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Aluminium(II) oxide

From Wikipedia, the free encyclopedia
Unusual compound of aluminium in its rare oxidation state II
Aluminium(II) oxide
Names
IUPAC name
Aluminium(II) oxide
Systematic IUPAC name
Oxoalumanyl radical
Other names
Aluminium monoxide
Oxidoaluminium
Oxoaluminum
Aluminious oxide
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
349
  • InChI=1S/Al.O checkY
    Key: AIRCTMFFNKZQPN-UHFFFAOYSA-N checkY
  • InChI=1/Al.O/rAlO/c1-2
    Key: AIRCTMFFNKZQPN-IPBSAJSUAY
  • O=[Al]
Properties
AlO
Molar mass42.98 g/mol
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Chemical compound

Aluminium(II) oxide oraluminium monoxide is a compound ofaluminium andoxygen with thechemical formula AlO. It has been detected in the gas phase after explosion of aluminized grenades in the upper atmosphere[1][2][3] and in stellar absorption spectra.[4]

Aluminium(II) oxide is one of thealuminium oxides (the most common isaluminium oxide Al2O3), as it was the rare example of an aluminium(II) compound since aluminium usually exists in its +3oxidation state.

Reactions

[edit]

Aluminium is an unstable compound, due to it easily reacting with oxygen to become aluminium(III) oxide:[5]

4AlO +O
2
2Al
2
O
3

See also

[edit]

References

[edit]
  1. ^D. C. Tyte (1964). "Red (B2Π–A2σ) Band System of Aluminium Monoxide".Nature.202 (4930): 383.Bibcode:1964Natur.202..383T.doi:10.1038/202383a0.S2CID 4163250.
  2. ^D. C. Tyte (1967). "The dissociation energy of aluminium monoxide".Proc. Phys. Soc.92 (4):1134–1137.Bibcode:1967PPS....92.1134T.doi:10.1088/0370-1328/92/4/339.
  3. ^Johnson E. R.; Low C. H. (1967)."Further spectral observations of grenade glow clouds in the lower thermosphere".Australian Journal of Physics.20 (5): 577.Bibcode:1967AuJPh..20..577J.doi:10.1071/ph670577.
  4. ^Merrill, P. W.; Deutsch, A. J. & Keenan, P. C. (1962). "Absorption Spectra of M-Type Mira Variables".Astrophysical Journal.136: 21.Bibcode:1962ApJ...136...21M.doi:10.1086/147348.
  5. ^"Aluminium(II) Oxide".QS Study. Retrieved2025-11-05.
Al(I)
Organoaluminium(I) compounds
Al(II)
Al(III)
Alums
Organoaluminium(III) compounds
Mixed oxidation states
+1 oxidation state
+2 oxidation state
+3 oxidation state
+4 oxidation state
+5 oxidation state
+6 oxidation state
+7 oxidation state
+8 oxidation state
Related
Oxides are sorted byoxidation state.Category:Oxides
Molecules
Diatomic








Triatomic
Four
atoms
Five
atoms
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atoms
Seven
atoms
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atoms
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Deuterated
molecules
Unconfirmed
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