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Atmosphere of Earth

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(Redirected fromAir)

"Air" redirects here. For other uses, seeAir (disambiguation)."Qualities of air" redirects here; not to be confused withAir quality.

Blue light is scattered more than other wavelengths by the gases in the atmosphere, surrounding Earth in a visibly blue layer at thestratosphere, above the clouds of thetroposphere, when seen from space on board theISS at an altitude of 335 km (208 mi) (theMoon is visible as a crescent in the far background).[1]

Theatmosphere of Earth is composed of a layer ofgas mixture that surrounds theEarth'splanetary surface (bothlands andoceans), known collectively asair, with variable quantities of suspendedaerosols andparticulates (which createweather features such asclouds andhazes), all retained byEarth's gravity. The atmosphere serves as a protective buffer between the Earth's surface andouter space, shields the surface from mostmeteoroids and ultravioletsolar radiation, keeps it warm and reducesdiurnal temperature variation (temperature extremes betweenday andnight) through heat retention (greenhouse effect), redistributes heat and moisture among different regions viaair currents, and provides thechemical andclimate conditions allowinglife to exist andevolve on Earth.

Bymole fraction (i.e., by quantity ofmolecules), dry air contains 78.08%nitrogen, 20.95%oxygen, 0.93%argon, 0.04%carbon dioxide, and small amounts of othertrace gases (seeComposition below for more detail). Air also contains a variable amount ofwater vapor, on average around 1% at sea level, and 0.4% over the entire atmosphere.

Earth's early atmosphere consisted ofaccreted gases from thesolar nebula, but the atmosphere changed significantly over time, affected by many factors such asvolcanism,impact events,weathering and theevolution of life (particularly thephotoautotrophs). Recently,human activity has alsocontributed to atmospheric changes, such asclimate change (mainly throughdeforestation andfossil fuel-relatedglobal warming),ozone depletion andacid deposition.

The atmosphere has a mass of about 5.15×1018 kg,[2] three quarters of which is within about 11 km (6.8 mi; 36,000 ft) of the surface. The atmosphere becomes thinner with increasing altitude, with no definite boundary between the atmosphere andouter space. TheKármán line, at 100 km (62 mi) or 1.57% of Earth's radius, is often used as the border between the atmosphere and outer space. Atmospheric effects become noticeable duringatmospheric reentry of spacecraft at an altitude of around 120 km (75 mi). Severallayers can be distinguished in the atmosphere based on characteristics such as temperature and composition, namely thetroposphere,stratosphere,mesosphere,thermosphere (formally theionosphere) andexosphere. Air composition, temperature andatmospheric pressure vary withaltitude. Air suitable for use inphotosynthesis byterrestrial plants andrespiration ofterrestrial animals is found within the troposphere.[3]

The study of Earth's atmosphere and its processes is calledatmospheric science (aerology), and includes multiple subfields, such asclimatology andatmospheric physics. Early pioneers in the field includeLéon Teisserenc de Bort andRichard Assmann.[4] The study of historic atmosphere is calledpaleoclimatology.

Composition

Main article:Atmospheric chemistry
Composition of Earth's atmosphere by molecular count, excluding water vapor. Lower pie represents trace gases that together compose about 0.0434% of the atmosphere.[5][6][7]

The three major constituents of Earth's atmosphere arenitrogen,oxygen, andargon. Water vapor accounts for roughly 0.25% of the atmosphere by mass. The concentration of water vapor (a greenhouse gas) varies significantly from around 10 ppm by mole fraction in the coldest portions of the atmosphere to as much as 5% by mole fraction in hot, humid air masses, and concentrations of other atmospheric gases are typically quoted in terms of dry air (without water vapor).[8]: 8  The remaining gases are often referred to as trace gases,[9] among which are othergreenhouse gases, principally carbon dioxide, methane, nitrous oxide, and ozone. Besides argon, othernoble gases,neon,helium,krypton, andxenon are also present. Filtered air includes trace amounts of many otherchemical compounds. Many substances of natural origin may be present in locally and seasonally variable small amounts asaerosols in an unfiltered air sample, includingdust of mineral and organic composition,pollen andspores,sea spray, andvolcanic ash. Various industrialpollutants also may be present as gases or aerosols, such aschlorine (elemental or in compounds),fluorine compounds and elementalmercury vapor. Sulfur compounds such ashydrogen sulfide andsulfur dioxide (SO2) may be derived from natural sources or from industrial air pollution.

The volume fraction of the main constituents of the Earth's atmosphere as a function of height, based on theMSIS-E-90 atmospheric model; the model only works above 85 km
Major constituents of air[5]
Dry air
GasVolume fraction(A)Mass fraction
NameFormulainppm(B)in%inppmin%
NitrogenN2780,80078.08755,20075.52
OxygenO2209,50020.95231,40023.14
ArgonAr9,3400.934012,9001.29
Carbon dioxide[6]CO24120.04126260.063
NeonNe18.20.0018212.70.00127
HeliumHe5.240.0005240.7240.0000724
Methane[7]CH41.790.0001790.990.000099
KryptonKr1.140.0001143.30.00033
If air is not dry:
Water vapor(D)H2O0–30,000(D)0–3%(E)

The total ppm above adds up to more than 1 million (currently 83.43 above it) due toexperimental error.
Notes
(A) In the atmosphere the pressure is low enough for the ideal gas laws to be correct within 1%. Therefore the mole fraction is very close to thevolume fraction.[10]: 4 
(B) ppm:parts per million by molecular count
(C) The concentration of CO2 has beenincreasing in recent decades, as has that ofCH4.
(D) Water vapor is about 0.25%by mass over full atmosphere
(E) Water vapor varies significantly locally[8]

The averagemolecular weight of dry air, which can be used to calculate densities or to convert between mole fraction and mass fraction, is about 28.946[11] or 28.964[12][5] g/mol. This is decreased when the air is humid.

The relative concentration of gases remains constant until about 10,000 m (33,000 ft).[13]

Stratification

Earth's atmosphere. Lower four layers of the atmosphere in three dimensions as seen diagonally from above the exobase. Layers drawn to scale, objects within the layers are not to scale. Aurorae shown at the bottom of the thermosphere can form at any altitude within this layer.

In general, air pressure and density decrease with altitude in the atmosphere. However, temperature has a more complicated profile with altitude and may remain relatively constant or even increase with altitude in some regions (see thetemperature section). Because the general pattern of the temperature/altitude profile, orlapse rate, is constant and measurable by means of instrumentedballoon soundings, the temperature behavior provides a useful metric to distinguish atmospheric layers. Thisatmospheric stratification divides the Earth's atmosphere into five main layers:[14]

  • Exosphere: 700–10,000 km (435–6,214 mi)[15]
  • Thermosphere: 80–700 km (50–435 mi)[16]
  • Mesosphere: 50–80 km (31–50 mi)
  • Stratosphere: 12–50 km (7–31 mi)
  • Troposphere: 0–12 km (0–7 mi)[17]

Exosphere

Main article:Exosphere

The exosphere is the outermost layer of Earth's atmosphere (though it is so tenuous that some scientists consider it to be part of interplanetary space rather than part of the atmosphere). It extends from thethermopause (also known as the "exobase") at the top of thethermosphere to a poorly defined boundary with thesolar wind andinterplanetary medium. The altitude of the exobase varies from about 500 kilometres (310 mi; 1,600,000 ft) to about 1,000 kilometres (620 mi) in times of higher incoming solar radiation.[18]

The upper limit varies depending on the definition. Various authorities consider it to end at about 10,000 kilometres (6,200 mi)[19] or about 190,000 kilometres (120,000 mi)—about halfway to the moon, where the influence of Earth's gravity is about the same asradiation pressure from sunlight.[18] Thegeocorona visible in the far ultraviolet (caused by neutral hydrogen) extends to at least 100,000 kilometres (62,000 mi).[18]

This layer is mainly composed of extremely low densities of hydrogen, helium and several heavier molecules including nitrogen, oxygen and carbon dioxide closer to the exobase. The atoms and molecules are so far apart that they can travel hundreds of kilometres without colliding with one another. Thus, the exosphere no longer behaves like a gas, and the particles constantlyescape into space. These free-moving particles followballistictrajectories and may migrate in and out of themagnetosphere or the solar wind. Every second, the Earth loses about 3 kg of hydrogen, 50 g of helium, and much smaller amounts of other constituents.[20]

The exosphere is too far above Earth formeteorological phenomena to be possible. However, Earth'sauroras—the aurora borealis (northern lights) and aurora australis (southern lights)—sometimes occur in the lower part of the exosphere, where they overlap into the thermosphere. The exosphere contains many of theartificial satellites thatorbit Earth.

Thermosphere

Main article:Thermosphere

The thermosphere is the second-highest layer of Earth's atmosphere. It extends from the mesopause (which separates it from the mesosphere) at an altitude of about 80 km (50 mi; 260,000 ft) up to thethermopause at an altitude range of 500–1000 km (310–620 mi; 1,600,000–3,300,000 ft). The height of the thermopause varies considerably due to changes in solar activity.[16] Because the thermopause lies at the lower boundary of the exosphere, it is also referred to as theexobase. The lower part of the thermosphere, from 80 to 550 kilometres (50 to 342 mi) above Earth's surface, contains theionosphere.

The temperature of the thermosphere gradually increases with height and can rise as high as 1500 °C (2700 °F), though the gas molecules are so far apart that itstemperature in the usual sense is not very meaningful. The air is so rarefied that an individual molecule (ofoxygen, for example) travels an average of 1 kilometre (0.62 mi; 3300 ft) between collisions with other molecules.[21] Although the thermosphere has a high proportion of molecules with high energy, it would not feel hot to a human in direct contact, because its density is too low to conduct a significant amount of energy to or from the skin.

This layer is completely cloudless and free of water vapor. However, non-hydrometeorological phenomena such as theaurora borealis andaurora australis are occasionally seen in the thermosphere. TheInternational Space Station orbits in this layer, between 350 and 420 km (220 and 260 mi). It is this layer where many of the satellites orbiting the Earth are present.

Mesosphere

Main article:Mesosphere
Afterglow of thetroposphere (orange), thestratosphere (blue) and the mesosphere (dark) at whichatmospheric entry begins, leaving smoke trails, such as in this case of aspacecraft reentry

The mesosphere is the third highest layer of Earth's atmosphere, occupying the region above the stratosphere and below the thermosphere. It extends from the stratopause at an altitude of about 50 km (31 mi; 160,000 ft) to the mesopause at 80–85 km (50–53 mi; 260,000–280,000 ft) above sea level.

Temperatures drop with increasing altitude to themesopause that marks the top of this middle layer of the atmosphere. It is the coldest place on Earth and has an average temperature around −85 °C (−120 °F; 190 K).[22][23]

Just below the mesopause, the air is so cold that even the very scarce water vapor at this altitude can condense into polar-mesosphericnoctilucent clouds of ice particles. These are the highest clouds in the atmosphere and may be visible to the naked eye if sunlight reflects off them about an hour or two after sunset or similarly before sunrise. They are most readily visible when the Sun is around 4 to 16 degrees below the horizon. Lightning-induced discharges known astransient luminous events (TLEs) occasionally form in the mesosphere above troposphericthunderclouds. The mesosphere is also the layer where mostmeteors burn up upon atmospheric entrance. It is too high above Earth to be accessible to jet-powered aircraft and balloons, and too low to permit orbital spacecraft. The mesosphere is mainly accessed bysounding rockets androcket-powered aircraft.

Stratosphere

Main article:Stratosphere

The stratosphere is the second-lowest layer of Earth's atmosphere. It lies above the troposphere and is separated from it by thetropopause. This layer extends from the top of the troposphere at roughly 12 km (7.5 mi; 39,000 ft) above Earth's surface to thestratopause at an altitude of about 50 to 55 km (31 to 34 mi; 164,000 to 180,000 ft).

The atmospheric pressure at the top of the stratosphere is roughly 1/1000 thepressure at sea level. It contains theozone layer, which is the part of Earth's atmosphere that contains relatively high concentrations of that gas. The stratosphere defines a layer in which temperatures rise with increasing altitude. This rise in temperature is caused by the absorption ofultraviolet radiation (UV) from the Sun by the ozone layer, which restricts turbulence and mixing. Although the temperature may be −60 °C (−76 °F; 210 K) at the tropopause, the top of the stratosphere is much warmer, and may be near 0 °C.[24]

The stratospheric temperature profile creates very stable atmospheric conditions, so the stratosphere lacks the weather-producing air turbulence that is so prevalent in the troposphere. Consequently, the stratosphere is almost completely free of clouds and other forms of weather. However, polar stratospheric ornacreous clouds are occasionally seen in the lower part of this layer of the atmosphere where the air is coldest. The stratosphere is the highest layer that can be accessed byjet-powered aircraft.

Troposphere

Main article:Troposphere
A picture of Earth's troposphere, with differentcloud types at low andhigh altitudes casting shadows. Sunlight, filtered into a reddish hue by passing through much of the troposphere at sunset, is reflected off the ocean. The above-lyingstratosphere can be seen at thehorizon as a band of its characteristic glow ofblue scattered sunlight.

The troposphere is the lowest layer of Earth's atmosphere. It extends from Earth's surface to an average height of about 12 km (7.5 mi; 39,000 ft), although thisaltitude varies from about 9 km (5.6 mi; 30,000 ft) at thegeographic poles to 17 km (11 mi; 56,000 ft) at theEquator,[17] with some variation due to weather. The troposphere is bounded above by thetropopause, a boundary marked in most places by atemperature inversion (i.e. a layer of relatively warm air above a colder one), and in others by a zone that isisothermal with height.[25][26]

Although variations do occur, the temperature usually declines with increasing altitude in the troposphere because the troposphere is mostly heated through energy transfer from the surface. Thus, the lowest part of the troposphere (i.e. Earth's surface) is typically the warmest section of the troposphere. This promotes vertical mixing (hence, the origin of its name in the Greek word τρόπος,tropos, meaning "turn"). The troposphere contains roughly 80% of themass of Earth's atmosphere.[27] The troposphere is denser than all its overlying layers because a larger atmospheric weight sits on top of the troposphere and causes it to be most severely compressed. Fifty percent of the total mass of the atmosphere is located in the lower 5.6 km (3.5 mi; 18,000 ft) of the troposphere.

Nearly all atmospheric water vapor or moisture is found in the troposphere, so it is the layer where most of Earth's weather takes place. It has basically all the weather-associated cloud genus types generated by active wind circulation, although very tall cumulonimbus thunder clouds can penetrate the tropopause from below and rise into the lower part of the stratosphere. Most conventionalaviation activity takes place in the troposphere, and it is the only layer accessible bypropeller-driven aircraft.

Other layers

Within the five principal layers above, which are largely determined by temperature, several secondary layers may be distinguished by other properties:

  • Theozone layer is contained within the stratosphere. In this layerozone concentrations are about 2 to 8 parts per million, which is much higher than in the lower atmosphere but still very small compared to the main components of the atmosphere. It is mainly located in the lower portion of the stratosphere from about 15–35 km (9.3–21.7 mi; 49,000–115,000 ft), though the thickness varies seasonally and geographically. About 90% of the ozone in Earth's atmosphere is contained in the stratosphere.
  • Theionosphere is a region of the atmosphere that is ionized by solar radiation. It is responsible forauroras. During daytime hours, it stretches from 50 to 1,000 km (31 to 621 mi; 160,000 to 3,280,000 ft) and includes the mesosphere, thermosphere, and parts of the exosphere. However, ionization in the mesosphere largely ceases during the night, so auroras are normally seen only in the thermosphere and lower exosphere. The ionosphere forms the inner edge of themagnetosphere. It has practical importance because it influences, for example, radio propagation on Earth.
  • Thehomosphere andheterosphere are defined by whether the atmospheric gases are well mixed. The surface-based homosphere includes the troposphere, stratosphere, mesosphere, and the lowest part of the thermosphere, where the chemical composition of the atmosphere does not depend on molecular weight because the gases are mixed by turbulence.[28] This relatively homogeneous layer ends at theturbopause found at about 100 km (62 mi; 330,000 ft), the veryedge of space itself as accepted by theFAI, which places it about 20 km (12 mi; 66,000 ft) above the mesopause.
Above this altitude lies the heterosphere, which includes the exosphere and most of the thermosphere. Here, the chemical composition varies with altitude. This is because thedistance that particles can move without colliding with one another is large compared with the size of motions that cause mixing. This allows the gases to stratify by molecular weight, with the heavier ones, such as oxygen and nitrogen, present only near the bottom of the heterosphere. The upper part of the heterosphere is composed almost completely of hydrogen, the lightest element.[29]
  • Theplanetary boundary layer is the part of the troposphere that is closest to Earth's surface and is directly affected by it, mainly throughturbulent diffusion. During the day the planetary boundary layer usually is well-mixed, whereas at night it becomes stably stratified with weak or intermittent mixing. The depth of the planetary boundary layer ranges from as little as about 100 metres (330 ft) on clear, calm nights to 3,000 m (9,800 ft) or more during the afternoon in dry regions.

The average temperature of the atmosphere at Earth's surface is 14 °C (57 °F; 287 K)[30] or 15 °C (59 °F; 288 K),[31] depending on the reference.[32][33][34]

Physical properties

Comparison of the 1962US Standard Atmosphere graph ofgeometric altitude againstair density,pressure, thespeed of sound andtemperature with approximate altitudes of various objects.[35]

Pressure and thickness

Main article:Atmospheric pressure

The average atmospheric pressure at sea level is defined by theInternational Standard Atmosphere as 101325pascals (760.00 Torr; 14.6959 psi; 760.00 mmHg). This is sometimes referred to as a unit ofstandard atmospheres (atm). Total atmospheric mass is 5.1480×1018 kg (1.13494×1019 lb),[36] about 2.5% less than would be inferred from the average sea-level pressure and Earth's area of 51007.2 megahectares, this portion being displaced by Earth's mountainous terrain. Atmospheric pressure is the total weight of the air above unit area at the point where the pressure is measured. Thus air pressure varies with location andweather.

If the entire mass of the atmosphere had a uniform density equal to sea-level density (about 1.2 kg/m3) from sea level upwards, it would terminate abruptly at an altitude of 8.50 km (27,900 ft).

Air pressure actually decreases exponentially with altitude, for altitudes up to around 70 km (43 mi; 230,000 ft), dropping by half every 5.6 km (18,000 ft), or by a factor of 1/e ≈ 0.368 every 7.64 km (25,100 ft), which is called thescale height. However, the atmosphere is more accurately modeled with a customized equation for each layer that takes gradients of temperature, molecular composition, solar radiation and gravity into account. At heights over 100 km, an atmosphere may no longer be well mixed. Then each chemical species has its own scale height.

In summary, the mass of Earth's atmosphere is distributed approximately as follows:[37]

  • 50% is below 5.6 km (18,000 ft),
  • 90% is below 16 km (52,000 ft),
  • 99.99997% is below 100 km (62 mi; 330,000 ft), theKármán line. By international convention, this marks the beginning of space where human travelers are consideredastronauts.

By comparison, the summit ofMount Everest is at 8,848 m (29,029 ft); commercialairliners typically cruise between 10 and 13 km (33,000 and 43,000 ft), where the lower density and temperature of the air improve fuel economy;weather balloons reach 30.4 km (100,000 ft) and above; and the highestX-15 flight in 1963 reached 108.0 km (354,300 ft).

Even above the Kármán line, significant atmospheric effects such asauroras still occur.Meteors begin to glow in this region, though the larger ones may not burn up until they penetrate more deeply. The various layers of Earth'sionosphere, important toHF radio propagation, begin below 100 km and extend beyond 500 km. By comparison, theInternational Space Station andSpace Shuttle typically orbit at 350–400 km, within theF-layer of the ionosphere, where they encounter enoughatmospheric drag to require reboosts every few months, otherwiseorbital decay will occur, resulting in a return to Earth. Depending on solar activity, satellites can experience noticeable atmospheric drag at altitudes as high as 700–800 km.

Temperature

Main article:Atmospheric temperature
Temperature trends in two thick layers of the atmosphere as measured between January 1979 and December 2005 bymicrowave sounding units andadvanced microwave sounding units onNOAA weather satellites. The instruments record microwaves emitted from oxygen molecules in the atmosphere. Source:[38]

The division of the atmosphere into layers mostly by reference to temperature is discussed above. Temperature decreases with altitude starting at sea level, but variations in this trend begin above 11 km, where the temperature stabilizes over a large vertical distance through the rest of the troposphere. In thestratosphere, starting above about 20 km, the temperature increases with height, due to heating within the ozone layer caused by the capture of significantultraviolet radiation from theSun by the dioxygen and ozone gas in this region. Still another region of increasing temperature with altitude occurs at very high altitudes, in the aptly-namedthermosphere above 90 km.

Speed of sound

Main article:Speed of sound

Because in anideal gas of constant composition thespeed of sound depends only on temperature and not on pressure or density, the speed of sound in the atmosphere with altitude takes on the form of the complicated temperature profile (see illustration to the right), and does not mirror altitudinal changes in density or pressure.

Density and mass

Temperature and mass density against altitude from theNRLMSISE-00standard atmosphere model (the eight dotted lines in each "decade" are at the eight cubes 8, 27, 64, ..., 729)
Main article:Density of air

The density of air at sea level is about 1.2 kg/m3 (1.2 g/L, 0.0012 g/cm3). Density is not measured directly but is calculated from measurements of temperature, pressure and humidity using the equation of state for air (a form of theideal gas law). Atmospheric density decreases as the altitude increases. This variation can be approximately modeled using thebarometric formula. More sophisticated models are used to predict the orbital decay of satellites.

The average mass of the atmosphere is about 5 quadrillion (5×1015)tonnes or 1/1,200,000 the mass of Earth. According to the AmericanNational Center for Atmospheric Research, "The total mean mass of the atmosphere is 5.1480×1018 kg with an annual range due to water vapor of 1.2 or 1.5×1015 kg, depending on whether surface pressure or water vapor data are used; somewhat smaller than the previous estimate. The mean mass of water vapor is estimated as 1.27×1016 kg and the dry air mass as 5.1352 ±0.0003×1018 kg."

Tabulated properties

Physical and thermal properties of air at atmospheric pressure[39]: 602 [40]
Temperature
[K]
Density
[kg/m3]
Specific
heat
[J/(kg⋅°C)]
Dynamic
viscosity
[kg/(m⋅s)]
Kinematic
viscosity
[m2/s]
Thermal
conductivity
[W/(m⋅°C)]
Thermal
diffusivity
[m2/s]
Prandtl
number
[1]
Bulk
modulus
[K−1]
1003.6011026.66.92×10−61.92×10−60.0009252.50×10−60.770.01
1502.36751009.91.03×10−54.34×10−60.0137355.75×10−60.7530.006667
2001.76841006.11.33×10−57.49×10−60.018091.02×10−50.7380.005
2501.41281005.31.60×10−51.13×10−50.022271.57×10−50.7220.004
3001.17741005.71.85×10−51.57×10−50.026242.22×10−50.7080.003333
3500.99810092.08×10−52.08×10−50.030032.98×10−50.6970.002857
4000.882610142.29×10−52.59×10−50.033653.76×10−50.6890.0025
4500.78331020.72.48×10−53.17×10−50.037074.22×10−50.6830.002222
5000.70481029.52.67×10−53.79×10−50.040385.56×10−50.680.002
5500.64231039.22.85×10−54.43×10−50.04366.53×10−50.680.001818
6000.58791055.13.02×10−55.13×10−50.046597.51×10−50.680.001667
6500.5431063.53.18×10−55.85×10−50.049538.58×10−50.6820.001538
7000.5031075.23.33×10−56.63×10−50.05239.67×10−50.6840.001429
7500.47091085.63.48×10−57.39×10−50.055091.08×10−40.6860.001333
8000.44051097.83.63×10−58.23×10−50.057791.20×10−40.6890.00125
8500.41491109.53.77×10−59.08×10−50.060281.31×10−40.6920.001176
9000.39251121.23.90×10−59.93×10−50.062791.43×10−40.6960.001111
9500.37161132.14.02×10−51.08×10−40.065251.55×10−40.6990.001053
10000.35241141.74.15×10−51.18×10−40.067531.68×10−40.7020.001
11000.320411604.44×10−51.39×10−40.07321.97×10−40.7040.000909
12000.294711794.69×10−51.59×10−40.07822.25×10−40.7070.000833
13000.270711974.93×10−51.82×10−40.08372.58×10−40.7050.000769
14000.251512145.17×10−52.06×10−40.08912.92×10−40.7050.000714
15000.235512305.40×10−52.29×10−40.09463.26×10−40.7050.000667
16000.221112485.63×10−52.55×10−40.13.61×10−40.7050.000625
17000.208212675.85×10−52.81×10−40.1053.98×10−40.7050.000588
18000.19712876.07×10−53.08×10−40.1114.38×10−40.7040.000556
19000.185813096.29×10−53.39×10−40.1174.81×10−40.7040.000526
20000.176213386.50×10−53.69×10−40.1245.26×10−40.7020.0005
21000.168213726.72×10−54.00×10−40.1315.72×10−40.70.000476
22000.160214196.93×10−54.33×10−40.1396.12×10−40.7070.000455
23000.153814827.14×10−54.64×10−40.1496.54×10−40.710.000435
24000.145815747.35×10−55.04×10−40.1617.02×10−40.7180.000417
25000.139416887.57×10−55.44×10−40.1757.44×10−40.730.0004

Optical properties

See also:Sunlight

Solarradiation (or sunlight) is the energy Earth receives from theSun. Earth also emits radiation back into space, but at longer wavelengths that humans cannot see. Part of the incoming and emitted radiation is absorbed or reflected by the atmosphere.[41][42] In May 2017, glints of light, seen as twinkling from an orbiting satellite a million miles away, were found to bereflected light fromice crystals in the atmosphere.[43][44]

Scattering

Main article:Atmospheric scattering

When light passes through Earth's atmosphere,photons interact with it throughscattering. If the light does not interact with the atmosphere, it is calleddirect radiation and is what you see if you were to look directly at the Sun.Indirect radiation is light that has been scattered in the atmosphere. For example, on anovercast day when you cannot see your shadow, there is no direct radiation reaching you, it has all been scattered. As another example, due to a phenomenon calledRayleigh scattering, shorter (blue) wavelengths scatter more easily than longer (red) wavelengths. This is why the sky looks blue; you are seeing scattered blue light. This is also why sunsets are red. Because the Sun is close to the horizon, the Sun's rays pass through more atmosphere than normal before reaching your eye. Much of the blue light has been scattered out, leaving the red light in a sunset.

Absorption

Main article:Absorption (electromagnetic radiation)
Rough plot of Earth's atmospherictransmittance (or opacity) to various wavelengths of electromagnetic radiation, includingvisible light

Different molecules absorb different wavelengths of radiation. For example, O2 and O3 absorb almost all radiation with wavelengths shorter than 300nanometres. Water (H2O) absorbs at many wavelengths above 700 nm. When a molecule absorbs a photon, it increases the energy of the molecule. This heats the atmosphere, but the atmosphere also cools by emitting radiation, as discussed below.

The combinedabsorption spectra of the gases in the atmosphere leave "windows" of lowopacity, allowing the transmission of only certain bands of light. Theoptical window runs from around 300 nm (ultraviolet-C) up into the range humans can see, thevisible spectrum (commonly called light), at roughly 400–700 nm and continues to theinfrared to around 1100 nm. There are alsoinfrared andradio windows that transmit some infrared andradio waves at longer wavelengths. For example, the radio window runs from about one centimetre to about eleven-metre waves.

Emission

Further information:Emission spectrum

Emission is the opposite of absorption, it is when an object emits radiation. Objects tend to emit amounts and wavelengths of radiation depending on their "black body" emission curves, therefore hotter objects tend to emit more radiation, with shorter wavelengths. Colder objects emit less radiation, with longer wavelengths. For example, the Sun is approximately 6,000 K (5,730 °C; 10,340 °F), its radiation peaks near 500 nm, and is visible to the human eye. Earth is approximately 290 K (17 °C; 62 °F), so its radiation peaks near 10,000 nm, and is much too long to be visible to humans.

Because of its temperature, the atmosphere emits infrared radiation. For example, on clear nights Earth's surface cools down faster than on cloudy nights. This is because clouds (H2O) are strong absorbers and emitters of infrared radiation. This is also why it becomes colder at night at higher elevations.

Thegreenhouse effect is directly related to this absorption and emission effect. Some gases in the atmosphere absorb and emit infrared radiation, but do not interact with sunlight in the visible spectrum. Common examples of these are CO2 and H2O.

Refractive index

Distortive effect ofatmospheric refraction upon the shape of the sun at the horizon
Main article:Atmospheric refraction
See also:Scintillation (astronomy)

Therefractive index of air is close to, but just greater than, 1. Systematic variations in the refractive index can lead to the bending of light rays over long optical paths. One example is that, under some circumstances, observers on board ships can see other vessels just over thehorizon because light is refracted in the same direction as thecurvature of Earth's surface.

The refractive index of air depends on temperature,[45] giving rise to refraction effects when the temperature gradient is large. An example of such effects is themirage.

Circulation

Main article:Atmospheric circulation
An idealised view of three pairs of large circulation cells

Atmospheric circulation is the large-scale movement of air through the troposphere, and the means (withocean circulation) by which heat is distributed around Earth. The large-scale structure of the atmospheric circulation varies from year to year, but the basic structure remains fairly constant because it is determined by Earth's rotation rate and the difference in solar radiation between the equator and poles.

Evolution of Earth's atmosphere

See also:History of Earth andPaleoclimatology

Earliest atmosphere

The first atmosphere, during theEarly Earth'sHadeaneon, consisted of gases in thesolar nebula, primarilyhydrogen, and probably simplehydrides such as those now found in thegas giants (Jupiter andSaturn), notablywater vapor,methane andammonia.During this earliest era, theMoon-forming collision and numerousimpacts with largemeteorites heated the atmosphere, driving off the most volatile gases. The collision withTheia, in particular, melted and ejected large portions ofEarth's mantle andcrust andoutgassed significant amounts ofsteam which eventually cooled and condensed to contribute to ocean water at the end of the Hadean.[46]: 10 

Second atmosphere

See also:Prebiotic atmosphere

The increasingsolidification ofEarth's crust at the end of the Hadean closed off most of theadvectiveheat transfer to the surface, causing the atmosphere to cool, whichcondensed most of the water vapor out of the airprecipitating into asuperocean. Furtheroutgassing fromvolcanism, supplemented by gases introduced by hugeasteroids during theLate Heavy Bombardment, created the subsequentArchean atmosphere, which consisted largely ofnitrogen pluscarbon dioxide,methane andinert gases.[46] A major part of carbon dioxide emissionsdissolved in water and reacted with metals such ascalcium andmagnesium duringweathering ofcrustal rocks to formcarbonates that were deposited assediments. Water-related sediments have been found that date from as early as 3.8 billion years ago.[47]

About 3.4 billion years ago, nitrogen formed the major component of the then-stable "second atmosphere". The influence of theevolution of life has to be taken into account rather soon in the history of the atmosphere because hints ofearliest life forms appeared as early as 3.5 billion years ago.[48] How Earth at that time maintained a climate warm enough for liquid water and life, if the early Sun put out 30% lower solar radiance than today, is a puzzle known as the "faint young Sun paradox".

The geological record however shows a continuous relatively warm surface during the complete earlytemperature record of Earth – with the exception of one cold glacial phase about 2.4 billion years ago. In the lateNeoarchean, an oxygen-containing atmosphere began to develop, apparently due to a billion years ofcyanobacterialphotosynthesis (seeGreat Oxygenation Event), which have been found asstromatolitefossils from 2.7 billion years ago. The early basic carbon isotopy (isotope ratio proportions) strongly suggests conditions similar to the current, and that the fundamental features of thecarbon cycle became established as early as 4 billion years ago.

Ancient sediments in theGabon dating from between about 2.15 and 2.08 billion years ago provide a record of Earth's dynamic oxygenation evolution. These fluctuations in oxygenation were likely driven by the Lomagundi carbon isotope excursion.[49]

Third atmosphere

Oxygen content of the atmosphere over the last billion years[50][51]
Main article:Geological history of oxygen

The constant re-arrangement ofcontinents byplate tectonics influences the long-term evolution of the atmosphere by transferring carbon dioxide to and from large continentalcarbonate stores. Free oxygen did not exist in the atmosphere until about 2.4 billion years ago during theGreat Oxygenation Event and its appearance is indicated by the end ofbanded iron formations (which signals the depletion ofsubstrates that can react with oxygen to produceferric deposits) during the earlyProterozoic eon.

Before this time, any oxygen produced by cyanobacterial photosynthesis would be readily removed by theoxidation ofreducing substances on the Earth's surface, notablyferrous iron,sulfur andatmospheric methane. Free oxygen molecules did not start to accumulate in the atmosphere until the rate of production of oxygen began to exceed the availability of reductant materials that removed oxygen. This point signifies a shift from areducing atmosphere to anoxidizing atmosphere. O2 showed major variations during the Proterozoic, includinga billion-year period ofeuxinia, until reaching a steady state of more than 15% by the end of thePrecambrian.[52] The rise of the more robusteukaryoticphotoautotrophs (green andred algae) injected further oxygenation into the air, especially after the end of theCryogenianglobal glaciation, which was followed by anevolutionary radiation event during theEdiacaranperiod known as theAvalon explosion, where complexmetazoan life forms (including the earliestcnidarians,placozoans andbilaterians) first proliferated. The following time span from 539 million years ago to the present day is thePhanerozoic eon, during the earliestperiod of which, theCambrian, moreactively moving metazoan life began to appear and rapidly diversify in another radiation event called theCambrian explosion, whoselocomotivemetabolism was fuelled by the rising oxygen level.

The amount of oxygen in the atmosphere has fluctuated over the last 600 million years, reaching a peak of about 30% around 280 million years ago during theCarboniferous period, significantly higher than today's 21%. Two main processes govern changes in the atmosphere: theevolution ofplants and their increasing role incarbon fixation, and the consumption of oxygen by rapidly diversifyinganimalfaunae and also by plants forphotorespiration and their own metabolic needs at night. Breakdown ofpyrite andvolcanic eruptions release sulfur into the atmosphere, which reacts and hence reduces oxygen in the atmosphere. However, volcanic eruptions also release carbon dioxide, which can fuel oxygenic photosynthesis byterrestrial andaquatic plants. The cause of the variation of the amount of oxygen in the atmosphere is not precisely understood. Periods with more oxygen in the atmosphere were often associated with more rapid development of animals.

Air pollution

Animation shows the buildup of tropospheric CO2 in the Northern Hemisphere with a maximum around May. The maximum in the vegetation cycle follows in the late summer. Following the peak in vegetation, the drawdown of atmospheric CO2 due to photosynthesis is apparent, particularly over theboreal forests.
Main article:Air pollution

Air pollution is the introduction of airbornechemicals,particulate matter orbiological materials that cause harm or discomfort to organisms.[53] Thepopulation growth,industrialization andmotorization ofhumansocieties have significantly increased the amount of airbornepollutants in the Earth's atmosphere, causing noticeable problems such assmogs,acid rains andpollution-related diseases. Thedepletion ofstratosphericozone layer, which shields the surface from harmfulionizingultraviolet radiations, is also caused by air pollution, chiefly fromchlorofluorocarbons and other ozone-depleting substances.

Since 1750, human activity, especially after theIndustrial Revolution, has increased the concentrations of variousgreenhouse gases, most importantly carbon dioxide, methane andnitrous oxide.Greenhouse gas emissions, coupled withdeforestation anddestruction ofwetlands vialogging andland developments, have caused an observedrise in global temperatures, with the global average surface temperatures being1.1 °C higher in the 2011–2020 decade than they were in 1850.[54] It has raised concerns of man-madeclimate change, which can have significantenvironmental impacts such assea level rise,ocean acidification,glacial retreat (which threatenswater security), increasingextreme weather events andwildfires,ecological collapse andmass dying of wildlife.

See also

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