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Attenuation coefficient

From Wikipedia, the free encyclopedia
(Redirected fromAbsorption coefficient)
Light or sound absorption in a substance
For "attenuation coefficient" as it applies to electromagnetic theory and telecommunications, seeAttenuation constant.

Thelinear attenuation coefficient,attenuation coefficient, ornarrow-beam attenuation coefficient characterizes how easily a volume of material can be penetrated by a beam oflight,sound,particles, or otherenergy ormatter.[1] A coefficient value that is large represents a beam becoming 'attenuated' as it passes through a given medium, while a small value represents that the medium had little effect on loss.[2] The (derived)SI unit of attenuation coefficient is thereciprocal metre (m−1).Extinction coefficient is another term for this quantity,[1] often used inmeteorology andclimatology.[3] Theattenuation length is the reciprocal of the attenuation coefficient.[4]

Overview

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The attenuation coefficient describes the extent to which theradiant flux of a beam is reduced as it passes through a specific material. It is used in the context of:

The attenuation coefficient is called the "extinction coefficient" or sometimesabsorption coefficient in the context ofsolar andinfrared radiative transfer in theatmosphere.[4]: 423 

A small attenuation coefficient indicates that the material in question is relativelytransparent, while a larger value indicates greater degrees ofopacity. The attenuation coefficient is dependent upon the type of material and the energy of the radiation. Generally, for electromagnetic radiation, the higher the energy of the incident photons and the less dense the material in question, the lower the corresponding attenuation coefficient will be.

Beer–Lambert law

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Main article:Beer–Lambert law

The attenuation of light as it moves through a thin layer of a homogenous material is proportional to the layer thickness,d{\displaystyle d} and the initial intensity,I0{\displaystyle I_{0}}. The resulting intensity is given byI(d)=I0eαd{\displaystyle I(d)=I_{0}e^{-\alpha d}}whereα{\displaystyle \alpha } is the attenuation coefficient. This formula is known as the Beer-Lambert law.[7]This attenuation coefficient measures theexponential decay of intensity, that is, the value of downwarde-folding distance of the original intensity as the energy of the intensity passes through a unit (e.g. one meter) thickness of material, so that an attenuation coefficient of 1 m−1 means that after passing through 1 metre, the radiation will be reduced by a factor ofe, and for material with a coefficient of 2 m−1, it will be reduced twice bye, ore2. Other measures may use a different factor thane, such as thedecadic attenuation coefficient below. Thebroad-beam attenuation coefficient counts forward-scattered radiation as transmitted rather than attenuated, and is more applicable toradiation shielding.Themass attenuation coefficient is the attenuation coefficient normalized by the density of the material.

Mathematical definitions

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Attenuation coefficient

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Theattenuation coefficient of a volume, denotedμ, is defined as[8]

μ=1ΦedΦedz,{\displaystyle \mu =-{\frac {1}{\Phi _{\mathrm {e} }}}{\frac {\mathrm {d} \Phi _{\mathrm {e} }}{\mathrm {d} z}},}

where

Note that for an attenuation coefficient which does not vary withz, this equation is solved along a line fromz{\displaystyle z}=0 toz{\displaystyle z} as:

Φe=Φe0eμz{\displaystyle \Phi _{\mathrm {e} }=\Phi _{\mathrm {e0} }e^{-\mu z}}

whereΦe0{\displaystyle \Phi _{\mathrm {e0} }} is the incoming radiation flux atz{\displaystyle z}=0 andΦe{\displaystyle \Phi _{\mathrm {e} }} is the radiation flux atz{\displaystyle z}.

Spectral hemispherical attenuation coefficient

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Thespectral hemispherical attenuation coefficient in frequency andspectral hemispherical attenuation coefficient in wavelength of a volume, denotedμν andμλ respectively, are defined as:[8]

μν=1Φe,νdΦe,νdz,{\displaystyle \mu _{\nu }=-{\frac {1}{\Phi _{\mathrm {e} ,\nu }}}{\frac {\mathrm {d} \Phi _{\mathrm {e} ,\nu }}{\mathrm {d} z}},}
μλ=1Φe,λdΦe,λdz,{\displaystyle \mu _{\lambda }=-{\frac {1}{\Phi _{\mathrm {e} ,\lambda }}}{\frac {\mathrm {d} \Phi _{\mathrm {e} ,\lambda }}{\mathrm {d} z}},}

where

Directional attenuation coefficient

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Thedirectional attenuation coefficient of a volume, denotedμΩ, is defined as[8]

μΩ=1Le,ΩdLe,Ωdz,{\displaystyle \mu _{\Omega }=-{\frac {1}{L_{\mathrm {e} ,\Omega }}}{\frac {\mathrm {d} L_{\mathrm {e} ,\Omega }}{\mathrm {d} z}},}

whereLe,Ω is theradiance.

Spectral directional attenuation coefficient

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Thespectral directional attenuation coefficient in frequency andspectral directional attenuation coefficient in wavelength of a volume, denotedμΩ,ν andμΩ,λ respectively, are defined as[8]

μΩ,ν=1Le,Ω,νdLe,Ω,νdz,μΩ,λ=1Le,Ω,λdLe,Ω,λdz,{\displaystyle {\begin{aligned}\mu _{\Omega ,\nu }&=-{\frac {1}{L_{\mathrm {e} ,\Omega ,\nu }}}{\frac {\mathrm {d} L_{\mathrm {e} ,\Omega ,\nu }}{\mathrm {d} z}},\\\mu _{\Omega ,\lambda }&=-{\frac {1}{L_{\mathrm {e} ,\Omega ,\lambda }}}{\frac {\mathrm {d} L_{\mathrm {e} ,\Omega ,\lambda }}{\mathrm {d} z}},\end{aligned}}}

where

Absorption and scattering coefficients

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Further information:Optical extinction coefficient

When a narrow (collimated) beam passes through a volume, the beam will lose intensity due to two processes:absorption andscattering. Absorption indicates energy that is lost from the beam, while scattering indicates light that is redirected in a (random) direction, and hence is no longer in the beam, but still present, resulting in diffuse light.

Theabsorption coefficient of a volume, denotedμa, and thescattering coefficient of a volume, denotedμs, are defined the same way as the attenuation coefficient.[8]

The attenuation coefficient of a volume is the sum of absorption coefficient and scattering coefficients:[8]

μ=μa+μs,μν=μa,ν+μs,ν,μλ=μa,λ+μs,λ,μΩ=μa,Ω+μs,Ω,μΩ,ν=μa,Ω,ν+μs,Ω,ν,μΩ,λ=μa,Ω,λ+μs,Ω,λ.{\displaystyle {\begin{aligned}\mu &=\mu _{\mathrm {a} }+\mu _{\mathrm {s} },\\\mu _{\nu }&=\mu _{\mathrm {a} ,\nu }+\mu _{\mathrm {s} ,\nu },\\\mu _{\lambda }&=\mu _{\mathrm {a} ,\lambda }+\mu _{\mathrm {s} ,\lambda },\\\mu _{\Omega }&=\mu _{\mathrm {a} ,\Omega }+\mu _{\mathrm {s} ,\Omega },\\\mu _{\Omega ,\nu }&=\mu _{\mathrm {a} ,\Omega ,\nu }+\mu _{\mathrm {s} ,\Omega ,\nu },\\\mu _{\Omega ,\lambda }&=\mu _{\mathrm {a} ,\Omega ,\lambda }+\mu _{\mathrm {s} ,\Omega ,\lambda }.\end{aligned}}}

Just looking at the narrow beam itself, the two processes cannot be distinguished. However, if a detector is set up to measure beam leaving in different directions, or conversely using a non-narrow beam, one can measure how much of the lost radiant flux was scattered, and how much was absorbed.

In this context, the "absorption coefficient" measures how quickly the beam would lose radiant flux due to the absorptionalone, while "attenuation coefficient" measures thetotal loss of narrow-beam intensity, including scattering as well. "Narrow-beam attenuation coefficient" always unambiguously refers to the latter. The attenuation coefficient is at least as large as the absorption coefficient; they are equal in the idealized case of no scattering.

Expression in terms of density and cross section

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The absorption coefficient may be expressed in terms of a number density of absorbing centersn and an absorbing cross section areaσ.[9] For a slab of areaA and thicknessdz, the total number of absorbing centers contained isn A dz. Assuming that dz is so small that there will be no overlap of the cross section areas, the total area available for absorption will ben A σ dz and the fraction of radiation absorbed is thenn σ dz. The absorption coefficient is thusμ = n σ

Mass attenuation, absorption, and scattering coefficients

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Main article:Mass attenuation coefficient

Themass attenuation coefficient,mass absorption coefficient, andmass scattering coefficient are defined as[8]

μρm,μaρm,μsρm,{\displaystyle {\frac {\mu }{\rho _{m}}},\quad {\frac {\mu _{\mathrm {a} }}{\rho _{m}}},\quad {\frac {\mu _{\mathrm {s} }}{\rho _{m}}},}

whereρm is themass density.

Napierian and decadic attenuation coefficients

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Decibels

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Main article:decibel

Engineering applications often express attenuation in thelogarithmic units ofdecibels, or "dB", where 10 dB represents attenuation by a factor of 10. The units for attenuation coefficient are thus dB/m (or, in general, dB per unit distance). Note that in logarithmic units such as dB, the attenuation is a linear function of distance, rather than exponential. This has the advantage that the result of multiple attenuation layers can be found by simply adding up the dB loss for each individual passage. However, if intensity is desired, the logarithms must be converted back into linear units by using an exponential:I=Io10(dB/10).{\displaystyle I=I_{o}10^{-(dB/10)}.}

Naperian attenuation

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Thedecadic attenuation coefficient ordecadic narrow beam attenuation coefficient, denotedμ10, is defined as

μ10=μln10.{\displaystyle \mu _{10}={\frac {\mu }{\ln 10}}.}

Just as the usual attenuation coefficient measures the number ofe-fold reductions that occur over a unit length of material, this coefficient measures how many 10-fold reductions occur: a decadic coefficient of 1 m−1 means 1 m of material reduces the radiation once by a factor of 10.

μ is sometimes calledNapierian attenuation coefficient orNapierian narrow beam attenuation coefficient rather than just simply "attenuation coefficient". The terms "decadic" and "Napierian" come from the base used for theexponential in theBeer–Lambert law for a material sample, in which the two attenuation coefficients take part:

T=e0μ(z)dz=100μ10(z)dz,{\displaystyle T=e^{-\int _{0}^{\ell }\mu (z)\mathrm {d} z}=10^{-\int _{0}^{\ell }\mu _{10}(z)\mathrm {d} z},}

where

  • T is thetransmittance of the material sample;
  • is the path length of the beam of light through the material sample.

In case ofuniform attenuation, these relations become

T=eμ=10μ10.{\displaystyle T=e^{-\mu \ell }=10^{-\mu _{10}\ell }.}

Cases ofnon-uniform attenuation occur inatmospheric science applications andradiation shielding theory for instance.

The (Napierian) attenuation coefficient and the decadic attenuation coefficient of a material sample are related to thenumber densities and theamount concentrations of itsN attenuating species as

μ(z)=i=1Nμi(z)=i=1Nσini(z),μ10(z)=i=1Nμ10,i(z)=i=1Nεici(z),{\displaystyle {\begin{aligned}\mu (z)&=\sum _{i=1}^{N}\mu _{i}(z)=\sum _{i=1}^{N}\sigma _{i}n_{i}(z),\\\mu _{10}(z)&=\sum _{i=1}^{N}\mu _{10,i}(z)=\sum _{i=1}^{N}\varepsilon _{i}c_{i}(z),\end{aligned}}}

where

by definition of attenuation cross section and molar attenuation coefficient.

Attenuation cross section and molar attenuation coefficient are related by

εi=NAln10σi,{\displaystyle \varepsilon _{i}={\frac {N_{\text{A}}}{\ln {10}}}\,\sigma _{i},}

and number density and amount concentration by

ci=niNA,{\displaystyle c_{i}={\frac {n_{i}}{N_{\text{A}}}},}

whereNA is theAvogadro constant.

Thehalf-value layer (HVL) is the thickness of a layer of material required to reduce the radiant flux of the transmitted radiation to half its incident magnitude. The half-value layer is about 69% (ln 2) of thepenetration depth. Engineers use these equations predict how much shielding thickness is required to attenuate radiation to acceptable or regulatory limits.

Attenuation coefficient is also inversely related tomean free path. Moreover, it is very closely related to the attenuationcross section.

Other radiometric coefficients

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Radiometry coefficients
QuantitySI unitsNotes
NameSym.
Hemispherical emissivityεRadiant exitance of asurface, divided by that of ablack body at the same temperature as that surface.
Spectral hemispherical emissivityεν
ελ
Spectral exitance of asurface, divided by that of ablack body at the same temperature as that surface.
Directional emissivityεΩRadianceemitted by asurface, divided by that emitted by ablack body at the same temperature as that surface.
Spectral directional emissivityεΩ,ν
εΩ,λ
Spectral radianceemitted by asurface, divided by that of ablack body at the same temperature as that surface.
Hemispherical absorptanceARadiant fluxabsorbed by asurface, divided by that received by that surface. This should not be confused with "absorbance".
Spectral hemispherical absorptanceAν
Aλ
Spectral fluxabsorbed by asurface, divided by that received by that surface. This should not be confused with "spectral absorbance".
Directional absorptanceAΩRadianceabsorbed by asurface, divided by the radiance incident onto that surface. This should not be confused with "absorbance".
Spectral directional absorptanceAΩ,ν
AΩ,λ
Spectral radianceabsorbed by asurface, divided by the spectral radiance incident onto that surface. This should not be confused with "spectral absorbance".
Hemispherical reflectanceRRadiant fluxreflected by asurface, divided by that received by that surface.
Spectral hemispherical reflectanceRν
Rλ
Spectral fluxreflected by asurface, divided by that received by that surface.
Directional reflectanceRΩRadiancereflected by asurface, divided by that received by that surface.
Spectral directional reflectanceRΩ,ν
RΩ,λ
Spectral radiancereflected by asurface, divided by that received by that surface.
Hemispherical transmittanceTRadiant fluxtransmitted by asurface, divided by that received by that surface.
Spectral hemispherical transmittanceTν
Tλ
Spectral fluxtransmitted by asurface, divided by that received by that surface.
Directional transmittanceTΩRadiancetransmitted by asurface, divided by that received by that surface.
Spectral directional transmittanceTΩ,ν
TΩ,λ
Spectral radiancetransmitted by asurface, divided by that received by that surface.
Hemispherical attenuation coefficientμm−1Radiant fluxabsorbed andscattered by avolume per unit length, divided by that received by that volume.
Spectral hemispherical attenuation coefficientμν
μλ
m−1Spectral radiant fluxabsorbed andscattered by avolume per unit length, divided by that received by that volume.
Directional attenuation coefficientμΩm−1Radianceabsorbed andscattered by avolume per unit length, divided by that received by that volume.
Spectral directional attenuation coefficientμΩ,ν
μΩ,λ
m−1Spectral radianceabsorbed andscattered by avolume per unit length, divided by that received by that volume.

See also

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References

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  1. ^abIUPAC,Compendium of Chemical Terminology, 5th ed. (the "Gold Book") (2025). Online version: (2006–) "Attenuation coefficient".doi:10.1351/goldbook.A00516
  2. ^Serway, Raymond; Moses, Clement; Moyer, Curt (2005).Modern Physics. California, USA: Brooks/Cole. p. 529.ISBN 978-0-534-49339-4.
  3. ^"2nd Edition of the Glossary of Meteorology".American Meteorological Society. Retrieved2015-11-03.
  4. ^abJackson, John David (1975).Classical electrodynamics (2d ed.). New York: Wiley.ISBN 978-0-471-43132-9.
  5. ^ISO 20998-1:2006 "Measurement and characterization of particles by acoustic methods"
  6. ^Dukhin, A.S. and Goetz, P.J. "Ultrasound for characterizing colloids", Elsevier, 2002
  7. ^Mayerhöfer, Thomas G.; Pahlow, Susanne; Popp, Jürgen (2020)."The Bouguer-Beer-Lambert Law: Shining Light on the Obscure".ChemPhysChem.21 (18):2029–2046.doi:10.1002/cphc.202000464.ISSN 1439-7641.PMC 7540309.PMID 32662939.
  8. ^abcdefg"Thermal insulation — Heat transfer by radiation — Physical quantities and definitions".ISO 9288:1989.ISO catalogue. 1989. Retrieved2015-03-15.
  9. ^Subrahmanyan Chandrasekhar (1960).Radiative Transfer. Dover Publications Inc. p. 355.ISBN 978-0-486-60590-6.{{cite book}}:ISBN / Date incompatibility (help)

External links

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