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Arsenide chloride

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Arsenide chlorides orchloride arsenides are compounds containing anions composed of chloride (Cl⁻) and arsenide (As³⁻). They can be considered asmixed anion compounds. They are in the category ofpnictidehalides. Related compounds include thearsenide bromides,arsenide iodides,phosphide chlorides, andantimonide chlorides.

List

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formula	system	space group	unit cell Å	volume	density	comment	ref
Ca₃AsCl₃		Pm3m	a= 5.760				^[1]
Sr₂AsCl						dark violet	^[2]
Cd₈As₇Cl	cubic	P23	a=7.266,Z=1				^[3]
Hg_7.4As₄Cl₆	cubic	Pa3	a= 12.178,Z= 4				^[4]
(Hg₆As₄)(HgCl₆)Hg_0.5	cubic	Pa3	a=12.189 Z=4	1810.7	7.398	yellow; air stable; band gap 2.01	^[5]
(Hg₆As₄)[TiCl₆]Cl	cubic	Pa3	a = 1209.4				^[6]
[Hg₄As₂][ZrCl₆]	orthorhombic	Pbca	a=13.277 b=13.420 c=16.814 Z=8	2769.1	5.570	dark yellow	^[7]
[Hg₄As₂][HfCl₆]	orthorhombic	Pbca	a=13.273 b=13.413 c=16.809 Z=8	2992	5.964	orange	^[7]
(Hg₃AsS)(GaCl₄)	hexagonal	P6₃/mc	a =7.245,c =11.960 ,Z = 2	543.6	5.622	light yellow	^[8]
Hg₃AsS₄Cl	hexagonal	P6₃mc	a = 7.431,c = 9.003 Z=2			yellow; air stable	^[9]
[Hg₆As₄](CuCl₃)₂	monoclinic	I2/a	a = 14.690,b = 9.1851,c = 20.285, β=92.170, Z=6				^[10]
(Hg_9.75As_5.5)(GaCl₄)₃	orthorhombic	Pmn2₁	a=22.567 b=12.146 c=12.983 Z=4	3559	5.604		^[11]
(Hg₆As₄)[MoCl₆]Cl	cubic	Pa3	a = 12.078				^[6]
[Hg₆As₄](AgCl₃)₂	monoclinic	I2/a	a = 14.690,b = 9.1851,c = 20.285,β = 93.17°,Z = 4				^[10]^[12]
(Hg₆As₄)(CdCl₆)Hg_0.5	cubic	Pa3	a=12.172 Z=4	1803.2	7.104	yellow; air stable; band gap 2.05	^[5]
[Hg₆As₄](InCl₆)Cl	cubic	Pa3	a = 12.109,Z = 4			dark red	^[13]
[Hg₆As₄Cl₃](SnCl₃)Hg_0.13	cubic	P2₁3	a=12.233 Z=4				^[14]
Hg₃As₂TlCl₃	orthorhombic	Pbcm	a = 6.292,b = 12.341c = 12.248 Z=4			red	^[15]
Hg₆As₄BiCl₇	cubic	Pa3	a=12.178 Z=4				^[16]
[Hg₄As₂][UCl₆]	orthorhombic	Pbca	a=13.316 b=13.636 c=16.853 Z=8	3060.0	6.090	red	^[7]^[17]

References

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^Hadenfeldt, C.; Vollert, H. O. (August 1982)."Darstellung, thermisches Verhalten und Kristallstruktur des Calciumarsenidchlorids Ca3AsCl3".Zeitschrift für anorganische und allgemeine Chemie (in German).491 (1):113–118.Bibcode:1982ZAACh.491..113H.doi:10.1002/zaac.19824910115.ISSN 0044-2313.
^Hadenfeldt, Claus (1976-04-01)."Darstellung und Eigenschaften von Ca 2 AsBr, Sr 2 AsCl und Ca 3 AsBr 3 .: Preparation and Properties of Ca 2 AsBr, Sr 2 AsCl, and Ca 3 AsBr 3".Zeitschrift für Naturforschung B.31 (4):408–410.doi:10.1515/znb-1976-0403.ISSN 1865-7117.S2CID 95122668.
^Shevelkov, Andrei V.; Reshetova, Ludmila N.; Popovkin, Boris A. (December 1997)."Cd8As7Cl: A Novel Pnictidohalide with a New Structure Type".Journal of Solid State Chemistry.134 (2):282–285.Bibcode:1997JSSCh.134..282S.doi:10.1006/jssc.1997.7555.
^Shevelkov, Andrei V.; Dikarev, Evgeny V.; Popovkin, Boris A. (November 1996)."Two New Cubic Structures of Mercury Arsenidehalides".Journal of Solid State Chemistry.126 (2):324–327.Bibcode:1996JSSCh.126..324S.doi:10.1006/jssc.1996.0344.
^^a ^bZou, Jian-Ping; Li, Yan; Fu, Ming-Lai; Guo, Guo-Cong; Xu, Gang; Liu, Xue-Hui; Zhou, Wei-Wei; Huang, Jin-Shun (March 2007)."The Synthesis, Crystal and Band Structures, and Properties of the Quaternary Supramolecular Complexes [Hg 6 Z 4 ](MX 6 )Hg y (Z = As, Sb; M = Hg, Cd; X = Cl, Br, I; y = 0, 0.5, 0.6)".European Journal of Inorganic Chemistry.2007 (7):977–984.Bibcode:2007EJIC.2007..977Z.doi:10.1002/ejic.200600894.ISSN 1434-1948.
^^a ^bBeck, Johannes; Neisel, Udo (2000). "Synthese, Kristallstrukturen und Magnetismus von (Hg6As4)[MoCl6]Cl, (Hg6As4)[TiCl6]Cl und (Hg6As4)[TiBr6]Br".Zeitschrift für Anorganische und Allgemeine Chemie.626 (7):1620–1626.doi:10.1002/1521-3749(200007)626:7<1620::AID-ZAAC1620>3.0.CO;2-R.
^^a ^b ^cLi, Xiao-Guo; Jiang, Xiao-Ming; Zhang, Ming-Jian; Liu, Bin-Wen; Fan, Yu-Hang; Guo, Guo-Cong; Huang, Jin-Shun (2013-12-02)."Three-Dimensional Mercury Pnictide [Hg 4 Z 2 ] 2+ Cationic Frameworks Stabilized by Tetravalent Metal Halide Anions in Supramolecular Complexes: [Hg 4 Z 2 ][MCl 6 ] (Z = P, As; M = Zr, Hf)".European Journal of Inorganic Chemistry.2013 (35):5980–5986.Bibcode:2013EJIC.2013.5980L.doi:10.1002/ejic.201300888.ISSN 1434-1948.
^Jiang, Xiao-Ming; Li, Xiao-Guo; Fan, Yu-Hang; Liu, Bin-Wen; Zeng, Hui-Yi; Guo, Guo-Cong (2013)."New mercury-contained cationic frameworks stabilized by (GaCl4)− unit via weak electrostatic forces in supramolecular compounds (Hg11P4)(GaCl4)4 and (Hg3AsS)(GaCl4)".Dalton Transactions.42 (43):15475–15481.doi:10.1039/c3dt51451j.ISSN 1477-9226.PMID 24022795.
^Beck, Johannes; Hedderich, Sylvia; Köllisch, Klaus (2000-12-01)."Hg 3 AsE 4 X (E = S, Se; X = Cl, Br, I), a Family of Isotypic Compounds with an Acentric, Layered Structure".Inorganic Chemistry.39 (25):5847–5850.doi:10.1021/ic0003527.ISSN 0020-1669.PMID 11151388.
^^a ^bOleneva, Olga S.; Olenev, Andrei V.; Dikarev, Evgeny V.; Shevelkov, Andrei V. (June 2005)."Solid State Supramolecular Complexes [Hg6As4](CuX3)2 (X = Cl, Br): One-Dimensional Helical Guest in a Three-Dimensional Host Framework".Journal of Cluster Science.16 (2):273–285.doi:10.1007/s10876-005-4548-y.ISSN 1040-7278.S2CID 95453360.
^Jiang, Xiao-Ming; Yan, Zhi-Bo; Liu, Dan; Wang, Ke-Feng; Guo, Guo-Cong; Li, Shao-Zhen; Liu, Jun-Ming (October 2014)."Large and Fast Single-Crystal Resistive Humidity Sensitivity of Metal Pnictide Halides Containing van der Waals Host-Guest Interactions".Chemistry: An Asian Journal.9 (10):2872–2879.doi:10.1002/asia.201402572.PMID 25110860.
^Oleneva, Olga S.; Olenev, Andrei V.; Dikarev, Evgeny V.; Shevelkov, Andrei V. (October 2004)."From Discrete to Extended Guests: A Novel Supramolecular [Hg 6 As 4 ](AgCl 3 ) 2 Assembly Featuring One-Dimensional (AgCl 3 ) 2− Anions".European Journal of Inorganic Chemistry.2004 (20):4006–4010.Bibcode:2004EJIC.2004.4006O.doi:10.1002/ejic.200400205.ISSN 1434-1948.
^Olenev, A. V.; Baranov, A. I.; Shatruk, M. M.; Tyablikov, A. S.; Shevelkov, A. V. (2002)."Synthesis and the crystal structure of [Hg₆As_4](InCl₆)Cl: influence of covalent and electrostatic factors on the supramolecular structure".Russian Chemical Bulletin.51 (3):444–448.doi:10.1023/A:1015500116907.S2CID 92070325.
^Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions".European Journal of Inorganic Chemistry.2002 (3):547–553.doi:10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N.
^Beck, Johannes; Neisel, Udo (2001). "Polykationische Hg-Pnictid-Gerüste mit einer neuen Füllungsvariante in den Strukturen von Hg3As2TlCl3 und Hg3Sb2TlBr3".Zeitschrift für Anorganische und Allgemeine Chemie.627 (8):2016–2022.doi:10.1002/1521-3749(200108)627:8<2016::AID-ZAAC2016>3.0.CO;2-N.
^Beck, Johannes; Hedderich, Sylvia; Neisel, Udo (November 2000)."Synthesis and Crystal Structures of Hg6Sb5Br7, Hg6As4BiCl7, and Hg6Sb4BiBr7, Built of a Polycationic Mercury-Pnictide Framework with Trapped Anions".Journal of Solid State Chemistry.154 (2):350–355.Bibcode:2000JSSCh.154..350B.doi:10.1006/jssc.2000.8794.
^Bugaris, Daniel E.; Ibers, James A. (December 2008)."Syntheses, structures, and magnetic and optical properties of the compounds [Hg3Te2][UCl6] and [Hg4As2][UCl6]".Journal of Solid State Chemistry.181 (12):3189–3193.Bibcode:2008JSSCh.181.3189B.doi:10.1016/j.jssc.2008.08.019.

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