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Hydrogen assisted magnesiothermic reduction

From Wikipedia, the free encyclopedia

Thehydrogen assisted magnesiothermic reduction ("HAMR") process is a thermochemical process to obtaintitanium metal from titanium oxides.[1][2]

A technical challenge in the production of titanium metal is the formation of oxide impurities. TheKroll process, which is widely used commercially, addresses this challenge by converting titanium ore (an oxide) intotitanium tetrachloride (TiCl4). This intermediate is readily purified. It is reduced to titanium metal with magnesium. This technology is both capital, energy, andcarbon-intensive. One advantage of the Kroll process, and several like it, is that it starts with titanium ores (e.g.,illmenite), not a purified dioxide.

The HAMR technology also entails a two step process, starting withTiO2 under an atmosphere of hydrogen gas. The productTiH2 can be further processed to titanium metal through standard methods. The reduction of titanium oxides to titanium metal using magnesium does not occur. The novelty of the HAMR process is the inclusion of hydrogen.[3]

References

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  1. ^Xia, Yang; Fang, Z. Zak; Zhang, Ying; Lefler, Hyrum; Zhang, Tuoyang; Sun, Pei; Huang, Zhe (2017)."Hydrogen Assisted Magnesiothermic Reduction (HAMR) of Commercial TiO2 to Produce Titanium Powder with Controlled Morphology and Particle Size".Materials Transactions.58 (3):355–360.doi:10.2320/matertrans.MK201628.
  2. ^Xia, Yang; Lefler, Hyrum D.; Zhang, Ying; Sun, Pei; Fang, Zhigang Zak (2020). "Hydrogen Assisted Magnesiothermic Reduction (HAMR) of TiO2 to Produce Titanium Metal Powder".Extractive Metallurgy of Titanium. pp. 165–179.doi:10.1016/b978-0-12-817200-1.00009-0.ISBN 9780128172001.S2CID 213342922.
  3. ^"asx.com.au, "TAO TO EXPLORE COMMERCIALIZATION OF LOW-CARBON, LOW-COST TITANIUM METAL POWDER IN THE USA"".
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