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2-Octyne

From Wikipedia, the free encyclopedia
2-Octyne
Names
Preferred IUPAC name
Oct-2-yne
Other names
Amylmethylacetylene; Methylpentylacetylene
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.018.685Edit this at Wikidata
EC Number
  • 220-553-3
UNII
  • InChI=1S/C8H14/c1-3-5-7-8-6-4-2/h3,5,7-8H2,1-2H3
    Key: QCQALVMFTWRCFI-UHFFFAOYSA-N
  • InChI=1/C8H14/c1-3-5-7-8-6-4-2/h3,5,7-8H2,1-2H3
    Key: QCQALVMFTWRCFI-UHFFFAOYAD
  • CC#CCCCCC
Properties
C8H14
Molar mass110.200 g·mol−1
Density0.759 g/mL
Boiling point137 °C (279 °F; 410 K)
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

2-Octyne, also known as methylpentylethyne and oct-2-yne,[1] is a type ofalkyne with atriple bond at its secondcarbon (the '2-' indicates the location of the triple bond in the chain). Its formula is C8H14.[2] Its density at 25 °C and otherwise stable conditions is 0.759 g/ml.[3] Theboiling point is 137 °C.[3] The averagemolar mass is 110.20 g/mol.[2]

It is formed by isomerization of1-octyne catalyzed by a YbII complex.[4]

References

[edit]
  1. ^"2-OCTYNE | C8H14 - PubChem".pubchem.ncbi.nlm.nih.gov. Retrieved16 August 2016.
  2. ^abRogers, D. W.; Dagdagan, O. A.; Allinger, N. L. (1979)."webbook.nist.gov/cgi/cbook.cgi". pp. 671–676. Retrieved16 August 2016.
  3. ^abSigma-Aldrich Co.,2-Octyne. Retrieved on 16 August 2016.
  4. ^Makioka, Yoshikazu; Taniguchi, Yuki; Kitamura, Tsugio; Fujiwara, Yuzo; Saiki, Akira; Takaki, Ken. Isomerization of terminal alkynes catalyzed by ytterbium(II)-aromatic imine complexes.Bulletin de la Société Chimique de France, 1997. Volume 134. (3&4) pp 349-355.
Preparations
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