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Ammonium hexachlororhodate(III)

From Wikipedia, the free encyclopedia
Ammonium hexachlororhodate(III)
Names
IUPAC name
Ammonium hexachlororhodate(III)
Other names
Ammonium chlororhodate(III), triammonium hexachlororhodate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.035.770Edit this at Wikidata
EC Number
  • 239-364-2
  • InChI=1S/6ClH.3H3N.Rh/h6*1H;3*1H3;/q;;;;;;;;;+3/p-3
    Key: OJNYBYILSUWBHM-UHFFFAOYSA-K
  • [Rh+3]([Cl-])([Cl-])([Cl-])([Cl-])([Cl-])[Cl-].[NH4+]
Properties
Cl6H12N3Rh
Molar mass369.72 g·mol−1
Appearancered crystals
Density2.2 g/cm3
slightly soluble
Hazards
GHS labelling:
GHS07: Exclamation mark[1]
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Ammonium hexachlororhodate(III) is an inorganicchemical compound with the chemical formula(NH4)3RhCl6.[2][3][4]

Synthesis

[edit]

Evaporation of solutions ofrhodium trichloride and excessammonium chloride:

RhCl3 + 3NH4Cl → (NH4)3RhCl6

Physical properties

[edit]

The compound forms red crystals. Slightly soluble in water.

Chemical properties

[edit]

The compound undergoes partial hydrolysis in dilute aqueous solutions:

(NH4)3[RhCl6] + H2O → (NH4)2[RhCl5(H2O)] + NH4Cl

Uses

[edit]

Ammonium hexachlororhodate(III) hydrate is a raw material and intermediate used inorganic synthesis, pharmaceuticals, andagrochemicals.[5]

References

[edit]
  1. ^"Ammonium hexachlororhodate(III) ROTI®METIC 99,995 % (4N5)"(PDF). carlroth.com. Retrieved16 October 2024.
  2. ^"Ammonium hexachlororhodate(III)".Sigma Aldrich. Retrieved16 October 2024.
  3. ^Emergency Planning and Community RightToKnow Act section 313 reporting guidance for the textile processing industry. DIANE Publishing. p. C-14.ISBN 978-1-4289-0164-3. Retrieved16 October 2024.
  4. ^"Ammonium Hexachlororhodate(III)".American Elements. Retrieved16 October 2024.
  5. ^"Ammonium hexachlororhodate(III) hydrate, Premion, 99.99% (metals basis), Thermo Scientific Chemicals | Fisher Scientific".Fisher Scientific. Retrieved16 October 2024.
Ammonium salts
Inorganic salts
monatomic anions
oxyanions
other anions
Organic salts
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