In 1980, he began working as a chief laboratory assistant at the Institute of Economics of theAcademy of Sciences of the Azerbaijan SSR. Asadov continued his education at the Institute of Economics of theUSSR Academy of Sciences inMoscow between 1981 and 1984, where he got his post-graduate diploma in Economics.[4]
In 1989–1995, Ali Asadov worked as an associate Professor and head of the department at the Baku Institute of Social Management and Political Science.[4]
On 17 April 1998, he was appointed assistant of theAzerbaijani President for economic affairs. According to the decree of the PresidentIlham Aliyev dated 30 November 2012, Asadov was appointed as the deputy head of thePresidential Administration;[6][7] in 2017, he was appointed an assistant of the President of Azerbaijan for economic affairs.[8] Asadov has been considered a close ally of President Aliyev. In October 2019, followingNovruz Mammadov's resignation, he was elected Prime Minister by a vote of 105 to 0.[1] He heads the8th Government of Azerbaijan.