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Nickel(II) phosphate

From Wikipedia, the free encyclopedia
Nickel(II) phosphate
Names
IUPAC name
Nickel(2+) diphosphate
Other names
Nickel(III) phosphate, nickel diphosphate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.030.755Edit this at Wikidata
EC Number
  • 233-844-5
UNII
  • InChI=1S/3Ni.2H3O4P/c;;;2*1-5(2,3)4/h;;;2*(H3,1,2,3,4)/q3*+2;;/p-6
    Key: AFYAQDWVUWAENU-UHFFFAOYSA-H
  • [O-]P(=O)([O-])[O-].[O-]P(=O)([O-])[O-].[Ni+2].[Ni+2].[Ni+2]
Properties
Ni3(PO4)2
Molar mass366.022924 g/mol
AppearanceGreen solid
Density4.38 g/cm3
4.74×10−32[1]
Structure[2]
Monoclinic,mP26
P21/c, No. 14
a = 0.58273 nm,b = 0.46964 nm,c = 1.01059 nm
α = 90°, β = 91.138°, γ = 90°
Hazards
GHS labelling:
GHS07: Exclamation markGHS08: Health hazardGHS09: Environmental hazard
Danger
H317,H334,H372,H410
P203,P260,P264,P270,P272,P273,P280,P284,P302+P352,P304+P340,P318,P319,P321,P333+P317,P342+P316,P362+P364,P391,P405,P501
NFPA 704 (fire diamond)
Safety data sheet (SDS)www.fishersci.com
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Nickel(II) phosphate is aninorganic compound with the formula Ni3(PO4)2. It is a mint green paramagnetic solid that is insoluble in water.[3]

Hydrated nickel(II) phosphate

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The hydrate Ni3(PO4)2·8(H2O) is a light green solid, which can be prepared byhydrothermal synthesis[4] and also occurs as the mineralarupite. It features octahedral Ni centers, which are bound towater and phosphate.[5]

Ni phosphate nanorings and nanotubes. Scale bar 50 nm.[6]

References

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Wikimedia Commons has media related toNickel phosphate.
  1. ^John Rumble (June 18, 2018).CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 5–189.ISBN 978-1138561632.
  2. ^McMurdie, Howard F.; Morris, Marlene C.; Evans, Eloise H.; Paretzkin, Boris;Wong-Ng, Winnie; Zhang, Yuming; Hubbard, Camden R. (2013). "Standard X-Ray Diffraction Powder Patterns from the JCPDS Research Associateship".Powder Diffraction.2 (1):41–52.Bibcode:1987PDiff...2...41M.doi:10.1017/S0885715600012239.S2CID 251057066.
  3. ^Calvo, Crispin; Faggiani, Romolo (1975)."Structure of Nickel Orthophosphate".Canadian Journal of Chemistry.53 (10):1516–1520.doi:10.1139/v75-210.
  4. ^Perry, Dale L. (18 May 2011).Handbook of Inorganic Compounds, Second Edition. CRC Press. p. 292.ISBN 978-1-4398-1462-8.
  5. ^Shouwen, Jin; Wang, Daqi; Gao, Xinjun; Wen, Xianhong; Zhou, Jianzhong (2008)."Poly[octaaquadi-μ-phosphato-trinickel(II)]".Acta Crystallographica Section E.64 (Pt 1): m259.Bibcode:2008AcCrE..64M.259S.doi:10.1107/S1600536807067050.PMC 2915172.PMID 21200596.
  6. ^Ni, Bing; Liu, Huiling; Wang, Peng-Peng; He, Jie; Wang, Xun (2015)."General synthesis of inorganic single-walled nanotubes".Nature Communications.6: 8756.Bibcode:2015NatCo...6.8756N.doi:10.1038/ncomms9756.PMC 4640082.PMID 26510862.
Nickel(0)
Nickel(II)
Nickel(III)
Nickel(IV)
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