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Adkins–Peterson reaction

From Wikipedia, the free encyclopedia

TheAdkins–Peterson reaction is the airoxidation ofmethanol toformaldehyde with metal oxidecatalysts such asiron oxide,molybdenum trioxide or combinations thereof.

Whilst this class of oxidation had been investigated previously, in-depth systemization of the behaviour of the iron oxide/molybdenum trioxide catalyst was carried out byHomer Burton Adkins andWesley R. Peterson.[1]

Reaction Conditions

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  • The reaction is typically conducted at 300°C to 400°C.
  • Equimolar proportions of iron and molybdenum oxides yields the highest conversion of methanol to formaldehyde, achieving over 90%conversion withcarbon monoxide as the secondary product.

References

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  1. ^Adkins, Homer; Peterson, Wesley R. (1931). "The Oxidation of Methanol with Air over Iron Molybdenum and Iron-Molybdenum Oxides".J. Am. Chem. Soc.53 (4):1512–1520.doi:10.1021/ja01355a050.
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