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Adolf von Baeyer

From Wikipedia, the free encyclopedia
German chemist (1835–1917)
For the founder of the pharmaceutical companyBayer, seeFriedrich Bayer.
Adolf von Baeyer
Baeyer in 1905
Born
Johann Friedrich Wilhelm Adolf Baeyer

(1835-10-31)31 October 1835
Died20 August 1917(1917-08-20) (aged 81)
NationalityGerman
Alma materUniversity of Berlin
Known forSynthesis ofindigo,phenolphthalein andfluorescein
Photogeochemistry
Baeyer nomenclature
Baeyer reagent
Baeyer strain
Baeyer–Drewson indigo synthesis
Baeyer–Emmerling indole synthesis
Baeyer–Villiger oxidation
Spouse
Adelheid Bendemann
(m. 1868)
Children3; includingOtto [de].
AwardsDavy Medal(1881)
Liebig Medal(1903)
Nobel Prize for Chemistry(1905)
Elliott Cresson Medal(1912)
Scientific career
FieldsOrganic chemistry
InstitutionsUniversity of Berlin
Gewerbe-Akademie, Berlin
University of Strasbourg
University of Munich
ThesisDe arsenici cum methylo conjunctionibus (1858)
Doctoral advisorsFriedrich August Kekulé
Robert Bunsen[1]
Doctoral studentsEmil Fischer
John Ulric Nef
Victor Villiger
Carl Theodore Liebermann
Carl Gräbe
Karl Andreas Hofmann

Johann Friedrich Wilhelm Adolf von Baeyer (German:[ˈaːdɔlffɔnˈbaɪɐ]; 31 October 1835 – 20 August 1917) was a Germanchemist who synthesisedindigo[2] and developed anomenclature for cyclic compounds (that was subsequently extended and adopted as part of theIUPAC organic nomenclature). He wasennobled in theKingdom of Bavaria in 1885 and was the 1905 recipient of theNobel Prize in Chemistry.[3]

Family and education

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FatherJohann Jacob Baeyer, Prussian lieutenant-general, the notedgeodesist

Baeyer was born inBerlin as the son of the notedgeodesist and captain of the Royal Prussian ArmyJohann Jacob Baeyer and his wife Eugenie Baeyer née Hitzig (1807–1843).[4] Both his parents wereLutherans at the time of his birth and he was raised in the Lutheran religion.[5] His mother was the daughter ofJulius Eduard Hitzig and a member of the originallyJewishItzig family, and had converted to Christianity before marrying his father, who was of non-Jewish German descent.[6] Baeyer had four sisters: Clara (born 1826) Emma (born 1831), Johanna (Jeanette) (born 1839), Adelaide (died 1843) and two brothers: Georg (born 1829) and Edward (born 1832). Baeyer lost his mother at a young age while she was giving birth to his sister Adelaide.[7]

Although his birth name was Johann Friedrich Wilhelm Adolf Baeyer, he was known simply as Adolf throughout most of his life. The poetAdelbert von Chamisso and the astronomerFriedrich Wilhelm Bessel were his godparents. On his 50th birthday he was raised to the hereditary nobility by KingLudwig II of Bavaria, conferring on him the "von" distinction.[8]

Baeyer became interested in science early, performing experiments on plant nutrition at his paternal grandfather's Müggelsheim farm as a boy. In Berlin he began chemical experimentation at the age of nine. Three years later, he synthesized a previously unknown chemical compound -double carbonate of copper and sodium.[8][9] On his 13th birthday, he initiated his lifework, buying a chunk of indigo worth twoThalers for his first dye experiments.[8]

When a schoolboy, his chemistry teacher at theFriedrich Wilhelm Gymnasium appointed him as his assistant. After graduating from secondary school in 1853, he entered theBerlin University to studyphysics and mathematics. A stint in the Prussian army interrupted his study until 1856, when he returned to academia at theUniversity of Heidelberg, intending to studychemistry underRobert Bunsen.[citation needed] After an argument with the renowned chemist he changed his mentor toAugust Kekulé. He continued to collaborate with Kekulé even after he returned to Berlin in 1858 for the completion of his doctorate on arsenic methyl chloride, orcacodylic chloride.[8]

Academic career and achievements

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After completing his doctorate, he followed Kekulé to theUniversity of Ghent, when Kekulé became professor there. He became a lecturer at theGewerbeinstitut Berlin [de] (Royal Trade Academy) in 1860 and a professor at theUniversity of Strasbourg in 1871. In 1875, he succeededJustus von Liebig as Chemistry Professor at theUniversity of Munich.[10]

Baeyer's chief achievements include thesynthesis and description of the plantdyeindigo, the discovery of thephthalein dyes, and the investigation ofpolyacetylenes,oxoniumsalts,nitroso compounds (1869) anduric acid derivatives (1860 and onwards) (including the discovery ofbarbituric acid (1864), the parent compound of thebarbiturates). He was the first to propose the correct formula forindole in 1869, after publishing the first synthesis three years earlier. His contributions totheoretical chemistry include the 'strain' (Spannung) theory oftriple bonds andstrain theory in smallcarbon rings.[11]

In 1871 he discovered the synthesis ofphenolphthalein bycondensation ofphthalic anhydride with two equivalents ofphenol underacidic conditions (hence the name). That same year he was the first to obtain syntheticfluorescein, afluorophorepigment which is similar to naturally occurringpyoverdin that is synthesised by microorganisms (e.g., by somefluorescent strains ofPseudomonas). Baeyer named his finding "resorcinphthalein" as he had synthesised it fromphthalic anhydride andresorcinol. The termfluorescein would not start to be used until 1878.

In 1872 he experimented withphenol andformaldehyde; the resinous product[12] was a precursor forLeo Baekeland's later commercialization ofBakelite.

In 1881 theRoyal Society of London awarded Baeyer theDavy Medal for his work with indigo. He was elected a Foreign Honorary Member of theAmerican Academy of Arts and Sciences in 1884.[13] In 1905 he was awarded theNobel Prize in Chemistry "in recognition of his services in the advancement of organic chemistry and the chemical industry, through his work on organic dyes and hydroaromatic compounds", and he continued in full active work as one of the best-known teachers in the world of organic chemistry up to within a year of his death.[14]

Honours

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TheAdolf von Baeyer Medal [de] has been awarded annually since 1911.

His name is reflected in various "name reactions" as theBaeyer–Villiger oxidation andBaeyer's reagent. There is also theVon Baeyer nomenclature in structural chemistry and Baeyerstrain theory (which granted him the Nobel prize) ofalicyclic compounds.

In 2009von Baeyerlunar crater was named after him.

Personal life

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In 1868, Baeyer married Adelheid (Lida) Bendemann, the daughter of a family friend, and together the couple had three children: Eugenie, Hans, andOtto [de].[8]

He died on 20 August 1917 inStarnberg at the age of 81.

See also

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References

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  1. ^"Johann Friedrich Wilhelm Adolf von Baeyer".The Mathematics Genealogy Project. Retrieved18 November 2022.
  2. ^Adolf Baeyer, Viggo Drewsen (1882)."Darstellung von Indigblau aus Orthonitrobenzaldehyd" [Preparation of blue indigo from o-nitrobenzaldehyde].Berichte der deutschen chemischen Gesellschaft.15 (2):2856–2864.doi:10.1002/cber.188201502274.
  3. ^Adolf von Baeyer: Winner of the Nobel Prize for Chemistry 1905 Armin de MeijereAngewandte Chemie International Edition Volume 44, Issue 48, Pages 7836 – 78402005Abstract
  4. ^"Adolf von Baeyer – Biographical". Nobelprize.org. 1917-08-20. Retrieved2013-12-09.
  5. ^Baeyer, Adolf Ritter von inDeutsche Biographie
  6. ^During the Nazi period, Baeyer's Jewish ancestry caused difficulties for his grandsons, who were compelled to emigrate to Canada and the United States.
  7. ^Schnurmann, Claudia (2014-10-15).Brücken aus Papier: Atlantischer Wissenstransfer in dem Briefnetzwerk des deutsch-amerikanischen Ehepaars Francis und Mathilde Lieber, 1827–1872 (in German). Note 1445. Germany: LIT Verlag Münster. p. 371.ISBN 978-3-643-12678-8.
  8. ^abcdeOakes, Elizabeth H. (2007).Encyclopedia of World Scientists. NY, USA: Infobase Publishing. p. 39.ISBN 978-1-4381-1882-6.
  9. ^Hudson, John (1992-01-01).Organic Chemistry since 1860. Springer US. p. 303.doi:10.1007/978-1-4684-6441-2.ISBN 978-1-4684-6443-6.
  10. ^Chisholm 1911.
  11. ^Adolf Baeyer (1885)."Ueber Polyacetylenverbindungen (Zweite Mittheilung)" [On polyacetylene compounds (Part II)].Berichte der deutschen chemischen Gesellschaft.18 (2):2269–2281.doi:10.1002/cber.18850180296. See especially pages 2277-2281.
  12. ^"Major industrial polymers".Encyclopedia Britannica.
  13. ^ab"Book of Members, 1780–2010: Chapter B"(PDF). American Academy of Arts and Sciences. Retrieved5 May 2011.
  14. ^ One or more of the preceding sentences incorporates text from a publication now in thepublic domainChisholm, Hugh, ed. (1922). "Baeyer, Johann Friedrich Wilhelm Adolf von".Encyclopædia Britannica. Vol. 30 (12th ed.). London & New York: The Encyclopædia Britannica Company. p. 365.
  15. ^"Mitglieder der Vorgängerakademien".Adolf Ritter von Baeyer.
  16. ^"Adolf Johann Friedrich Wilhelm von Baeyer".American Academy of Arts & Sciences. 2023-02-09. Retrieved2023-12-07.
  17. ^"Baeyer, Johann Friedrich Wilhelm Adolf von (1835–1917)".Archive of Royal Society. Archived fromthe original on 2020-05-27. Retrieved2016-07-17.
  18. ^Orden Pour le Mérite für Wissenschaften und Künste (1978).Die Mitglieder des Ordens. 2 1882–1952(PDF). Berlin: Gebr. Mann Verlag. p. 104.ISBN 978-3-7861-1125-2. Archived fromthe original(PDF) on 2016-07-11. Retrieved2018-06-22.
  19. ^Memoirs and proceedings of the Manchester Literary & Philosophical Society FOURTH SERIES Eighth VOLUME 1894
  20. ^"Adolf von Baeyer".www.nasonline.org. Retrieved2023-12-07.
  21. ^"APS Member History".search.amphilsoc.org. Retrieved2023-12-07.

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