulse.[19]

Short pulses of light

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The 2023Nobel Prize in Physics wasawarded toPierre Agostini,Ferenc Krausz, andAnne L'Huillier for demonstrating a way to create "almost unimaginably" shortpulses of light, measured in attoseconds. These pulses can be used to capture and study rapid processes insideatoms, such as the behavior of electrons.[20][21]

See also

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References

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  1. ^"attosecond - Memidex dictionary/thesaurus". 7 April 2019. Archived fromthe original on 7 April 2019. Retrieved24 October 2023.
  2. ^"Exploring "Attosecond" Time - Steacie Institute for Molecular Sciences (SIMS)". 11 November 2007. Archived fromthe original on 11 November 2007. Retrieved24 October 2023.
  3. ^Grundmann, Sven; Trabert, Daniel; Fehre, Kilian; Strenger, Nico; Pier, Andreas; Kaiser, Leon; Kircher, Max; Weller, Miriam; Eckart, Sebastian; Schmidt, Lothar Ph. H.; Trinter, Florian; Jahnke, Till; Schöffler, Markus S.; Dörner, Reinhard (16 October 2020)."Zeptosecond birth time delay in molecular photoionization".Science.370 (6514):339–341.arXiv:2010.08298.Bibcode:2020Sci...370..339G.doi:10.1126/science.abb9318.ISSN 0036-8075.PMID 33060359.S2CID 222412229.
  4. ^"CODATA Value: atomic unit of time".physics.nist.gov. Retrieved24 October 2023.
  5. ^"Optica Publishing Group".opg.optica.org. Retrieved24 October 2023.
  6. ^Kim, H. Y.; Garg, M.; Mandal, S.; Seiffert, L.; Fennel, T.; Goulielmakis, E. (January 2023)."Attosecond field emission".Nature.613 (7945):662–666.doi:10.1038/s41586-022-05577-1.ISSN 1476-4687.PMC 9876796.PMID 36697865.
  7. ^"Attosecond electron pulses are claimed as shortest ever".Physics World. 17 February 2023. Retrieved17 February 2023.
  8. ^Li, Jie; Ren, Xiaoming; Yin, Yanchun; Zhao, Kun; Chew, Andrew; Cheng, Yan; Cunningham, Eric; Wang, Yang; Hu, Shuyuan; Wu, Yi; Chini, Michael; Chang, Zenghu (4 August 2017)."53-attosecond X-ray pulses reach the carbon K-edge".Nature Communications.8 (1): 186.Bibcode:2017NatCo...8..186L.doi:10.1038/s41467-017-00321-0.ISSN 2041-1723.PMC 5543167.PMID 28775272.
  9. ^"Watching quantum mechanics in action: Researchers create world record laser pulse".ScienceDaily. Retrieved24 October 2023.
  10. ^"Beryllium-8",Wikipedia, 21 June 2023, retrieved24 October 2023
  11. ^"Fastest view of molecular motion". 4 March 2006. Retrieved24 October 2023.
  12. ^"Electron timed hopping between atoms | New Scientist". 11 May 2016. Archived fromthe original on 11 May 2016. Retrieved24 October 2023.
  13. ^Föhlisch, A.; Feulner, P.; Hennies, F.; Fink, A.; Menzel, D.; Sanchez-Portal, D.; Echenique, P. M.; Wurth, W. (1 July 2005)."Direct observation of electron dynamics in the attosecond domain".Nature.436 (7049):373–376.Bibcode:2005Natur.436..373F.doi:10.1038/nature03833.ISSN 0028-0836.PMID 16034414.S2CID 4411563.
  14. ^"Attosecond Physics becomes a Milestone".www.mpq.mpg.de. Retrieved24 October 2023.
  15. ^Krausz, Ferenc (2016)."The birth of attosecond physics and its coming of age".Physica Scripta.91 (6).Bibcode:2016PhyS...91f3011K.doi:10.1088/0031-8949/91/6/063011.S2CID 124590030.
  16. ^"The Nobel Prize in Chemistry 1999".NobelPrize.org. Retrieved24 October 2023.
  17. ^Canada, National Research Council (15 June 2017)."Importance of attosecond research".www.canada.ca. Retrieved4 November 2023.
  18. ^"The Nobel Prize in Physics 2023".NobelPrize.org. Retrieved5 November 2023.
  19. ^Goulielmakis, E.; Uiberacker, M.; Kienberger, R.; Baltuska, A.; Yakovlev, V.; Scrinzi, A.; Westerwalbesloh, Th.; Kleineberg, U.; Heinzmann, U.; Drescher, M.; Krausz, F. (27 August 2004)."Direct Measurement of Light Waves".Science.305 (5688):1267–1269.Bibcode:2004Sci...305.1267G.doi:10.1126/science.1100866.ISSN 0036-8075.PMID 15333834.S2CID 38772425.
  20. ^Gill, Victoria (3 October 2023)."Nobel Prize for 'attosecond physicists' Agostini, L'Huillier and Krausz".BBC. Retrieved8 May 2024.
  21. ^Bubola, Emma; Miller, Katrina (3 October 2023)."Nobel Prize in Physics Awarded to 3 Scientists for Illuminating How Electrons Move".The New York Times. Retrieved8 May 2024.
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