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Andradite

From Wikipedia, the free encyclopedia
Nesosilicate mineral species of garnet
Andradite [Adr]
Single crystal (4.2 cm) – Diakon, Nioro du Sahel Circle, Kayes Region, Mali
General
CategoryGarnet group
FormulaCa3Fe2(SiO4)3
IMA symbolAdr[1]
Strunz classification9.AD.25
Crystal systemCubic
Crystal classHexoctahedral (m3m)
H-M symbol: (4/m3 2/m)
Space groupIa3d
Unit cella = 12.056 Å; Z = 8
Identification
ColorYellow, greenish yellow to emerald-green, dark green; brown, brownish red, brownish yellow; grayish black, black; may be sectored
Crystal habitCommonly well-crystallized dodecahedra, trapezohedra, or combinations, also granular to massive
Cleavagenone
Fractureconchoidal to uneven
TenacityBrittle
Mohs scale hardness6.5 to 7
LusterAdamantine to resinous, dull
StreakWhite
DiaphaneityTransparent to translucent
Specific gravity3.859 calculated; 3.8–3.9 measured
Optical propertiesIsotropic, typically weakly anisotropic
Refractive indexn = 1.887
Absorption spectrademantoid – 440 nm band or complete absorption at 440 nm and below, may also have lines at 618, 634, 685, 690 nm[2]
References[2][3][4][5]
Major varieties
Demantoidtransparent light to dark green to yellow-green
Melaniteopaque black
Topazolitetransparent to translucent yellow, may showchatoyancy

Andradite is amineral species of thegarnet group. It is anesosilicate, with formula Ca3Fe2Si3O12.

Andradite includes three varieties:

  • Colophonite: a historical variety found in the Scandinavian islands, brownish or reddish in color, often opaque or translucent.[6]: 61 
  • Demantoid: Vivid green in color, one of the most valuable and rare stones in thegemological world.[7]
  • Melanite: Black in color due to limited substitution oftitanium for iron. Also known as "titanian andradite". Forms a solid solution withmorimotoite andschorlomite depending on titanium and iron content.[8]
  • Topazolite: Yellow-green in color and sometimes of high enough quality to be cut into a facetedgemstone, it is rarer than demantoid.[7]

It was first described in 1868 for an occurrence inDrammen,Buskerud,Norway.[3][4][7] Andradite was named after theBrazilian statesman, naturalist, professor and poetJosé Bonifácio de Andrada e Silva (1763–1838).[3][7]

Occurrence

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It occurs inskarns developed incontact metamorphosed impurelimestones or calcicigneous rocks; in chloriteschists andserpentinites and in alkalicigneous rocks (typicallytitaniferous). Associated minerals includevesuvianite,chlorite,epidote,spinel,calcite,dolomite andmagnetite.[3] It is found inIran,Italy, theUral Mountains ofRussia,Arizona andCalifornia and inDnipropetrovsk Oblast inUkraine.

Like the other garnets, andradite crystallizes in the cubicspace group [[Ia3d]], with unit-cell parameter of 12.051 Å at 100 K.[9]

Thespin structure of andradite contains two mutually canted equivalentantiferromagnetic sublattices[10] below theNéel temperature (TN=11 K[11]).

  • Black crystals of andradite: melanite
    Black crystals of andradite: melanite

See also

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References

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  1. ^Warr, L.N. (2021)."IMA–CNMNC approved mineral symbols".Mineralogical Magazine.85 (3):291–320.Bibcode:2021MinM...85..291W.doi:10.1180/mgm.2021.43.S2CID 235729616.
  2. ^abGemological Institute of America,GIA Gem Reference Guide 1995,ISBN 0-87311-019-6
  3. ^abcdHandbook of Mineralogy
  4. ^abAndradite, Mindat.org
  5. ^Webmineral data
  6. ^Olga Bortnik. All about precious stones. ― Moscow: Harvest, 2011.
  7. ^abcdGrande, Lance; Augustyn, Allison (2009).Gems and Gemstones: Timeless Natural Beauty of the Mineral World. University of Chicago Press. pp. 188–91.ISBN 978-0-226-30511-0.
  8. ^Melanite, Mindat.org
  9. ^Thomas Armbruster and Charles A. Geiger (1993): "Andradite crystal chemistry, dynamic X-site disorder and structural strain in silicate garnets."European Journal of Mineralogy v. 5, no. 1, p. 59-71.
  10. ^Danylo Zherebetskyy (2010).Quantum mechanical first principles calculations of the electronic and magnetic structure of Fe-bearing rock-forming silicates, PhD Thesis,Universal Publishers/Dissertation.com, Boca Raton, Florida, USA, p. 136.ISBN 1-59942-316-2.
  11. ^Enver Murad (1984): "Magnetic ordering in andradite."American Mineralogist 69, no. 7-8; pp. 722–24.

External links

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Media related toAndradite at Wikimedia Commons

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